Effects of acoustic alarms, designed to reduce small cetacean bycatch in gillnet fisheries, on the behaviour of North Sea fish species in a large tank

World-wide many cetaceans drown incidentally in fishing nets. To reduce the unwanted bycatch in gillnets, pingers (acoustic alarms) have been developed that are attached to the nets. In the European Union, pingers will be made compulsory in some areas in 2005 and in others in 2007. However, pingers may effect non-target marine fauna such as fish. Therefore in this study, the effects of seven commercially-available pingers on the behaviour of five North Sea fish species in a large tank were quantified. The species tested were: sea bass (Dicentrarchus labrax), pout (Trisopterus luscus), thicklip mullet (Chelon labrosus), herring (Clupea harengus), and cod (Gadus morhua). The fish were housed as single-species schools of 9-13 individuals in a tank. The behaviour of fish in quiet periods was compared with their behaviour during periods with active pingers. The results varied both between pingers and between fish species. Sea bass decreased their speed in response to one pinger and swam closer to the surface in response to another. Thicklip mullet swam closer to the bottom in response to two pingers and increased their swimming speed in response to one pinger. Herring swam faster in response to one pinger, and pout and cod (close relatives) showed no behavioural responses to any of the pingers. Of the seven pingers tested, four elicited responses in at least one fish species, and three elicited no responses. Whether similar responses would be elicited in these fish species in the wild, and if so, whether such responses would influence the catch rate of fisheries, cannot be derived from the results of this study. However, the results indicate the need for field studies with pingers and fish. Based on the small number of fish species tested, the present study suggests that the higher the frequency of a pinger, the less likely it is to affect the behaviour of marine fish.     

Regional investigations of vertical crustal movements in the U.S., using precise relevelings and mareograph data

In the past two years, the National Geodetic Survey has been creating a data base of vertical crustal movement information. The data elements are relative elevation changes along lines of releveling which are used to produce graphic displays on microfilm. In separate studies, the releveling data, together with information extracted from mareograph records, have been used to create two networks of velocity differences. The two networks, one in the vicinity of Chesapeake Bay and the other covering the Gulf Coast states, have been adjusted in order to prepare maps showing the velocities of elevation change. In the adjustments, the velocities derived from mareograph records were treated as observations. The results indicate annual subsidence ranging between −1.2 mm and −4.0 mm in the Chesapeake Bay area, with significant local variation. In the Gulf Coast region there is generally slight subsi'dence along the coast, ranging between 0.0 and −1.5 mm/year. Stability and slight uplift is indicated to the north where bedrock reaches the terrain surface. Anomalous subsidence of −7.0 mm/year occurs at New Orleans, La., and at Houston, Texas, there has been several decimeters change in the last ten years.     

Airborne LiDAR and Terrestrial Laser Scanning Derived Vegetation Obstruction Factors for Visibility Models

Research presented here explores the feasibility of leveraging vegetation data derived from airborne light detection and ranging (LiDAR) and terrestrial laser scanning (TLS) for visibility modeling. Using LiDAR and TLS datasets of a lodgepole pine (Pinus contorta) dominant ecosystem, tree canopy and trunk obstructions were isolated relevant to a discrete visibility beam in a short‐range line‐of‐sight model. Cumulative obstruction factors from vegetation were compared with reference visibility values from digital photographs along sightline paths. LiDAR‐derived tree factors were augmented with single‐scan TLS data for obstruction prediction. Good correlation between datasets was found up to 10 m from the terrestrial scanner, but fine scale visibility modeling was problematic at longer distances. Analysis of correlation and regression results reveal the influence of obstruction shadowing inherent to discrete LiDAR and TLS, potentially limiting the feasibility of modeling visibility over large areas with similar technology. However, the results support the potential for TLS‐derived subcanopy metrics for augmenting large amounts of aerial LiDAR data to significantly improve models of forest structure. Subtle LiDAR processing improvements, including more accurate tree delineation through higher point density aerial data, combined with better vegetation quantification processes for TLS data, will advance the feasibility and accuracy of data integration.     

Conditions of core formation in the earth: Constraints from Nickel and Cobalt partitioning

The abundances of Ni and Co in the Earth’s mantle are depleted relative to chondrites due to terrestrial core formation. Recently, the observed mantle depletions of these elements have been explained by liquid metal-liquid silicate equilibrium during core formation in a high pressure, high temperature magma ocean on the early Earth. However, different magma ocean models, which would be expected to give consistent results, have proposed vastly different pressures (24 to 59 GPa), temperatures (2200 to >4000 K) and oxygen fugacities (−0.15 to −2.4 ΔIW) for the Earth’s magma ocean. In an attempt to resolve the contradictory results from different magma ocean models and determine the thermodynamic conditions appropriate for core formation in the Earth, experiments were conducted to better constrain the influences of temperature and C on the partitioning behaviors of Ni and Co. Results of experiments at 7 GPa with temperatures of 1923-2673 K show that the metal-silicate partition coefficients for both Ni and Co decrease with increasing temperature, with the effect being more significant for Ni. Little change in the partitioning behaviors of either Ni or Co with varying C-content of the metallic liquid was found. By combining the new temperature data with previous results from pressure and oxygen fugacity studies, we parameterized the partitioning behavior of Ni and Co and applied the parameterizations to core formation in a terrestrial magma ocean. Multiple combinations of pressure, temperature, and oxygen fugacity can explain the observed mantle depletions of Ni and Co, and all of the very different previously proposed magma ocean conditions are generally consistent with valid solutions. By using the FeO content of the Earth’s mantle as an additional constraint on the oxygen fugacity, magma ocean conditions of 30-60 GPa, > 2000 K, and −2.2 ΔIW are suggested. Similar systematic approaches and studies of other moderately siderophile elements could further constrain the magma ocean conditions on the early Earth.     

Gases and water isotopes in a geochemical section across the Larderello,Italy, geothermal field

Steam samples from six wells (Colombaia, Pineta, Larderello 57, Larderello 155, Gabbro 6, and Gabbro 1) in a south to north section across the Larderello geothermal field have been analyzed for inorganic and hydrocarbon gases and for oxygen-18 and deuterium of steam. The wells generally decrease in depth and increase in age toward the south. The steam samples are generally characterized by

1. Total gas contents increasing south to north from 0.003 to 0.05 mole fraction;
2. Constant CO₂ (95±2 percent); near constant H₂S (1.6±0.8), N₂ (1.2±0.8), H₂ (2±1), CH₄ (1.2±1), and no O₂ in the dry gas;
3. Presence of numerous, straight chain and branched C₂ to C₆ hydrocarbons plus benzene in amounts independent of CH₄ contents with highest concentrations in the deeper wells;
4. Oxygen-18 contents of steam increasing south to north from ?5.0‰ to ?0.4‰ with little change in deuterium (?42±2‰).

These observations are interpreted as showing:

1. Decreasing gas contents with amount of production because the proportion of steam boiled from liquid water increases with production;
2. Synthesis of CH₄ from H₂ and CO₂ with CO₂ and H₂ produced by thermal metamorphism and rock-water reactions;
3. Extraction of C₂ to C₆ hydrocarbons from rock organic matter;
4. Either oxygen isotope exchange followed by distillation of steam from the north toward the south (2 plates at ～220°C) or mixture of deeper more-exchange waters from the north with shallow, less-exchanged recharging waters from the south.

     

Chemical equilibrium model of solution behavior and solubility in the H-Na-K-OH-Cl-HSO4-SO4-H2O system to high concentration and temperature

This paper describes a chemical model that calculates solute and solvent activities and solid-liquid equilibria in the H-Na-K-OH-Cl-HSO₄-SO₄-H₂O system from dilute to high solution concentration within the 0° to 250°C temperature range. All binary and ternary subsystems are included in the model parameterization. The model is validated by comparing predictions with experimental data, primarily in higher order systems, not used in the parameterization process. Limitations of the model due to data insufficiencies are discussed.The Harvie and Weare (GCA44, 981, 1980) solubility modeling approach, incorporating their implementation of the concentration-dependent specific interaction equations of Pitzer (J. Phys. Chem.77, 268, 1973), is employed. This model expands the variable temperature Na-K-Cl-SO₄-H₂O model of Greenberg and Moller (GCA53, 2503, 1989) by including acid (H₂SO₄, HCl) and base (NaOH, KOH) species. Temperature functions for the chemical potentials of 5 acidic (sodium bisulfate, sodium sesquisulfate, mercallite, potassium sesquisulfate and misenite) and 6 basic (4 sodium hydroxide hydrates and 2 potassium hydroxide hydrates) solid phases are determined.     

Stratal architecture and platform evolution of an early Frasnian syn‐tectonic carbonate platform,Canning Basin,Australia

Facies architecture and platform evolution of an early Frasnian reef complex in the northern Canning Basin of north‐western Australia were strongly controlled by syn‐depositional faulting during a phase of basin extension. The margin‐attached Hull platform developed on a fault block of Precambrian basement with accommodation largely generated by movement along the Mount Elma Fault Zone. Recognition of major subaerial exposure and flooding surfaces in the Hull platform (from outcrop and drillcore) has enabled comparison of facies associations within a temporal framework and led to identification of three stages of platform evolution. Stage 1 records initial ramp development on the hangingwall dip slope with predominantly deep subtidal conditions that prevented any cyclic facies arrangements. This stage is characterised by basal siliciclastic deposits and a major deepening‐upward facies pattern that is capped by a sequence boundary towards the footwall (north‐west) and a major flooding surface towards the hangingwall. Stage 2 reflects the bulk of platform aggradation, significant platform growth towards the hangingwall and the development of reef margins and cyclic facies arrangements. Thickening of this stage towards the hangingwall indicates that accommodation was generated by rotation of the fault block and overlying platform. Stage 3 records a major flooding and backstep of the platform margin. The Hull platform illustrates important elements of margin‐attached carbonate platforms in a half‐graben setting, including: (i) prominent, but limited, coarse siliciclastic input that does not have a major detrimental effect on carbonate production near the rift margin in arid to semi‐arid settings; (ii) wedge‐shaped accommodation created by syn‐depositional rotation of fault blocks and tilting of the hangingwall dip slope, resulting in shallow‐water facies and subaerial exposure up‐dip of the rotational axis and deeper water facies down‐dip; and (iii) evolution of a ramp to rimmed shelf, coincident with a sequence boundary–flooding surface, that is accelerated by tilting of the hangingwall dip slope during fault‐block rotation.     

A high temperature equation of state for the H2O-CaCl2 and H2O-MgCl2 systems

An equation of state (EOS) is developed for salt-water systems in the high temperature range. As an example of the applications, this EOS is parameterized for the calculation of density, immiscibility, and the compositions of coexisting phases in the CaCl₂-H₂O and MgCl₂-H₂O systems from 523 to 973 K and from saturation pressure to 1500 bar. All available volumetric and phase equilibrium measurements of these binaries are well represented by this equation. This EOS is based on a Helmholtz free energy representation constructed from a reference system containing hard-sphere and polar contributions plus an empirical correction. For the temperature and pressure range in this study, the electrolyte solutes are assumed to be associated. The water molecules are modeled as hard spheres with point dipoles and the solute molecules, MgCl₂ and CaCl₂, as hard spheres with point quadrupoles. The free energy of the reference system is calculated from an analytical representation of the Helmholtz free energy of the hard-sphere contributions and perturbative estimates of the electrostatic contributions. The empirical correction used to account for deviations of the reference system predictions from measured data is based on a virial expansion. The formalism allows generalization to aqueous systems containing insoluble gases (CO₂, CH₄), alkali chlorides (NaCl, KCl), and alkaline earth chlorides (CaCl₂, MgCl₂). The program of this model is available as an electronic annex (see EA1 and EA2) and can also be downloaded at: http://www.geochem-model.org/programs.htm.     

Apatite-rich pyrometamorphic rocks from Suweileh area,Jordan

Representative samples from the upper Cretaceous pyrometamorphic rocks from Suweileh area were investigated by using XRD, XRF, SEM/EDS, and microprobe techniques. Suweileh area is characterized by the presence of varicolored marble (dominated by green apatite-rich rocks) overlying bituminous marl and silicified limestone-phosphorite beds. The bituminous rocks are enriched with P, S, and F in addition to reduced sensitive trace elements that were inherited later by their metamorphic equivalents. The rocks were affected by severe tectonism that produced intensive fracturing which facilitated the chemical leaching. The mineralogy of the varicolored marble from Suweileh area is equivalent to Daba-Siwaqa and Maqarin areas in central and north Jordan. High-temperature and low-temperature groups of minerals were recognized. The first group is the result of pyrometamorphism produced from the spontaneous combustion of bituminous marl. The metamorphism was contemporaneous with tectonism of the Rift Valley. The second secondary group of minerals is the result of alteration by high alkaline waters followed by precipitation along the weakness zones. A hyperalkaline circulating water similar to the current issuing waters from Maqarin (north Jordan) was responsible for leaching and precipitation of anions and trace elements. A similar scenario was reported in north and central Jordan. The calculated structural formula of fluorapatite is Ca_5.02 (P_2.325, Si_0.22, S_0.0833) O₁₂ F_0.975. The apatite structure incorporates S and Si (inherited from the bituminous precursor) that substitute for P in the tetrahedral positions.