Potential protonation sites in the Al<Subscript>2</Subscript>SiO<Subscript>5</Subscript> polymorphs based on polarized FTIR spectroscopy and properties of the electron density distribution

Potential protonation sites for, kyanite, sillimanite, and andalusite, located in a mapping of the (3, −3) critical points displayed by their L(r) = −∇²ρ(r) distributions, are compared with polarized single-crystal FTIR spectra of kyanite and sillimanite determined earlier and with andalusite measured in this study. For andalusite, seven peaks were observed when the electric vector, E, is parallel to [100]: four intense ones at 3,440, 3,460, 3,526, and 3,597 cm⁻¹ and three weaker ones at 3,480, 3,520, and 3,653 cm⁻¹. Six peaks, three intense ones at 3,440, 3,460, and 3,526 cm⁻¹ and three weaker ones at 3,480, 3,520, and 3,653 cm⁻¹ when E parallels [010]. No peaks were observed when E is parallel to [001]. The concentration of water in andalusite varies between 110 and 168 ppm by weight % H₂O. Polarized FTIR spectra indicate that the OH vector is parallel to (001) in andalusite and sillimanite and in kyanite. Examination of the L(r) (3, −3) critical points in comparison with the polarized FTIR indicates that H prefers to bond to the oxygen atoms O1 and O2 in andalusite and O2 and O4 in sillimanite which correspond to the underbonded oxygen atoms and those with the largest L(r) maxima. In kyanite, comparison of the FTIR spectrum and the critical points indicates that H will preferentially bond to the two 4-coordinated O2 and O6 atoms.     

Geochemistry and Evolution of Subcontinental Lithospheric Mantle in Central Europe: Evidence from Peridotite Xenoliths of the Kozakov Volcano, Czech Republic

Neogene basanite lavas of Kozákov volcano, located alongthe Lusatian fault in the northeastern Czech Republic, containabundant anhydrous spinel lherzolite xenoliths that providean exceptionally continuous sampling of the upper two-thirdsof central European lithospheric mantle. The xenoliths yielda range of two-pyroxene equilibration temperatures from 680°Cto 1070°C, and are estimated to originate from depths of32–70 km, based on a tectonothermal model for basalticunderplating associated with Neogene rifting. The sub-Kozákovmantle is layered, consisting of an equigranular upper layer(32–43 km), a protogranular intermediate layer that containsspinel–pyroxene symplectites after garnet (43–67km), and an equigranular lower layer (67–70 km). Negativecorrelations of wt % TiO₂, Al₂O₃, and CaO with MgO and clinopyroxenemode with Cr-number in the lherzolites record the effects ofpartial fusion and melt extraction; Y and Yb contents of clinopyroxeneand the Cr-number in spinel indicate 5 to 15% partial melting.Subsequent metasomatism of a depleted lherzolite protolith,probably by a silicate melt, produced enrichments in the largeion lithophile elements, light rare earth elements and highfield strength elements, and positive anomalies in primitivemantle normalized trace element patterns for P, Zr, and Hf.Although there are slight geochemical discontinuities at theboundaries between the three textural layers of mantle, theretends to be an overall decrease in the degree of depletion withdepth, accompanied by a decrease in the magnitude of metasomatism.Clinopyroxene separates from the intermediate protogranularlayer and the lower equigranular layer yield ¹⁴³Nd/¹⁴⁴Nd valuesof 0·51287–0·51307 (_Nd = +4·6 to+8·4) and ⁸⁷Sr/⁸⁶Sr values of 0·70328–0·70339.Such values are intermediate with respect to the Nd–Srisotopic array defined by anhydrous spinel peridotite xenolithsfrom central Europe and are similar to those associated withthe present-day low-velocity anomaly in the upper mantle beneathEurope. The geochemical characteristics of the central Europeanlithospheric mantle reflect a complex evolution related to Devonianto Early Carboniferous plate convergence, accretion, and crustalthickening, Late Carboniferous to Permian extension and gravitationalcollapse, and Neogene rifting, lithospheric thinning, and magmatism. KEY WORDS: xenoliths; lithospheric mantle; REE–LILE–HFSE; Sr–Nd isotopes; Bohemian Massif     

Quantifying impacts of forecast uncertainties on predicted storm surges

In this paper, we propose a framework for quantifying risks, including (1) the effects of forecast errors, (2) the ability to resolve critical grid features that are important to accurate site-specific forecasts, and (3) a framework that can move us toward performance-based/cost-based decisions, within an extremely fast execution time. A key element presently lacking in previous studies is the interrelationship between the effects of combined random errors and bias in numerical weather prediction (NWP) models and bias and random errors in surge models. This approach examines the number of degrees of freedom in present forecasts and develops an equation for the quantification of these types of errors within a unified system, given the number of degrees of freedom in the NWP forecasts. It is shown that the methodology can be used to provide information on the forecasts and along with the combined uncertainty due to all of the individual contributions. A potential important benefit from studies using this approach would be the ability to estimate financial and other trade-offs between higher-cost “rapid” evacuation methods and lower-cost “slower” evacuation methods. Analyses here show that uncertainty inherent in these decisions depends strongly on forecast time and geographic location. Methods based on sets of surge maxima do not capture this uncertainty and would be difficult to use for this purpose. In particular, it is shown that surge model bias can play a dominant role in distorting the forecast probabilities.     

Three Spaces of Spatial Cognition

As we move about and interact in the world, we keep track of different spaces, among them the space of navigation, the space immediately around the body, and the space of the body. We review research showing that these spaces are conceptualized differently. Knowledge of the space of navigation is systematically distorted. For example, people mentally rotate roads and land masses to greater correspondence with global reference frames, they mentally align roads and land masses, they overestimate distances near the viewpoint relative to those far from it. These and other distortions indicate that the space of navigation is schematized to elements and spatial relations relative to reference frames and perspective. The space around the body is organized into a mental framework consisting of extensions of the major axes of the body. Times to report objects around the body suggest that the relative accessibility of the axes depends on their perceptual and functional properties and the relation of the body to the world. Finally, times to verify named or depicted body parts indicate that body schemas depend on perceptual and functional significance. Thus, these spaces (and they are not the only ones important to human interaction) differ from one another and are not conceptualized as Euclidean. Rather they are schematized into elements and spatial relations that reflect perceptual and conceptual significance.     

Hierarchical spatial modeling of the presence of Chagas disease insect vectors in Argentina. A comparative approach

We modeled the spatial distribution of the most important Chagas disease vectors in Argentina, in order to obtain a predictive mapping method for the probability of presence of the vector species. We analyzed both the binary variable of presence-absence of Chagas disease and the vector species richness in Argentina, in combination with climatic and topographical covariates associated to the region of interest. We used several statistical techniques to produce distribution maps of presence–absence for the different insect species as well as species richness, using a hierarchical Bayesian framework within the context of multivariate geostatistical modeling. Our results show that the inclusion of covariates improves the quality of the fitted models, and that there is spatial interaction between neighboring cells/pixels, so mapping methods used in the past, which assumed spatial independence, are not adequate as they provide unreliable results.     

The influence of underwater data transmission sounds on the displacement behaviour of captive harbour seals (Phoca vitulina)

To prevent grounding of ships and collisions between ships in shallow coastal waters, an underwater data collection and communication network (ACME) using underwater sounds to encode and transmit data is currently under development. Marine mammals might be affected by ACME sounds since they may use sound of a similar frequency (around 12 kHz) for communication, orientation, and prey location. If marine mammals tend to avoid the vicinity of the acoustic transmitters, they may be kept away from ecologically important areas by ACME sounds. One marine mammal species that may be affected in the North Sea is the harbour seal (Phoca vitulina). No information is available on the effects of ACME-like sounds on harbour seals, so this study was carried out as part of an environmental impact assessment program. Nine captive harbour seals were subjected to four sound types, three of which may be used in the underwater acoustic data communication network. The effect of each sound was judged by comparing the animals' location in a pool during test periods to that during baseline periods, during which no sound was produced. Each of the four sounds could be made into a deterrent by increasing its amplitude. The seals reacted by swimming away from the sound source. The sound pressure level (SPL) at the acoustic discomfort threshold was established for each of the four sounds. The acoustic discomfort threshold is defined as the boundary between the areas that the animals generally occupied during the transmission of the sounds and the areas that they generally did not enter during transmission. The SPLs at the acoustic discomfort thresholds were similar for each of the sounds (107 dB re 1 microPa). Based on this discomfort threshold SPL, discomfort zones at sea for several source levels (130-180 dB re 1 microPa) of the sounds were calculated, using a guideline sound propagation model for shallow water. The discomfort zone is defined as the area around a sound source that harbour seals are expected to avoid. The definition of the discomfort zone is based on behavioural discomfort, and does not necessarily coincide with the physical discomfort zone. Based on these results, source levels can be selected that have an acceptable effect on harbour seals in particular areas. The discomfort zone of a communication sound depends on the sound, the source level, and the propagation characteristics of the area in which the sound system is operational. The source level of the communication system should be adapted to each area (taking into account the width of a sea arm, the local sound propagation, and the importance of an area to the affected species). The discomfort zone should not coincide with ecologically important areas (for instance resting, breeding, suckling, and feeding areas), or routes between these areas.     

Evaluation of Zerovalent Zinc for Treatment of 1,2,3‐Trichloropropane‐Contaminated Groundwater: Laboratory and Field Assessment

The efficacy and feasibility of using zerovalent zinc (ZVZ) to treat 1,2,3‐trichloropropane (TCP)‐contaminated groundwater was assessed in laboratory and field experiments. In the first portion of the study, the reactivity of commercially available granular ZVZ toward TCP was measured in bench‐scale batch‐reactor and column experiments. These results were used to design columns for on‐site pilot‐scale treatment of contaminated groundwater at a site in Southern California. Two of the ZVZ materials tested were found to produce relatively high rates of TCP degradation as well as predictable behavior when scaling from bench‐scale to field testing. In addition, there was little decrease in the rates of TCP degradation over the duration of field testing. Finally, no secondary impacts to water quality were identified. The results suggest that ZVZ may be an effective and feasible material for use in engineered treatment systems, perhaps including permeable reactive barriers.     

Variability of Sea-Ice Extent in Baffin Bay over the Last Millennium

Comparison of an ice core glaciochemical time-series developed from thePenny Ice Cap (PIC), Baffin Island and monthly sea-ice extent reveals astatisticallysignificant inverse relationship between changes in Baffin Bay spring sea-iceextent andPenny Ice Cap sea-salt concentrations for the period 1901–1990 AD.Empiricalorthogonal function analysis demonstrates the joint behavior between changesin PICsea-salt concentrations, sea-ice extent, and changes in North Atlanticatmosphericcirculation. Our results suggest that sea-salt concentrations in snowpreserved on thePIC reflect local to regional springtime sea-ice coverage. The PIC sea-saltrecord/sea-ice relationship is further supported by decadal and century scalecomparisonwith other paleoclimate records of eastern Arctic climate change over the last700 years. Our sea-salt record suggests that, while the turn of the century wascharacterized bygenerally milder sea-ice conditions in Baffin Bay, the last few decades ofsea-ice extentlie within Little Ice Age variability and correspond to instrumental recordsof lowertemperatures in the Eastern Canadian Arctic over the past three decades.     

Catchment-scale observations at the Niwot Ridge long-term ecological research site

The Niwot Ridge and Green Lakes Valley (NWT) long-term ecological research (LTER) site collects environmental observations spanning both alpine and subalpine regimes. The first observations began in 1952 and have since expanded to nearly 300 available datasets over an area of 99 km² within the north-central Colorado Rocky Mountains that include hydrological (n = 101), biological (n = 79), biogeochemical (n = 62), and geographical (n = 56) observations. The NWT LTER database is well suited to support hydrologic investigations that require long-term and interdisciplinary data sets. Experimentation and data collection at the NWT LTER are designed to characterize ecological responses of high-mountain environments to changes in climate, nutrients, and water availability. In addition to the continuation of the many legacy NWT datasets, expansion of the breadth and utility of the NWT LTER database is driven by new initiatives including (a) a catchment-scale sensor network of soil moisture, temperature, humidity, and snow-depth observations to understand hydrologic connectivity and (b) snow-albedo alteration experiments using black sand to evaluate the effects of snow-disappearance on ecosystems. Together, these observational and experimental datasets provide a substantial foundation for hydrologic studies seeking to understand and predict changes to catchment and local-scale process interactions.