Laboratory Study of the Bidirectional Reflectance of Powdered Surfaces: On the Asymmetry Parameter of Asteroid Photometric Data

We performed laboratory experiments on the bidirectional reflectance of powdered surfaces of dunite, graphite, and Allende (CV3) and Gao (H5) meteorites. The particle size of each sample varied from tens to hundreds of micrometers. The absolute bidirectional reflectance was determined for two ranges of phase angle: from 2° to 80° at 0° angle of incidence and from 2° to 155° at 75° angle of incidence. The phase angle was incremented every 1° in between 2° and 5° and every 10° between 10° and 150°. We determined the Hapke parameters and found that the values of the asymmetry parameter retrieved for most of the samples were positive when the coverage of the phase angle was wide, 2° to 155°, although the values derived from remote sensing instruments on asteroid flyby missions have been negative or nearly zero. Among our sample surfaces, only those of graphite, Allende, and Gao with particle sizes of hundreds micrometers show negative or nearly zero values. The single-scattering albedos determined for the Gao samples are comparable to the values of S-class asteroids, while those for the Allende samples are much larger than those of C-class asteroids.     

Precise determination of ferrous iron in silicate rocks

We have developed a highly precise method for the determination of ferrous iron (Fe²⁺) in silicate rocks. Our new method is based on Wilson’s procedure (1955) in which surplus V⁵⁺ is used to oxidize Fe²⁺ into Fe³⁺ while equivalently reducing V⁵⁺ into V⁴⁺. Because V⁴⁺ is more resistant to atmospheric oxidation than Fe²⁺, Fe²⁺ in the sample can be determined by measuring unreacted V⁵⁺ by adding excess Fe²⁺ after sample decomposition and then titrating the unreacted Fe²⁺ with Cr⁶⁺. With our method, which involves conditioning the sample solution with 5 M H₂SO₄ in a relatively small beaker (7 mL), the oxidation of Fe²⁺ or V⁴⁺ that leads to erroneous results can be completely avoided, even in 100-h sample decompositions at 100°C. We have measured the concentration of FeO in 15 standard silicate rock powders provided by the Geological Survey of Japan (GSJ). Analytical reproducibility was better than 0.5% (1σ) for all but those samples that had small amounts of Fe²⁺ (<1.5 wt.% of FeO). Fourteen of these samples gave FeO contents significantly higher than the GSJ reference values. This likely indicates that the GSJ reference values, obtained by compiling previously published data, contain a large number of poor-quality data obtained by methods with lower recovery of Fe²⁺ caused by oxidation or insufficient sample decomposition during analyses. To achieve accurate determinations of Fe²⁺ in our method, several factors besides the oxidation must be considered, including: (1) long-term variations in the concentration of Fe²⁺ solution must be corrected; (2) excess use of the indicator must be avoided; and (3) the formation of inert FeF⁺ complex must be avoided during titration when using boric acid as a masking agent.     

Accuracy assessment of QuickBird stereo imagery

The Geographical Survey Institute of Japan has recently carried out an evaluation of the metric performance of QuickBird stereo satellite imagery. This paper describes the accuracy assessment of the sensor orientation and geopositioning phases of the study, the aim of which was twofold. First, it was desired to confirm the metric potential of QuickBird imagery for 1:25 000 scale topographic mapping. Second, a determination was to be made of the accuracy attainable from the Basic image product. The techniques of rational functions and affine bundle adjustment were employed, the former with bias compensation. The results obtained both reassert the high precision of the rational functions approach and cast doubt upon the applicability of the 3D affine model for accurate geopositioning from QuickBird imagery.     

Validation of HRDI MLT winds with meteor radars

A validation study of the mesospheric and lower-thermospheric (MLT) wind velocities measured by the High-Resolution Doppler Imager (HRDI) on board the Upper-Atmosphere Research Satellite (UARS) has been carried out, comparing with observations by meteor radars located at Shigaraki, Japan and Jakarta, Indonesia. The accuracy of the HRDI winds relative to the meteor radars is obtained by a series of simultaneous wind measurements at the time of UARS overpasses. Statistical tests on the difference in the wind vectors observed by HRDI and the meteor radars are applied to determine whether the wind speed has been overestimated by HRDI (or underestimated by the MF radars) as previously noticed in HRDI vs. MF radar comparisons. The techniques employed are the conventional t-test applied to the mean values of the paired wind vector components as well as wind speeds, and two nonparametric tests suitable for testing the paired wind speed. The square-root transformation has been applied before the Mests of the wind speed in order to fit the wind-speed distribution function to the normal distribution. The overall results show little evidence of overestimation by HRDI (underestimation by meteor radars) of wind velocities in the MLT region. Some exceptions are noticed, however, at the altitudes around 88 km, where statistical differences occasionally reach a level of significance of 0.01. The validation is extended to estimate the precision of the wind velocities by both HRDI and meteor radars. In the procedure, the structure function defined by the mean square difference of the observed anomalies is applied in the vertical direction for the profile data. This method assumes the isotropy and the homogeneity of variance for the physical quantity and the homogeneity of variance for the observational errors. The estimated precision is about 6m s^– for the Shigaraki meteor radar, 15 m s^–1 for the Jakarta meteor radar, and 20 m s^–1 for HRDI at 90-km altitude. These values can be used ot confirm the statistical significance of the wind field obtained by averaging the observed winds.     

An intercomparison between the GSWM, UARS, and ground based radar observations: a case-study in January 1993

The Global-Scale Wave Model (GSWM) is a steady-state two-dimensional linearized model capable of simulating the solar tides and planetary waves. In an effort to understand the capabilities and limitations of the GSWM throughout the upper mesosphere and thermosphere a comparative analysis with observational data is presented. A majority of the observational data used in this study was collected during the World Day campaign which ran from 20 January to 30 January 1993. During this campaign data from 18 ground-based observational sites across the globe and two instruments located on the UARS spacecraft were analyzed. Comparisons of these data with the simulations from the GSWM indicate that the GSWM results are in reasonable agreement with the observations. However, there are a number of cases where the agreement is not particularly good. One such instance is for the semidiurnal tide in the northern hemisphere, where the GSWM estimates may exceed observations by 50%. Through a number of numerical simulations, it appears that this discrepancy may be due to the eddy diffusivity profiles used by the GSWM. Other differences relating to the diurnal tide and the quasi-two-day wave are presented and discussed. Additionally, a discussion on the biases and aliasing difficulties which may arise in the observational data is alos presented.     

S, O and Sr isotope systematics of active vent materials from the Mariana backarc basin spreading axis at 18°N

Stable isotope ratios of S, O and Sr have been measured for active vent materials which were first found and sampled in April 1987 from the Mariana backarc spreading axis at 18°N. Chimneys consisted mostly of barite with a lesser proportion of sulfide minerals such as sphalerite, galena, chalcopyrite and pyrite. Theδ³⁴S values of sphalerite and galena taken from several chimneys and various parts of a chimney showed a narrow range from 2.1 to 3.1‰, suggesting uniform conditions of fluid chemistry during chimney growth. The sulfur isotopic results imply a contribution of hydrogen sulfide reduced from seawater sulfate in the deep hydrothermal reaction zone, considering that fresh glasses of the Mariana Trough basalts haveδ³⁴S= −0.6 ± 0.3‰. Sulfur isotopic compositions of hydrogen sulfide in the high temperature vent fluids (δ³⁴S= 3.6–4.8‰) which are higher than those of the sulfide minerals suggest the secondary addition of hydrogen sulfide partially reduced from entrained seawater SO₄²⁻ at a basal part of the chimneys. This interpretation is consistent with theδ³⁴S values of barite (21–22‰) that are higher than those of seawater sulfate. The residence time of the entrained SO₄²⁻ was an order of an hour on a basis of oxygen isotopic disequilibrium of barite. Strontium isotopic variations of barite and vent waters indicated that Sr in barite was mostly derived from the Mariana Trough basalts with a slight contribution from Sr in circulating sea-water, and that 10–20% mixing of seawater with ascending hydrothermal fluids induced precipitation of barite at the sea-floor.     

The Japan Trench and its juncture with the Kuril Trench: cruise results of the Kaiko project, Leg 3

This paper presents the results of a detailed survey combining Seabeam mapping, gravity and geomagnetic measurements as well as single-channel seismic reflection observations in the Japan Trench and the juncture with the Kuril Trench during the French-Japanese Kaiko project (northern sector of the Leg 3) on the R/V “Jean Charcot”. The main data acquired during the cruise, such as the Seabeam maps, magnetic anomalies pattern, and preliminary interpretations are discussed. These new data cover an area of 18,000 km² and provide for the first time a detailed three-dimensional image of the Japan Trench. Combined with the previous results, the data indicate new structural interpretations. A comparative study of Seabeam morphology, single-channel and reprocessed multichannel records lead to the conclusion that along the northern Japan Trench there is little evidence of accretion but, instead, a tectonic erosion of the overriding plate. The tectonic pattern on the oceanic side of the trench is controlled by the creation of new normal faults parallel to the Japan Trench axis, which is a direct consequence of the downward flexure of the Pacific plate. In addition to these new faults, ancient normal faults trending parallel to the N65° oceanic magnetic anomalies and oblique to the Japan trench axis are reactivated, so that two directions of normal faulting are observed seaward of the Japan Trench. Only one direction of faulting is observed seaward of the Kuril Trench because of the parallelism between the trench axis and the magnetic anomalies. The convergent front of the Kuril Trench is offset left-laterally by 20 km relative to those of the Japan Trench. This transform fault and the lower slope of the southernmost Kuril Trench are represented by very steep scarps more than 2 km high. Slightly south of the juncture, the Erimo Seamount riding on the Pacific plate, is now entering the subduction zone. It has been preceded by at least another seamount as revealed by magnetic anomalies across the landward slope of the trench. Deeper future studies will be necessary to discriminate between the two following hypothesis about the origin of the curvature between both trenches: Is it due to the collision of an already subducted chain of seamounts? or does it correspond to one of the failure lines of the America/Eurasia plate boundary?