Validation of the Meteosat Second Generation (MSG) fire monitoring product using ground observations over Turkey

Validation of the active fire monitoring (FIR) product from Spinning Enhanced Visible and Infrared Imager sensor of Meteosat Second Generation satellite is performed over Turkey. Ground truth data from the Ministry of Environment and Forestry for the years 2007, 2008, and 2009 is used by taking the active fire months of April–September into consideration. The contingency tables are obtained on a monthly basis and categorical statistics of probability of detection (POD) and false alarm rate (FAR) are derived. The results are introduced for each subclass, namely probable, possible, and combined cases. The highest POD amounts of 8.5, 1.93, and 9.4 % are obtained for the possible, probable, and combined cases, respectively, with the lowest FAR amounts of 70.9, 4.5, and 86.1 % for the same categories. FIR product validation with respect to predefined burnt area thresholds is introduced in the second part of the study in order to investigate burnt area effect in active fire detection. Increasing POD values with respect to burnt area amount is obtained with relatively higher values in probable than possible type. On the other hand, FAR variation is observed to be not correlated with the burnt area amount.     

A New Modification to the Chemical Mass Balance Receptor Model for Volatile Organic Compound Source Apportionment

In this study, a modification to the chemical mass balance (CMB) receptor model presented in an earlier work was expanded to account for the changes in volatile organic compound (VOC) source fingerprints due to atmospheric reactions of VOCs that take place after being emitted to the atmosphere. The photochemical reactions consume VOCs that participate in, causing changes in the source fingerprints. These changes are of considerable magnitude when the travel durations from the source to the receptor (measurement point) are considered. The current study focuses on expansion of the integrated reaction rates of VOCs with ambient reactive species such as OH ^? , O₃, NO₃, and O ^? in order to estimate the source emission profiles simultaneously at the receptor site. Two test cases with different travel times and with different ambient OH ^? , O₃, and NO₃ concentrations were also provided to compare the standard model, the modified model suggested in the previous work, and the current modification. F‐tests were also performed to determine whether the changes in source compositions are significant or not. The results from both the standard model and the modified model were evaluated in terms of χ², R², percent mass apportioned (MA), and a best fit (BF) measure. Maximum values of BF for the test cases from the three models were 0.70 ± 0.03, 0.74 ± 0.05, and 1.000 ± 0.00, respectively, indicating that the current modification increases the performance of two previous models and was better in explaining the effects of chemical reactions of VOCs.     

The influence of capillarity on multiphase flow within porous media: a new model for interpreting fluid levels in groundwater monitoring wells in dynamic aquifers

A new approach is presented to calculate the volume of oil in the underground at an oil spill site from fluid levels in monitoring wells. The approach includes the effects of hysteresis due to irregular pore geometry and to phase entrapment. It is possible to explain the drastic changes in the oil thickness in a monitoring well due to the decrease and increase in the groundwater table. A correct evaluation of the oil volume infiltrated underground from an oil spill and the effective control of remediation works can only be done by using the newly developed approach with a consideration of the dynamic changes in the groundwater table.     

Evolution of the Palaeotethys in the Eastern Mediterranean: a multi-method approach to unravel the age,provenance and tectonic setting of the Upper Palaeozoic Konya Complex and its Mesozoic cover sequence (south-central Turkey)

ABSTRACT

Siliciclastic sediments from the Upper Palaeozoic Konya Complex and its Mesozoic cover were studied by a multi-method approach combining thin-section petrography, bulk-rock geochemistry, mineral chemistry of rutile, and U–Pb geochronology of detrital zircons. Provenance sensitive data of samples from the Upper Palaeozoic Hal?c? Formation indicate sediment supply from mainly low- to medium-grade metamorphosed sedimentary rocks of felsic character, while the contribution from volcanic rocks was rare. The detrital zircon record of sediments from the Hal?c? Formation documents sediment supply from different sources and excludes a similar provenance. Some samples show great similarities with Palaeozoic sandstones from the cover sequence of the Saharan Metacraton and the Arabian–Nubian Shield, while the other samples indicate a provenance that must be sought in units with a southern Eurasian affinity. The upper limit for sediment deposition in the Hal?c? Formation is mostly constrained by Early Palaeozoic zircon populations; however, sediment accumulation in Pennsylvanian–Cisuralian time is more likely, contemporaneously with the Upper Palaeozoic succession on the Karaburun Peninsula (western Turkey). The provenance of sediments from the Upper Triassic Ard?çl? Formation remains enigmatic, but the source should be sought nonetheless in units close to the depositional site. In any case, detrital zircon age spectra and compositional data exclude recycling of underlying rock units (i.e. Hal?c? Formation). Overall, our new provenance data reveal great similarities between the Konya Complex and comparable units (Chios, Karaburun) but also highlight distinct differences in terms of sediment composition and provenance.     

Geochemical and petrographic studies of Ta mineralization in the Nuweibi albite granite complex, Eastern Desert, Egypt

The Nuweibi albite granite is one of 14 known Sn-Ta-Nb bearing granitoids in the Eastern Desert region of Egypt. The granite is a highly leucocratic, albite-rich rock with accessory columbite-tantalite, cassiterite, microlite and ixiolite as well as topaz, garnet and white mica. Ages of 450–600 Ma were obtained from zircons by the ²⁰⁷Pb/²⁰⁶Pb evaporation method. Great uncertainty is caused by the small size and poor quality of the grains, but the precision is sufficient to indicate that the granite is late- or postorogenic with respect to the Panafrican orogeny. The Nuweibi granite is divided into a western and an eastern part by a regional fault. Both parts of the granite are compositionally similar but there are important differences and a clear compositional gap between them, so they are considered separate facies of an intrusive complex. The eastern part of the granite is more highly mineralized, has higher modal albite contents and higher Ta/Nb ratios, both in the whole rock and in the ore minerals. It is suggested that the two parts of the granite evolved from a common source and were emplaced sequentially, the eastern part representing a later, more fractionated magma. Textural evidence strongly suggests that the granite has a magmatic origin overall, but disturbance of geochemical trends at the whole-rock scale and at the scale of zoning profiles in individual grains of columbite-tantalite indicate post-magmatic overprinting. By analogy with other Ta-bearing albite granites, the sodic bulk composition of the Nuweibi granite can be explained by fluorine enrichment in the magma. Fluorine contents in the magma were high enough to stabilize topaz, and muscovites contain 2–4 wt.%. F. However, whole-rock F contents are low. We speculate that the low Ca, Al and P contents of the magma prevented abundant F-bearing minerals to form and led to loss of fluorine to now-eroded roof rocks. Received: 8 November 1995 / Accepted: 10 June 1996     

Investigation of the photoluminescence properties of Urfa stone powder doped with chromium oxide

In this study, the structural properties of Urfa stone (US) doped with chromium oxide (Cr₂O₃) were investigated using X-ray diffraction (XRD) and FT-IR spectroscopy. The photoluminescence properties of US doped with varying amounts of Cr₂O₃ (5, 10, 20, 30, and 40%) were also investigated. US powder was obtained via grinding with an agate mortar, and Cr₂O₃ was then added as a dopant to the US powder. The samples were sintered at 1000 °C for 1 h. The XRD results of the US powder doped with Cr₂O₃ via mechanical alloying showed the presence of some crystalline phases: calcite (CaCO₃) and eskolate (Cr₂O₃). Furthermore, it was found that calcium oxide (CaO) and tongbaite (Cr₃C₂) were also present in the sintered samples. The photoluminescence analysis results indicated that the emission and excitation bands of the US-Cr complex shifted to longer and shorter wavelengths in the solid state (non-aqueous media), respectively.     

Spatially weighted principal component analysis (PCA) method for water quality analysis

Incorporating spatial information data into the principal component analysis is of importance. Some proposed methods of spatial weighting schemes to be applied to the ordinary PCA are reviewed and a new version of the method is proposed in the context of spatial analysis for geospatial multivariate analysis. In view of spatial variations in the hydrochemistry of rivers such combined version of the technique might be useful for reliable estimates.     

Petrological and source region characteristics of ophiolitic hornblende gabbros from the Aksaray and Kayseri regions, central Anatolian crystalline complex, Turkey

Many Neo-Tethyan ophiolitic bodies are well exposed as thrust-slices in Central Anatolia and are predominantly represented by massive hornblende gabbros, most of which are cut by Supra Subduction Zone (SSZ) plagiogranites. The allochthonous gabbros are distinct from their autochthonous counterparts, with their mineralogy including both igneous hornblende, relict diopside rimmed by replacement hornblende and their chemical composition corresponding mostly to gabbro rather than diorite.The results of major and trace element analyses of forty-two samples, and REE analyses of nine samples, indicate that the hornblende gabbros are SSZ-type and formed from a wet magma by high-degree partial melting of peridotite possibly coupled with contamination by predominantly neighbouring-slab derived fluids within an intra-oceanic back-arc basin. The mafic magmas then underwent high-level fractional crystallization involving titaniferous magnetite, diopside, tschermakite and possibly olivine. Emplacement was followed by extensive ocean–floor metamorphism, which has induced crystallization (or recrystallization) of chlorite, biotite, amphiboles and mobilisation of most of the major elements such as alkali and alkali earth elements, and some LREE.     

The distribution and elevated solubility of lead,arsenic and cesium in contaminated paddy soil enhanced with the electrokinetic field

The objectives of this study were to investigate fractionation, solubility and potential bioavailability of Pb, As and Cs in Mississippi River Delta paddy soil under an electrokinetic field (EKF). Effects of EKF on soil pH changes and solid-phase distributions of metal(loid)s were examined. Results showed that fractionation of Pb, As and Cs was largely determined by the nature of elements, loading levels and EKF treatment. Native Pb in the soil was mostly in the amorphous iron oxide, organic matter and residual fractions, native As in the amorphous iron oxide, easily reducible oxide and residue fractions while native Cs in the residue fraction. Added Pb, As and Cs showed distinguished solid-phase distributions: Pb dominantly in the organic matter fraction; As in the amorphous iron oxide fraction, and Cs in the residue with a significant water-soluble plus exchangeable fraction. EKF treatment is effective on lowering soil pH to 1.5 near the anode due to water electrolysis releasing proton which is beneficial for dissolution of metal(loid)s, increasing their overall solubility. The acidification in the anode soil efficiently increased the water-soluble Pb and the exchangeable Cs, implying enhanced solubility and elevated their overall potential bioavailability in the anode region while lower solubility in the cathode area. The building up of water-soluble As in the anode region may be from electromigration of As anion from the cathode. This study shows significant enhancement of redistribution, elevated solubility and overall bioavailability of Pb, As and Cs in Mississippi Delta paddy soil under the EKF.     

A comparative study on linear and nonlinear site response analysis

Site response analysis is usually the first step of any seismic soil-structure study. Geotechnical earthquake engineers and engineering geologist have been trying to find both practical and most appropriate solution techniques for ground response analysis under earthquake loadings. The paper attempts to give a critical overview of the field of site response analysis. In this paper, the influences of nonlinearity on the site response analysis summarized and were evaluated with a numerical example. Site response of a two layered soil deposit with the assumption of linear and rigid base bedrock (or viscoelastic half-space) was analyzed by using linear and nonlinear approaches. The amplification spectrum of the soil column is computed between the top and the bottom of this soil deposit. Nonlinear analysis was compared with the linear method of analysis. Steps involved in ground response analyses to develop site-specific response spectra at a soil site are briefly summarized. Some of the well-known site response analysis methods are summarized and similarities and differences between linear and nonlinear methods are compared by a numerical example.