Cation sorption on the muscovite (0 0 1) surface in chloride solutions using high-resolution X-ray reflectivity

The structure and mechanism of cation sorption at the (0 0 1) muscovite-water interface were investigated in 0.01 and 0.5 m KCl, CsCl, and CaCl₂ and 0.01 m BaCl₂ solutions at slightly acidic pH by high-resolution X-ray reflectivity. Structural relaxations of atom positions in the 2M₁ muscovite were small (?0.07 Å) and occurred over a distance of 30 to 40 Å perpendicular to the interface. Cations in all solutions were sorbed dominantly in the first and second solution layers adjacent to the mineral surface. The derived heights of the first solution layer in KCl and CsCl solutions, 1.67(6)-1.77(7) and 2.15(9)-2.16(2) Å, respectively, differ in magnitude by the approximate difference in crystallographic radii between K and Cs, and correspond closely to the interlayer cation positions in bulk K- and Cs-mica structures. The first solution layer heights in CaCl₂ and BaCl₂ solutions, 2.46(5)-2.56(11) and 2.02(5) Å, respectively, differ in a sense opposite to that expected based on crystallographic or hydrated radii of the divalent cations. The derived ion heights in all solutions imply that there is no intercalated water layer between the first solution layer and the muscovite surface. Molecular compositions were assigned to the first two solution layers in the electron density profiles using models that constrain the number density of sorbed cations, water molecules, and anions by considering the permanent negative charge of the muscovite and average solution density. The models result in partial charge balance (at least 50%) by cations sorbed in the first two layers in the 0.01 m solutions and approximately full charge balance in the 0.5 m solutions. Damped oscillations of model water density away from the first two solution layers agree with previous X-ray reflectivity results on the muscovite (0 0 1) surface in pure water.     

Intrusion-related Gold Deposits in Egypt

Intrusion-related gold deposits(IRGDs) occur in the Eastern Desert(ED) of Egypt within magmatic districts that are exploited for tungsten and tin mineralization. IRGDs and intrusion-related rare metal deposits(IRRMDs) are almost invariably linked with the late to post collisional Younger Granites(YGs) that have three successive phases(I, II and III). At ～635–630 Ma, the ED underwent a transition in deformation style from compressional to extensional and a switch from subduction with crustal thickening to delamination with crustal thinning. This transition was concurrent with the emplacement of a short magmatic pulse(～635–630 Ma) that represents a transition between orogenic gold deposits and IRGDs. K-rich calc alkaline granites(phase I and II of the YGs) hosting IRGDs like the Hangalia deposit were emplaced during the time span 630–610 Ma. Alkaline magmatism began at 610 Ma, coexisting with the K-rich calc-alkaline magmatism over the 610–590 Ma time span, where the Fawakhir(598 ± 3 Ma) and Um Had(596 ± 2 Ma) granites that host the IRGDs were emplaced. In time, the alkaline magmatism became more alkaline giving rise to phase III of the YGs that hosts IRRMDs. A distinct metallogenic epoch comprising both IRGDs and IRRMDs, was undergoing extreme growth at ～600 Ma.     

Biogeochemistry of trace metals (Mn, Sr, Rb, Ba, Cu, Zn, Pb and Cd) in a river-wetland-lake system (Balaton Region, Hungary)

Mn, Sr, Ba, Rb, Cu, Zn, Pb and Cd concentrations have been measured seasonally in the water and deposited sediments of the system comprising: Zala river (main input) — Lakes Kis-Balaton 1 and 2 (small artificial lakes created in a former bay of Lake Balaton) — Keszthely bay (hypertrophic part of Lake Balaton). The concentrations of the trace elements together with pH, alkalinity, dissolved cations (Ca²⁺, Mg²⁺, Na⁺, and K⁺), dissolved inorganic ligands (Cl^–, SO₄ ^2–), particulate Al, Ca, inorganic and organic carbon are used to assess the contamination of the study area and biogeochemical processes controlling trace element concentrations. Thermodynamic speciation calculations have also been utilized to enhance our understanding of the system. In the sediments Rb, Ba, Cu and Zn concentrations were mainly controlled by the abundance of the aluminosilicate fraction. Strontium was mainly associated with the calcium carbonate fraction. The aluminosilicate fraction constitutes a major sink for Mn and Cd but the concentration of these elements are also strongly related to calcite precipitation. The main processes that control the dissolved distribution of trace elements in the Balaton system were: solid phase formation (carbonate) for Mn; coprecipitation with calcite for Sr, Ba, Rb and possibly Mn and Cd; adsorption/desorption processes (pH dependent) for Zn and Pb; solubilization of Mn and precipitation of Cd and Cu in reed covered wetland areas where anoxic conditions were probably existing during the warm season. A preliminary budget of atmospheric and river input to Lake Balaton has also been outlined. Although Lake Balaton, is subjected to anthropogenic inputs mainly from agricultural and domestic activities, their impact on trace element concentrations in the Balaton system is very limited due to the efficiency of removal processes (i.e. adsorption and co-precipitation) and to high sedimentation rates and strong sediment re-suspension. Anthropogenic inputs are only detected for Pb.     

Four‐colour photometry of EY Dra: A study of an ultra‐fast rotating active dM1‐2e star

We present more than 1000‐day long photometry of EY Draconis in BV (RI)_C passbands. The changes in the light curve are caused by the spottedness of the rotating surface. Modelling of the spotted surface shows that there are two large active regions present on the star on the opposite hemispheres. The evolution of the surface patterns suggests a flip‐flop phenomenon. Using Fourier analysis, we detect a rotation period of P_rot = 0.45875 d, and an activity cycle with P ≈ 350 d, similar to the 11‐year long cycle of the Sun. This cycle with its year‐long period is the shortest one ever detected on active stars. Two bright flares are also detected and analysed (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Vertical crustal motions from differential tide gauge observations and satellite altimetry in southern Italy

Our goal is to determine vertical crustal movement rates from tide gauge and satellite altimetry measurements. Tide gauges measure sea level, but as they are fixed to the crust, they sense both sea surface height variations and vertical crustal movements. The differential sea level rates of sufficiently nearby stations are a good means to determine differential crustal movement rates, when sea level height variations can be assumed to be homogeneous. Satellite altimetric measurements determine sea surface height variations directly and can be used to separate the crustal signal from the sea surface height variations in tide gauge measurements. The correction of the tide gauge sea level rates for the sea surface height contribution requires collocation of the satellite pass and the tide gauge station. We show that even if this is not the case, the satellite altimetric observations enable correction of differential tide gauge rates for the effects of sea surface rate inhomogeneities.     

Hydrothermal origin of hexagonal CaAl2Si2O8 (dmisteinbergite) in a compact type A CAI from the Northwest Africa 2086 CV3 chondrite

We report an occurrence of hexagonal CaAl₂Si₂O₈ (dmisteinbergite) in a compact type A calcium‐aluminum‐rich inclusion (CAI) from the CV3 (Vigarano‐like) carbonaceous chondrite Northwest Africa 2086. Dmisteinbergite occurs as approximately 10 μm long and few micrometer‐thick lath‐shaped crystal aggregates in altered parts of the CAI, and is associated with secondary nepheline, sodalite, Ti‐poor Al‐diopside, grossular, and Fe‐rich spinel. Spinel is the only primary CAI mineral that retained its original O‐isotope composition (Δ¹⁷O ~ ?24‰); Δ¹⁷O values of melilite, perovskite, and Al,Ti‐diopside range from ?3 to ?11‰, suggesting postcrystallization isotope exchange. Dmisteinbergite, anorthite, Ti‐poor Al‐diopside, and ferroan olivine have ¹⁶O‐poor compositions (Δ¹⁷O ~ ?3‰). We infer that dmisteinbergite, together with the other secondary minerals, formed by replacement of melilite as a result of fluid‐assisted thermal metamorphism experienced by the CV chondrite parent asteroid. Based on the textural appearance of dmisteinbergite in NWA 2086 and petrographic observations of altered CAIs from the Allende meteorite, we suggest that dmisteinbergite is a common secondary mineral in CAIs from the oxidized Allende‐like CV3 chondrites that has been previously misidentified as a secondary anorthite.     

Numerical interpretation of high-altitude photoelectron observations

The Electron Spectrometer (ELS) instrument of the ASPERA-3 package on the Mars Express satellite has recorded photoelectron energy spectra up to apoapsis (∼10,000 km altitude). The characteristic photoelectron shape of the spectrum is sometimes seen well above the ionosphere in the evening sector across a wide range of near-equatorial latitudes. Two numerical models are used to analyze the characteristics of these high-altitude photoelectrons. The first is a global, multi-species MHD code that produces a 3-D representation of the magnetic field and bulk plasma parameters around Mars. It is used here to examine the possibility of magnetic connectivity between the high-altitude flanks of the martian ionosheath and the subsolar ionosphere. It is shown that some field lines in this region are draped interplanetary magnetic lines while others are open field lines (connected to both the IMF and the crustal magnetic field sources). The second model is a kinetic electron transport model that calculates the electron velocity space distribution along a selected, non-uniform, magnetic field line. It is used here to simulate the high-altitude ELS measurements. It is shown that the photoelectrons are essentially confined to the source cone, as governed by magnetic field inhomogeneity along the field line. Reasonable agreement is shown between the data and the model results, and a method is demonstrated for inferring properties of the local and photoelectron source region magnetic field from the ELS measurements. Specifically, the number of sectors in which photoelectrons are measured is a function of the magnetic field intensity ratio and the field's angle with respect to the detector plane. In addition, the sector of the photoelectron flux peak is a function of the magnetic field azimuthal angle in the detector plane.     

Quaternary foraminifera and sediments in the Norwegian Channel

The foraminiferal fauna and lithology of 17 short sediment cores from two profiles in the Norwegian Channel have been investigated. Three ecostratigraphical zones are distinguished and their depositional environment, age and correlation with adjacent areas are discussed. The zones form a climatically conditioned succession (from below): the Cassidulina-Nonion zone contains an arctic fauna affected by meltwater influx, and its deposition was in progress in Late Weichselian; the Uvigerina-Cassidulina zone with a mixed fauna of arctic and boreal species is referred to the Early Flandrian; the Uvigerina-Bulimina zone contains a boreal fauna and was deposited under influence of Atlantic water; its age is regarded as Middle and Late Flandrian. Transport and deposition of sediments in the channel is discussed on the basis of recent current conditions and distribution of the zones.     

Foraminiferal morphogroups in dysoxic shelf deposits from the Jurassic of Spitsbergen

Analysis of benthic foraminiferal assemblages was performed in Bathonian to Kimmeridgian deposits through a section covering the lower half of the Agardhfjellet Formation in central Spitsbergen. The section consists mainly of organic-rich shales, which contain low-diversity agglutinated assemblages. In this foraminiferal succession five morphogroups were differentiated according to shell architecture (general shape, mode of coiling and number of chambers), integrated with the supposed microhabitat (epifaunal, shallow infaunal and deep infaunal) and feeding strategy (suspension-feeder, herbivore, bacterivore, etc.). The environmental evolution of the analysed section is interpreted by using the stratigraphic distribution of morphogroups, combined with species diversities and sedimentary data, in a sequence stratigraphic framework. The section comprises two depositional sequences, which demonstrate that species diversity and relative frequency of morphogroups are correlative with transgressive–regressive trends controlling depth and oxygenation of the water column. In both sequences, the maximum flooding interval is characterized by increased organic carbon content, dominance of the epifaunal morphogroups and reduced species diversity: features reflecting the increased degree of stagnation separating the transgressive phase from the regressive phase.