Heat wave risk assessment and mapping in urban areas: case study for a midsized Central European city,Novi Sad (Serbia)

Risk assessment and mapping methodologies for heat waves as frequently occurring hazards in central and southeastern Europe were applied in this study, and the impact of heat waves on the mortality of urban populations was determined as part of the assessment. The methodology for conducting the heat wave risk assessment is based on European Commission’s Guidelines for Risk Assessment and Mapping. The Novi Sad (Serbia) urban area was studied during summer 2015, which was one of the hottest summers in the last few decades. In situ air temperature measurements from urban stations and mortality of urban populations were used. Nocturnal urban heat island (UHI) intensity values between the various built-up zones and natural surrounding areas were used for the hazard level calculation. Temperature data from 9 p.m. to 5 a.m. were used because during the night, the UHI intensity reached its maximum values. The average daily number of deaths by LCZs was used to define the impact level of the vulnerability index. Calculations for both hazard levels were completed during two intensive heat waves (in July and August 2015) when it was expected that there may be a high level of risk. The results and maps show that the urban area is complex, and the heat wave risk on the population is not uniform. The most densely built-up areas (LCZs 2, 5 and 6) have very high or high risk values that are influenced by a higher rate of mortality. The obtained results and maps can be used by local authorities to prevent and mitigate climate-related hazards, for medical institutions as well as urban planners and for ancillary local, regional or national services. According to these results, the local authorities could define hot spots where they can place medical and rescue teams and install points with water supplies, etc.     

Growth and urban differentiation on the urban periphery: A case study from Szeged, Hungary

In late nineteenth century Hungarian cities there were strong contrasts between the inner ‘urban’ core and the rural periphery in terms of housing conditions, accessibility and lifestyle. Rural-urban fringe zones in the Great Plain were quite distinctive because the Turkish period was followed by an outflow of population which resulted in scattered settlement around the urban centres. The fringe could be regarded simply as a zone of transition, but the differences between urban centres and their immediate surroundings were gradually reduced through the industrialisation of the larger towns in the communist period. A study of Szeged examines the expansion of the fringe zone and its gradual urbanisation through the growth of housing as people have moved out from the centre to live among the rural population which increasingly turned from agriculture to commuting. Villages on either side of Szeged's administrative boundary accommodated more migrants from the city during the 1980s and experienced a gradual positive change in the quality of life as people escaped from the decaying residential blocs in the centre. During the years since 1989 there has been further migration, coupled with a growth of small businesses and a big improvement in services (shopping, running water, sewage and telecommunications). Further change may be expected in line with the forces of counterurbanisation. This revised version was published online in July 2006 with corrections to the Cover Date.     

The role of relative ion flows on the thermal structure of the ionosphere

Calculations are presented which show that, contrary to previous suggestions, ion flow velocity differences do not have a significant effect on the thermal structure of the midlatitude topside ionosphere.     

FTIR characterization of amorphous uranyl-silicates

Ambient-temperature environments in which dissolved silica and U(VI) are present may lack the conditions necessary to readily form crystalline uranyl-silicate phases; however amorphous phases, as defined by the absence of well-defined Bragg reflections in powder X-ray diffraction patterns, are kinetically favored when solution saturation levels are appropriate. Such amorphous uranyl-silicates may be related to the crystalline phases predicted to be thermodynamically stable and influence the mobility of U in the environment. To investigate amorphous uranyl-silicates and their relation to crystalline phases we precipitated solids from solutions containing 0.05 M UO₂(ClO₄)₂ and 0.1 M Na₂SiO₃ adjusted to pH values from 2.2 to 9 and allowed the precipitates to age in their mother liquors for approximately 6 weeks at 22 °C. We compared the chemical composition, X-ray diffraction patterns, and Fourier transform infrared spectra of the precipitates to those of the crystalline phases predicted by thermodynamic modeling. The precipitates were amorphous with U:Si ratios of 0.8 ± 0.1. Their FTIR spectra revealed changes in the UO₂²⁺ and SiO₄⁴⁻ vibrations as a function of pH that are consistent with a shift in mid-range structural linkages from those similar to soddyite to those more like Na-boltwoodite. Structural H₂O, OH, and SiO₃OH³⁻ vibrations do not change as a function of pH and are consistent with a mixture of soddyite-like and Na-boltwoodite-like features. Six weeks of aging at ambient temperature is enough time for the precipitate structures to rearrange and adopt mid-range structural linkages characteristic of crystalline phases predicted by thermodynamic modeling.     

Carbonate xenoliths in La Palma: Carbonatite or alteration product?

Carbonate xenoliths containing olivine and rimmed by kaersutitic amphibole were collected in basaltic rocks of the Basal Complex of La Palma. The mineralogical composition and microscopic appearance may suggest a relationship with carbonatites in general, thus a major element, trace element and stable isotope study was conducted to investigate the origin of the carbonate formation. Based on electron microprobe analyses, the carbonate is calcite with up to 6.3 wt% MgO and 7.2 wt% SiO₂. The elevated SiO₂ content may suggest a melt origin for the carbonate. However, the C and O isotope compositions of the carbonate xenoliths (δ¹³C and δ¹⁸O around −1‰ and 13‰, respectively) are similar to those of calcite veins and amygdales in basaltic rocks of the Basal Complexes of La Palma and Fuerteventura and are interpreted as produced by fluid degassing and metasomatism by CO₂-H₂O fluid derived from mobilization of sedimentary material. Trace element contents determined by laser-ablation ICP-MS analyses support the assumed origin, thus, the relationship with carbonatitic melts can be excluded. Based on trace element compositions, the amphibole surrounding the xenoliths is not related genetically to the carbonate. The elevated SiO₂ content of the calcite can be attributed to submicron relics of pyroxene, thus, the use of this feature as an evidence for melt origin is questionable.     

Secondary resonances of co-orbital motions

The size distribution of the stability region around the Lagrangian point L ₄ is investigated in the elliptic restricted three-body problem as the function of the mass parameter and the orbital eccentricity of the primaries. It is shown that there are minimum zones in the size distribution of the stability regions, and these zones are connected with the secondary resonances between the frequencies of librational motions around L ₄. The results can be applied to hypothetical Trojan planets for predicting values of the mass parameter and the eccentricity for which such objects can be expected or their existence is less probable.     

Cathodoluminescence microscopy and spectroscopy of forsterite from Kaba meteorite: An application to the study of hydrothermal alteration of parent body

Highly forsteritic olivine (Fo: 99.2–99.7) in the Kaba meteorite emits bright cathodoluminescence (CL). CL spectra of red luminescent forsterite grains have two broad emission bands at approximately 630 nm (impurity center of divalent Mn ions) in the red region and above 700 nm (trivalent Cr ions) in the red–IR region. The cores of the grains show CL blue luminescence giving a characteristic broad band emission at 400 nm, also associated with minor red emissions related to Mn and Cr ions. CL color variation of Kaba forsterite is attributed to structural defects. Electron probe microanalyzer (EPMA) analysis shows concentrations of Ca, Al, and Ti in the center of the forsterite grain. The migration of diffusible ions of Mn, Cr, and Fe to the rim of the Kaba meteoritic forsterite was controlled by the hydrothermal alteration at relatively low temperature (estimated at about 250 °C), while Ca and Al ions might still lie in the core. A very unusual phase of FeO (wüstite) was also observed, which may be a terrestrial alteration product of FeNi‐metal.     

OSL-dating the Quaternary landscape evolution in the Vértes Hills forelands (Hungary)

Fluvial, colluvial, and aeolian sediments were dated by optically stimulated luminescence (OSL) on quartz to improve the chronological framework for Quaternary sedimentation and landscape evolution in the forelands of the Vértes Hills (central Hungary). The separated quartz was suitable for age determination based on an OSL SAR protocol. Most samples have asymmetric equivalent dose distributions and OSL ages were calculated by the mean, central, and minimum D_e values. Considering geomorphology and earlier age data from the area, the central D_e values seem most appropriate for age calculation. A fan on the geomorphological level QV in the western foreland of the Vértes Hills was deposited 79–75 (±8) ka ago. In the south-eastern foreland an alluvial fan on level QIIb is at most 42 ± 4 ka old. Fluvial incision and aggradation occurred 16–10 (±1) ka ago on the geomorphic surface QIIa. Loess is 14 ± 1 ka old, and slope sedimentation was active 11–9 (±1) ka ago. Our OSL data demonstrate that in the north-western foreland of the Vértes Hills wind remained an important agent after the last glacial times, into the early Holocene (9–8 ± 1 ka) and was able to accumulate large aeolian dunes.     

Regional studies of dolomites and their included fluids: recognizing multiple chemically distinct fluids during the complex diagenetic history of Lower Carboniferous (Mississippian) rocks of the Irish Zn-Pb ore field

This study provides a regional framework within which studies of ore-related dolomite and dolomite cements may be placed. Fluid inclusion data indicate the presence of three distinct fluids following early dolomitization: 1) a ubiquitous low-temperature, higher salinity fluid found in saddle dolomite; 2) a low-temperature, lower salinity fluid limited to sub-Waulsortian and Waulsortian carbonates; and 3) a higher temperature, lower salinity fluid found in Waulsortian and supra-Waulsortian rocks. Similar fluids have been reported in ore-associated minerals and postmineralization dolomite (Type 1) and in ore-stage carbonates and sphalerite (Types 2 and 3). The halogen geochemistry of included fluids indicates genesis from evaporated seawater. Type 1 fluids are enriched in chloride relative to bromide, reflecting a component of salinity derived via dissolution of halite or from dehydration of seawater. These data suggest that dolomitization and mineralization of Mississippian rocks in the Midlands requires both regionally extensive and localized fluid flow.