Lu-Hf garnet geochronology of eclogites from the Balma Unit (Pennine Alps): implications for Alpine paleotectonic reconstructions

Three samples of eclogite from the Balma Unit, an ophiolite sheet on top of the Monte Rosa Nappe in the Pennine Alps, were investigated in terms of their P-T evolution, geochemistry, and Lu-Hf geochronology. The paleogeographic origin of this unit is controversial (North Penninic vs. South Penninic). It has been interpreted as a piece of Late Cretaceous oceanic crust, on the basis of ca. 93 Ma U-Pb SHRIMP ages of synmagmatic zircon cores in an eclogite. Trace element and isotope data suggest a mid ocean ridge (MOR) rather than an intraplate or OIB setting for the protoliths of the eclogites. Electron microprobe analyses of representative garnets show typical prograde zoning profiles. Estimated peak metamorphic temperatures of 550–600 Cº most likely did not exceed the closure temperature of the Lu-Hf system. Hence, Lu-Hf ages most likely reflect garnet growth in the studied samples. To minimize inclusion effects on age determinations, a selective digestion procedure for garnet was applied, in which zircon and rutile inclusions are not dissolved. The ages obtained for three samples, 42.3 ± 0.6 Ma (MSWD: 0.47), 42 ± 1 Ma (MSWD: 3.0) and 45.5 ± 0.3 Ma (MSWD: 0.33), are younger than all Lu-Hf ages reported so far for South Penninic Units. Metamorphic zircon domains of the 42.3 Ma sample (PIS1) were previously dated by U-Pb SHRIMP at 40.4 ± 0.7 Ma, indicating that the growth of metamorphic zircon post-dated the onset of garnet growth.These new data put important constraints on the paleogeographic reconstruction of the Alps. The MORB character of the rocks, together with their previously published protolith age, imply that oceanic spreading was still taking place in the Late Cretaceous. This supports a North Penninic origin for our samples because plate tectonic models predict Cretaceous spreading in the North Penninic but not in the South Penninic Ocean. If the Balma Unit is indeed North Penninic, the new Lu-Hf data, in combination with published geochronological data, require that two independent subduction zones consumed the South and North Penninic oceans.     

Zur Stabilitätstheorie des geostrophischen Windes

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Impacts of Coastal Land Use and Shoreline Armoring on Estuarine Ecosystems: an Introduction to a Special Issue

The nearshore land-water interface is an important ecological zone that faces anthropogenic pressure from development in coastal regions throughout the world. Coastal waters and estuaries like Chesapeake Bay receive and process land discharges loaded with anthropogenic nutrients and other pollutants that cause eutrophication, hypoxia, and other damage to shallow-water ecosystems. In addition, shorelines are increasingly armored with bulkhead (seawall), riprap, and other structures to protect human infrastructure against the threats of sea-level rise, storm surge, and erosion. Armoring can further influence estuarine and nearshore marine ecosystem functions by degrading water quality, spreading invasive species, and destroying ecologically valuable habitat. These detrimental effects on ecosystem function have ramifications for ecologically and economically important flora and fauna. This special issue of Estuaries and Coasts explores the interacting effects of coastal land use and shoreline armoring on estuarine and coastal marine ecosystems. The majority of papers focus on the Chesapeake Bay region, USA, where 50 major tributaries and an extensive watershed (~ 167,000 km²), provide an ideal model to examine the impacts of human activities at scales ranging from the local shoreline to the entire watershed. The papers consider the influence of watershed land use and natural versus armored shorelines on ecosystem properties and processes as well as on key natural resources.     

Error-controlled implicit time integration of elasto-visco-plastic constitutive models for rock salt

The mechanical behavior of rock salt is rate-dependent at different time scales. Using caverns in rock salt formations for renewable energy storage implies that the underground structures are subjected to both short-term and long-term loads, increasing robustness and flexibility requirements for numerical simulators used to assess the safety of such structures. So far, explicit time integration with model-specific heuristics for time-step size determination dominate in application studies. In this paper, the suitability of error-controlled adaptive time-integration schemes of the diagonally implicit Runge-Kutta type is investigated in comparison with the Backward Euler and Crank-Nicolson schemes when applied to the integration of typical elasto-visco-plastic constitutive models of rock salt. The comparison is made both for monotonic and for cyclic loads as well as taking account of thermo-mechanical coupling. Analyses of the time-integration errors and the time step-size evolution show the suitability of the integration scheme for these material models. The automatic adjustment of the time-step size was found to be robust across all material models and boundary conditions as well as for non-isothermal situations for a single algorithmic parameter set.     

A comparison of coincident GRACE and ICESat data over Antarctica

In this study, we present a comparison of coincident GRACE and ICESat data over Antarctica. The analysis focused on the secular changes over a 4-year period spanning from 2003 to 2007, using the recently reprocessed and publicly available data sets for both missions. The results show that the two independent data sets possess strong spatial correlations, but that there are several factors that can significantly impact the total derived ice mass variability from both missions. For GRACE, the primary source of uncertainty comes from the modelling of glacial isostatic adjustment, along with the estimates of C _2,0 and the degree one terms. For ICESat, it is shown that assumptions about firn density, rate biases, and the sampling interval of the various laser campaigns can have large effects on the results. Despite these uncertainties, the similarities that do exist indicate a strong potential for the future refinement of both GIA and mass balance estimates of Antarctica.     

Use of the Spectrometric Sum Parameter for Aromatic Amines in the Monitoring of a Former Ammunition Plant

Aromatic amines are important metabolites of nitroaromatic explosives, hence monitoring of aromatic amines’ content at former ammunition plants is necessary. Twenty years ago, a threshold limit value of 0.1 μg/L for the sum of diazotizable aromatic amines in water distributed from the waterworks at the former ammunition plant in Stadtallendorf/Hesse was established. This value is still measured with a spectrometric sum parameter, in which diazotization and a subsequent azo coupling of the analytes are utilized. The sum parameter is well suited for the long‐term monitoring of filter installations, and it allows very quick measurements and a non‐target screening of aniline contents, both of which are important in research. Nevertheless, as several problems are associated with this parameter, we developed analytical methods suitable for the determination of the most important single compounds contributing to the overall sum. Initial results of these methods show that amphoteric anilines are of considerable importance in ammunition waste but have been neglected up to now in official monitoring schemes. The summation of single compound contents in ammunition wastewater generally gives 3 to 6 times higher values than the spectrometrically determined sum, which is mainly due to the choice of the reference substance 4‐nitroaniline in the sum parameter.     

Coupled Numerical Evaluations of the Geomechanical Interactions Between a Hydraulic Fracture Stimulation and a Natural Fracture System in Shale Formations

Due to the low permeability of many shale reservoirs, multi-stage hydraulic fracturing in horizontal wells is used to increase the productive, stimulated reservoir volume. However, each created hydraulic fracture alters the stress field around it, and subsequent fractures are affected by the stress field from previous fractures. The results of a numerical evaluation of the effect of stress field changes (stress shadowing), as a function of natural fracture and geomechanical properties, are presented, including a detailed evaluation of natural fracture shear failure (and, by analogy, the generated microseismicity) due to a created hydraulic fracture. The numerical simulations were performed using continuum and discrete element modeling approaches in both mechanical-only and fully coupled, hydro-mechanical modes. The results show the critical impacts that the stress field changes from a created hydraulic fracture have on the shear of the natural fracture system, which in-turn, significantly affects the success of the hydraulic fracture stimulation. Furthermore, the results provide important insight into: the role of completion design (stage spacing) and operational parameters (rate, viscosity, etc.) on the possibility of enhancing the stimulation of the natural fracture network (‘complexity’); the mechanisms that generate the microseismicity that occurs during a hydraulic fracture stimulation; and the interpretation of the generated microseismicity in relation to the volume of stimulated reservoir formation.