Development of a surrogate model and sensitivity analysis for spatio-temporal numerical simulators

Stochastic Environmental Research and Risk Assessment - To evaluate the consequences on human health of radionuclide releases in the environment, numerical simulators are used to model the...     

Glutamic Acid Modified Fenton System for Degradation of BTEX Contamination

The present study employed a modified Fenton system that aims to extend the optimum pH range towards neutral conditions for studying the oxidation of benzene, toluene, ethyl benzene, xylenes (BTEX) using glutamic acid (Glu) as an iron chelator. Addition of 20 mM Glu greatly enhanced the oxidation rate of BTEX in modified Fenton system at pH 5–7. A rapid mass destruction (>97% after 1 h) of BTEX as a water contaminant carried out in the presence of 500 mM H₂O₂, 10 mM Fe²⁺, and 20 mM Glu at pH 5 could be shown. The efficiency of this modified Fenton's system for mass destruction of BTEX in contaminated water was measured to estimate the impact of the major process variables that include initial concentrations of soluble Fe, H₂O₂, Glu (as metal chelating agent), and reaction time.     

Multi-nest high-resolution model of submesoscale circulation features in the Gulf of Taranto

Recent oceanographic field measurements and high-resolution numerical modelling studies have revealed intense, transient, submesoscale motions characterised by a horizontal length scale of 100–10,000 m. This submesoscale activity increases in the fall and winter when the mixed layer (ML) depth is at its maximum. In this study, the submesoscale motions associated with a large-scale anticyclonic gyre in the central Gulf of Taranto were examined using realistic submesoscale-permitting simulations. We used realistic flow field initial conditions and multiple nesting techniques to perform realistic simulations, with very-high horizontal resolutions (> 200 m) in areas with submesoscale variability. Multiple downscaling was used to increase resolution in areas where instability was active enough to develop multi-scale interactions and produce 5-km-diameter eddies. To generate a submesoscale eddy, a 200-m resolution was required. The submesoscale eddy was formed through small-scale baroclinic instability in the rim of a large-scale anticyclonic gyre leading to large vertical velocities and rapid restratification of the ML in a time-scale of days. The submesoscale eddy was confirmed by observational data from the area and we can say that for the first time we have a proof that the model reproduces a realistic submesoscale vortex, similar in shape and location to the observed one.     

Smart Cartographic Background Symbolization for Map Mashups in Geoportals: A Proof of Concept by Example of Landuse Representation

Geospatial data are now widely available to the general public thanks to geoportals and online mapping platforms. However, creating a map involves more than just combining data layers. Thus we develop cartographic functions for geoportals to support better visual hierarchy in user map mashups. This includes a couple of preparatory steps followed by a smart cartographic background symbolization derived from the original layer style. We evaluate different approaches to background symbolization: greyscale, desaturation, and smart background. The different background symbolization methods are analysed with two concrete map examples and evaluated with a survey. The smart background symbolization developed in this work improves the visual hierarchy of the map mashup by reducing the visual importance of the background layers.     

Simulating sub-daily hydrological process with SWAT: a review

ABSTRACT

The Soil and Water Assessment Tool (SWAT) is a watershed-scale hydrologic model that integrates water quantity and quality modules. Despite the large amount of knowledge on the SWAT model, specific understanding of sub-daily applications remains limited. In this review, we identify the shortcomings and possible ways forward in simulating sub-daily processes with the model. A literature review was conducted, along with a participatory method based on a questionnaire. We reviewed 28 scientific articles and categorized them into: (i) model development, (ii) streamflow methods comparison, (iii) water quality, and (iv) other applications. We found that using sub-daily data improves hydrograph peak simulation, while for medium flows use of daily data was better. From all the reviewed studies, a 1-hour time step was the most suitable time scale for the sub-daily model application. The participatory questionnaire confirmed the hypothesis that the main challenge for using the sub-daily routine was the lack of high-resolution data.     

Noble gases in chondrules and associated metal‐sulfide‐rich samples: Clues on chondrule formation and the behavior of noble gas carrier phases

Abstract— Chondrules are generally believed to have lost most or all of their trapped noble gases during their formation. We tested this assumption by measuring He, Ne, and Ar in chondrules of the carbonaceous chondrites Allende (CV3), Leoville (CV3), Renazzo (CR2), and the ordinary chondrites Semarkona (LL3.0), Bishunpur (LL3.1), and Krymka (LL3.1). Additionally, metalsulfide‐rich chondrule coatings were measured that probably formed from chondrule metal. Low primordial ²⁰Ne concentrations are present in some chondrules, while even most of them contain small amounts of primordial ³⁶Ar. Our preferred interpretation is that‐in contrast to CAIs‐the heating of the chondrule precursor during chondrule formation was not intense enough to expel primordial noble gases quantitatively. Those chondrules containing both primordial ²⁰Ne and ³⁶Ar show low presolar‐diamond‐like ³⁶Ar/²⁰Ne ratios. In contrast, the metal‐sulfide‐rich coatings generally show higher gas concentrations and Q‐like ³⁶Ar/²⁰Ne ratios. We propose that during metalsilicate fractionation in the course of chondrule formation, the Ar‐carrying phase Q became enriched in the metal‐sulfide‐rich chondrule coatings. In the silicate chondrule interior, only the most stable Ne‐carrying presolar diamonds survived the melting event leading to the low observed ³⁶Ar/²⁰Ne ratios. The chondrules studied here do not show evidence for substantial amounts of fractionated solar‐type noble gases from a strong solar wind irradiation of the chondrule precursor material as postulated by others for the chondrules of an enstatite chondrite.     

Thermal expansion and dehydroxylation of phengite micas

Phengite samples (2M ₁ and 3T politypes) and a synthetic end-member muscovite specimen were studied by in situ high-temperature synchrotron radiation X-ray diffraction. The measured volume thermal expansion of 2M ₁ phengite (<α _V> ≈ 36.6 × 10⁻⁶ K⁻¹) was systematically greater than <α _V> of the 3T polytype (≈33.3 × 10⁻⁶ K⁻¹). A positive linear correlation between the average thermal expansion on (001) plane and the mean tetrahedral rotation angle at ambient condition is proposed on the ground of new measurements and literature data. Dehydroxylation processes were observed in 2M ₁, starting at 1,000 K in 3T at 800 and 945 K in synthetic muscovite. Rietveld refinements allowed a determination of structural variations upon heating of phengite samples and their dehydroxylate phases. The phengite structure expands by regularizing the tetrahedral sheet and by reducing the bond length differences between the outer and inner coordination shell of the interlayer site. The dehydroxylate phase derived from 2M ₁ is characterized by fivefold polyhedra in the low temperature form as a consequence of two OH groups reacting to form H₂O + O (residual). The dehydroxylate exhibits an increase of the cation–cation distances along the M–Or–M bonds with respect to low-temperature phengite structures. For the 3T phase, we were unable to achieve completion of dehydroxylation. The refined structural model of the dehydroxylate phase shows two hydroxyl sites, but at a short distance from one another. This result suggests that the dehydroxylation reaction did not proceed to completion. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Flow units delineation of multiple hydrocarbon reservoirs using hydraulic zonation technique via cluster analysis algorithm,Zeit Bay Field,Gulf of Suez,Egypt

Investigation of hydraulic units in drilled wells through multiple reservoirs in Zeit Bay Field is the main target of this paper. Karim Limestone and Nubian Sandstone are target reservoirs in this study. Hydraulic zones provide a fundamental unit for subsequent reservoir characterization and simulation and also prove to be helpful in defining future well completion and work over practices. Hydraulic zonation by means of cluster analysis has been utilized to achieve this target. Hierarchical cluster analysis, elbow method, and k-means clustering are the main steps of this analysis. Petrophysical properties obtained from cores are utilized to perform this zonation. These properties are permeability and porosity data. Results have been validated by comparing the geological behavior of each zone against the measured permeability curve. Finally through this zonation, flow units which have the potential to extract fluids are determined more accurately. Petroleum geologists and engineers are more interested in these results. The cluster analysis flow suggesting in this paper is cost-effective due to lack of need for any commercial software.