Physical chemical analysis of marine sediment cementation from the Gulf of Guinea

This study aims at investigating the cementation of marine sediments from the Gulf of Guinea by using physicochemical analysis. In order to highlight the presence of cementation in the sediments, three conventional consolidation tests were conducted on intact and remoulded samples. Mercury intrusion porosimetry analyses were then carried out on the specimens taken from samples after consolidation tests. Several physicochemical experimental techniques were used to analyze these cementations, such as cation exchange capacity analysis, batch test, scanning electron microscope imaging coupled with EDS chemical analysis, and thermal analysis. The results seem to indicate that the cementation of these sediments is predominated by the presence of smectite gel between clay aggregates (clusters). Finally, a conceptual sediment microstructural model is proposed to describe the cementation.     

IT-OSRA: applying ensemble simulations to estimate the oil spill risk associated to operational and accidental oil spills

Oil Spill Risk Assessments (OSRAs) are widely employed to support decision making regarding oil spill risks. This article adapts the ISO-compliant OSRA framework developed by Sepp Neves et al. (J Environ Manag 159:158–168, 2015) to estimate risks in a complex scenario where uncertainties related to the meteo-oceanographic conditions, where and how a spill could happen exist and the risk computation methodology is not yet well established (ensemble oil spill modeling). The improved method was applied to the Algarve coast, Portugal. Over 50,000 simulations were performed in 2 ensemble experiments to estimate the risks due to operational and accidental spill scenarios associated with maritime traffic. The level of risk was found to be important for both types of scenarios, with significant seasonal variations due to the the currents and waves variability. Higher frequency variability in the meteo-oceanographic variables were also found to contribute to the level of risk. The ensemble results show that the distribution of oil concentrations found on the coast is not Gaussian, opening up new fields of research on how to deal with oil spill risks and related uncertainties.     

A relocatable ocean model in support of environmental emergencies

During the Costa Concordia emergency case, regional, subregional, and relocatable ocean models have been used together with the oil spill model, MEDSLIK-II, to provide ocean currents forecasts, possible oil spill scenarios, and drifters trajectories simulations. The models results together with the evaluation of their performances are presented in this paper. In particular, we focused this work on the implementation of the Interactive Relocatable Nested Ocean Model (IRENOM), based on the Harvard Ocean Prediction System (HOPS), for the Costa Concordia emergency and on its validation using drifters released in the area of the accident. It is shown that thanks to the capability of improving easily and quickly its configuration, the IRENOM results are of greater accuracy than the results achieved using regional or subregional model products. The model topography, and to the initialization procedures, and the horizontal resolution are the key model settings to be configured. Furthermore, the IRENOM currents and the MEDSLIK-II simulated trajectories showed to be sensitive to the spatial resolution of the meteorological fields used, providing higher prediction skills with higher resolution wind forcing.     

Experimental investigation of microstructural changes in soils eroded by suffusion using X-ray tomography

Internal erosion is a complex phenomenon which represents one of the main risks to the safety of earthen hydraulic structures such as embankment dams, dikes or levees. Its occurrence may cause instability and failure of these structures with consequences that can be dramatic. The specific mode of erosion by suffusion is the one characterized by seepage flow-induced erosion, and the subsequent migration of the finest soil particles through the surrounding soil matrix mostly constituted of large grains. Such a phenomenon can lead to a modification of the initial microstructure and, hence, to a change in the physical, hydraulic and mechanical properties of the soil. A direct comparison of the mechanical behaviour of soil before and after erosion is often used to investigate the impact of internal erosion on soil strength (shear strength at peak and critical state) using triaxial tests. However, the obtained results are somehow contradictory, as for instance in Chang’s study (Chang and Zhang in Geotech Test J 34(6):579–589, 2011), where it is concluded that the drained strength of eroded soil decreases compared to non-eroded soil, while both Xiao and Shwiyhat (Geotech Test J 35(6):890–900, 2012) and Ke and Takahashi (Geotech Test J 37(2):347–364, 2014) have come to the opposite conclusion. A plausible explanation of these contradictions might be attributed to the rather heterogeneous nature of the suffusion process and to the way the coarse and fine grains are rearranged afterwards leading to a heterogeneous soil structure, a point that, for now, is not taken into account, nor even mentioned, in the existing analyses. In the present study, X-ray computed tomography (X-ray CT) is used to follow the microstructure evolution of a granular soil during a suffusion test, and, therefore, to capture the induced microstructural changes. The images obtained from X-ray CT reveal indeed that fine particles erosion is obviously not homogeneous, highlighting the existence of preferential flow paths that lead to a heterogeneous sample in terms of fine particles, void ratio and inter-granular void ratio distribution.

     

Impact of data assimilation of glider observations in the Ionian Sea (Eastern Mediterranean)

Glider observations of temperature, salinity and vertically averaged velocity in the Ionian Sea (Eastern Mediterranean Sea), made in the period October 2004–December 2004, were assimilated into an operational forecasting model together with other in situ and satellite observations. The study area has a high spatial and temporal variability of near surface dynamics, characterized by the entrance of the Atlantic Ionian Stream (AIS) into the Northern Ionian Sea. The impact of glider observations on the estimation of the circulation is studied, and it is found that their assimilation locally improves the prediction of temperature, salinity, velocity and surface elevation fields. However, only the assimilation of temperature and salinity together with the vertically averaged velocity improves the forecast of all observed parameters. It is also found that glider observations rapidly impact the analyses even remotely, and the remote impacts on the analyses remain several months after the presence of the glider. The study emphasizes the importance of assimilating as much as possible all available information from gliders, especially in dynamically complex areas.     

Nature, distribution and origin of polycyclic aromatic hydrocarbons (PAHs) in the sediments of Olbia harbor (Northern Sardinia, Italy)

The nature, origin and distribution of US EPA polycyclic aromatic hydrocarbons (PAHs) in the sediments of Olbia harbor (North Sardinia, Italy) were investigated by gas-chromatography/mass spectrometry (GCMS). PAH concentrations in the sediments (SigmaPAHs) ranged from 0.16 to 0.77 microg g(-1), indicating a homogeneously low level of pollution. A rather exceptional prevalence of low molecular weight PAHs was substantiated: nearly 80% of SigmaPAHs include naphthalene (15.19%) and phenanthrene (64.47%). Carcinogenic compounds were present in very low (BaP, BkF, BaA and DBA) or negligible (BbF and Inp) concentrations. As indicated by the Phen/Ant molar ratio, the main source of PAHs is petrogenic, probably due to oil spills from shipping. The low/high molecular weight ratio (ranging between 1.2 and 26) distinguishes the sediments of the tourist harbor from those of the commercial/industrial harbor. Moreover, a slight but meaningful pyrolytic contribution to pollution was found in the tourist harbor, which has the most polluted sediments in the whole harbor. Finally, good linear correlations were found between a selected PAH (Phen and Naph) and selected sums of PAHs (i.e. the total amount of the other 15 US EPA and the sum of low molecular weight PAHs).     

Collaborative geomatics and the Mushkegowuk Cree First Nations: Fostering adaptive capacity for community-based sub-arctic natural resource management

The remote First Nation (FN) communities of the Mushkegowuk Territory on the west coast of James Bay, Ontario, Canada are currently facing increased development pressures and the imposition of a government land use planning process. The land use planning process is mandated in the Far North Act (received Royal Assent on September 23, 2010). There is a need for capacity enhancement for community-based natural resource planning and management in the Territory. A number of frameworks are emerging for addressing change brought on by resource development and building resilience to such change at the community level. Among these include the concept of adaptive capacity. In collaboration with FN community leaders, we explored the use of “collaborative geomatics” tools to foster adaptive capacity. Our action research suggests that collaborative geomatics technologies should enhance the Mushkegowuk First Nations’ adaptive capacity to address environmental and policy change by allowing them to collect and manage data collaboratively (e.g., traditional environmental knowledge, western science) to create opportunities for innovative community development, including natural resource development and management.     

Opaque mineralogy and magnetic investigation of some basaltic occurrences, Sinai, Egypt

Ore microscopic investigation of the Fe?CTi oxide minerals was carried out on samples from three Oligo-Miocene basaltic occurrences from Sinai, Egypt. These occurrences are Gebel Maghara (north Sinai), Rageibet Naama (central Sinai), and Wadi Matulla (west Sinai). The results and correlations of magnetic parameters such as NRM intensity and susceptibility, coercive force H _c, and the ratio M _r/M _s, H _c and Q value, the ratio M _r/M _s, saturation magnetization M _s, and K are discussed in light of opaque mineralogical studies. It has been found that the variations in the magnetic properties of the basaltic occurrences are strongly dependent on the crystallite size and nature and style of exsolution textures and fabrics. The latter are controlled by the cooling conditions, being most sensitive to the partial pressure of oxygen in the melt.