新疆北部库尔提蛇绿岩中角闪片岩的原岩恢复及其成因

库尔提角闪片岩产于库尔提蛇绿岩南部岩片中,与斜长花岗岩呈互层产出。这套角闪片岩的不相容微量元素组分显示了大洋中脊和岛弧玄武岩的双重特征,主要表现为大离子亲石元素(LILE)富集,高场强元素(HFSE)亏损以及平坦到亏损的轻稀土(LREE)配分模式。原岩恢复的结果表明,该角闪片岩的原岩为亚碱性的拉斑玄武岩类。库尔提角闪片岩亏损的LREE、高ε_(Nd)(t),以及关键元素比值(Th/Nb,La/Yb和Th/Yb)呈正相关都表明,其源区可能以MORB地幔为主,同时还伴有少量弧组分。因此,我们认为其形成于弧后盆地环境,同时推断该区弧后盆地存在一个二阶段的熔融演化模式:第一阶段,大约在晚古生代早期,古亚洲洋向西伯利亚板块发生北向俯冲,在会聚板块边界,弧火山岩被从含水的地幔楔中提取出来,留下一个亏损地幔;第二阶段,随着古亚洲洋板块持续消减,在中-晚泥盆世形成了库尔提弧后盆地,下部的亏损地幔发生了小比例的部分熔融形成了这套角闪片岩的原岩。     

郯庐断裂带张八岭隆起南段花岗岩LA-ICP MS锆石U-Pb年龄及其构造意义

本文利用LA-ICP MS方法,对零星分布于郯庐断裂带张八岭隆起南段肥东-巢湖地区的一些花岗岩体进行了锆石U-Pb同位素年代学研究.结果表明,西徐村北岩体、尖山岩体、西花村岩体、永丰岩体和锦张村岩体的形成年龄分别为126.9 ±1.0Ma、114.8±1.3Ma、108.1 ±1.6Ma、103.0 ±0.9Ma和120.3 ±0.7Ma,这些花岗岩体均形成于早白垩世,但侵位时间有一定差异.与郯庐断裂带西侧的鲁西、徐淮、蚌埠地区同时代克拉通内部侵入岩相比,断裂带内岩浆活动持续的时间更长(～27Ma).这一结果不但指示郯庐断裂带上的岩浆活动是不均一的,各地岩浆在活动的强烈程度和时间特征上均有很大的差异,而且显示了断裂带内比克拉通内部岩浆活动结束时间较晚,暗示其下岩石圈可能有更为强烈的减薄程度和更长的减薄历史.     

海水中砷标准物质的研制

本文介绍了海水中砷标准物质的研制过程，其中包括溶液的配制、均匀性和稳定性检验，标样的分析方法。并对标准物质的定值数据进行统计处理，两种浓度的定值结果分别为：１．００μｇ／ｃｍ３±０．０４μｇ／ｃｍ３和５１．０μｇ／ｄｍ３±２．６μｇ／ｄｍ３。两种浓度砷标准物质的稳定期均为一年     

Variation of reactivity of particulate and sedimentary organic matter along the Zhujiang River Estuary

To investigate organic matter source and reactivity in the Zhujiang River (Pearl River)Estuary and its adjacent areas, particulate organic carbon (POC), particulate hydrolysable amino acids (PHAA), and Chl a during two cruises in July 1999 and July 2000 were measured. The highest POC and PHAA concentration was observed in the waters with maximum Chl a. The spectra distribution,relative content (dry weight in milligram per gram), PHAA-C% POC and other indicators such as the ratios of amino acids vs. amino sugars (AA/AS) and glucosamine vs. galactosamine (Glum/Gal) suggested that particulate amino acids in the water column and sediments in the Zhujiang River Estuary were mainly derived from biogenic processes rather than transported from terrestrial erosion. In inner estuary where high turbidity was often observable, organic matter was mainly contributed by re-suspension of bottom sediments with revealed zooplankton, microbial reworked characteristics, which suggest that these organic matters were relatively “old“. In the estuarine brackish region, organic matter in water column is mainly contributed by relatively fresh, easily degradable phytoplankton derived organic matter.During physical - biological processes within the eastuary, organic matter derived from phytoplankton was subjected to alteration by zooplankton grazing and bacterial reworking.     

The influence of 30~60 d oscillation on the development of the South China Sea summer monsoon

Using the National Center for Enviromental Prediction/National Center for Atmospheric Research (NCEP/NCAR) reanalysis data and NOAA satellite-obser ved outgoing long-wave radiation (OLR) data, the development of the South China Sea (SCS) summer monsoon and intraseasonal (30-60 d) oscillation (ISO) have been examined. The results show that there exists obvious interannual variability of intraseasonal oscillaiton. Using the 16 a time series of filtered OLR averaged over the SCS, an index is defined to define ““onset events““ over the SCS on the ISO time scales. Of the 16 a examined here, 10 shows a strong ISO signal in the onset of monsoon convection over the SCS. In these cases, the ISO initially suppresses the seasonal development of southwesterly and cyclonic circulation over the SCS before the ISO onset. As the ISO propagates northeastward, the low frequency cyclonic circulation anomaly occurs in the SCS and the low frequency southwesterly wind and convection over here dramatically intensify. The northeast progression of the ISO anomaleis plays a role in the initial suppression and then acceleration of the seasonal cycle of the SCS summer monsoon.     

Seasonal and annual variations of marine sinking particulate flux during 1993~1996 in the central South China Sea

A total of 67 samples from the upper and lower sediment traps in the central South China Sea were analyzed, which were collected during 1993~1996. It is indicated that the distribution of stable isotope values, surface primary productivity, fluxes of total particulate matter, carbonate, biogenic opal, organic carbon, planktonic foraminiferal species and their total amount exhibit obviously seasonal and annual fluctuations. High values of the fluxes occurred in the prevailing periods of the northeastern and southwestern monsoons, and the low values occurred during the periods between the two monsoons. The fluxes of some planktonic foraminiferal species (Globigerinoides sacculifer, G. ruber, Globigerinita glutinata, Neogloboquadrina dutertrei) and their percentages also exhibit two prominent peaks during the prevailing periods of the northeastern and southwestern monsoons respectively, while those of Globigerina bulloides, Globorotalia menardii and Pulleniatina obliquiloculata only exhibit one peak in the prevailing periods of the northeastern monsoon. In addition, fluxes and percentages of Globigerinoides sacculifer and Globorotalia menardii as well as the fluxes of carbonate and total amount of planktonic foraminifera decrease gradually from 1993 to 1996, and those of Globigerina bulloides, Globigerinita glutinata and biogenic opal increase gradually from 1993 to 1996. The fluxes of carbonate and organic carbon in the upper trap are higher than those in the lower one. The study indicates that the seasonal and annual variations of the sediment fluxes and planktonic foraminiferal species are mainly controlled by the changes of surface primary productivity and hydrological conditions related to the East Asian monsoon. The lower carbonate and organic carbon fluxes in the lower trap are related to the dissolution.     

黄河水中胱氨酸对铅(Ⅱ)与悬浮粒子相互作用的影响

研究了黄河水中胱氨酸对铅(Ⅱ)与悬浮粒子相互作用的离子交换率E(%)-pH关系曲线的影响.结果表明:(1)2.0 u mol·L-1 的胱氨酸降低了离子交换率E(%);(2)与未加有机物相比"S型曲线"左移0.95个pH单位;(3)随着胱氨酸浓度的增加,离子交换率提高.     

山东莱州仓上泻湖Y86孔微量元素地球化学特征及沉积相判别

本文通过对山东莱州仓上泻湖Y86孔柱状样的系统取样，利用X荧光光谱分析了沉积柱状样品中的主要微量元素含量，结合已有的粒度分析、微体古生物及孢粉结果相分析对比，对泻湖沉积相进行地球化学判别，结果表明，Rb，Cr，Nb，Ni，Rb，Sr，Th，V，Zn，Zr等元素含量及Sr／Ba，Sr／Ca、Mn／Fe比值在不同的沉积相中均有明显的变异特征。因此可根据泻湖沉积物中的微量元素含量及Sr／Ba，Sr／Ca，Mn／Fe比值判别泻湖沉积环境及沉积相。     

萼花臂尾轮虫(Brachionus calyciflorus)COI基因序列变异及种群遗传结构分析

利用线粒体细胞色素氧化酶亚基Ⅰ(cytochrome oxidaseⅠ，COI)基因序列对北京地区和江汉湖群部分湖泊萼花臂尾轮虫(Brachionus calyciflorus)种群遗传结构进行了初步分析。以特异引物进行PCR扩增，获得了661bp的基因片断序列，所得序列与Genbank中B．calyciflorus COI序列的同源性为82％—93％。在6个种群中，共获得了15种单元型。序列分析结果表明，不同季节单元型之间的遗传距离较大(0．248-0．263)，而在同一季节单元型之间遗传距离较小(0．002-0．031)。种群遗传结构分析表明，各种群之间无共享的单元型，同一季节不同湖泊种群之间存在着一定程度的遗传分化，但未按照地理位置形成明显的地理格局。按采样时间分组进行AMOVA分析，组间差异高达94．09％；DH-I与其他种群之间存在着明显的遗传分化。同一湖泊不同季节样品之间，遗传变异较大，这表明在同一湖泊存在着不同基因型的轮虫休眠卵，当环境条件发生了变化后，不同基因型之间会发生更迭。     

海洋环境荷载下输液立管的静、动力特性研究

考虑管内流动流体和管外海洋环境荷载共同作用 ,建立海洋立管侧向运动微分方程。用Hermite插值函数离散 ,在微机上编写海洋立管静、动力分析程序 ,通过计算分析研究管内流体对立管侧向变形和应力的作用 ;另外 ,探讨管内流体的流动速度和立管顶端的预张力对立管动力特性的影响。结果表明 ,立管变形和应力均随管内流体流动速度增加而增大 ,同时内流速度的增大会降低立管的固有频率 ,但适当增大立管顶端预张力会抵消内流流速增加引起的固有频率下降。