Oxide and sulphide minerals in highly oxidized, Rb-depleted, Archaean granulites of the Shevaroy Hills Massif, South India: Oxidation states and the role of metamorphic fluids

The Shevaroy Hills of northern Tamil Nadu, southern India, expose the highest-grade granulites of a prograde amphibolite facies to granulite facies deep-crustal section of Late Archaean age. These highly oxidized quartzofeldspathic garnet charnockites generally show minor high-TiO₂ biotite and amphibole as the only hydrous minerals and are greatly depleted in the incompatible elements Rb and Th. Peak metamorphic temperatures (garnet–orthopyroxene) and pressures (garnet–orthopyroxene–plagioclase–quartz) are near 750 °C and 8 kbar, respectively. Pervasive veinlets of K-feldspar exist throughout dominant plagioclase in each sample and show clean contact with orthopyroxene. They are suggested to have been produced by a low H₂O activity, migrating fluid phase under granulite facies conditions, most likely a concentrated chloride/carbonate brine with high alkali mobility accompanied by an immiscible CO₂-rich fluid. Silicate, oxide and sulphide mineral assemblages record high oxygen fugacity. Pyroxenes in the felsic rocks have high Mg/(Mg+Fe) (0.5–0.7). The major oxide mineral is ilmenite with up to 60 mole per cent exsolved hematite. Utilizing three independent oxygen barometers (ferrosilite–magnetite–quartz, ferrosilite–hematite–quartz and magnetite–hematite) in conjunction with garnet–orthopyroxene exchange temperatures, samples with XIlmHm>0.1 yield a consistent oxygen fugacity about two log units above fayalite stability. Less oxidized samples (XIlmHm<0.1) show some scatter with indications of having equilibrated under more reducing conditions. Temperature-f (O₂ ) arrays result in self consistent conditions ranging from 660 °C and 10^?16 bar to 820 °C and 10^?11.5 bar. These trends are confirmed by calculations based on the assemblage clinopyroxene–orthopyroxene–magnetite–ilmenite using the QUIlF program. In the most oxidized granulite samples (XIlmHm>0.4) pyrite is the dominant sulphide and pyrrhotite is absent. Pyrite grains in these samples have marginal alteration to magnetite along the rims, signifying a high-temperature oxidation event. Moderately oxidized samples (0.1no coexisting magnetite. Chalcopyrite is a common accessory mineral of pyrite and pyrrhotite in all the samples. Textures in some samples suggest that it formed as an exsolution product from pyrrhotite. Extensive vein networks of magnetite and pyrite, associated principally with the pyroxene and amphibole, give evidence for a pervasive, highly oxidizing fluid phase. Thermodynamic analysis of the assemblage pyrrhotite, pyrite and magnetite yields consistent high oxidation states at 700–800 °C and 8 kbar. The oxygen fugacity in our most oxidized pyrrhotite-bearing sample is 10^?12.65 bar at 770 °C. There are strong indications that the Shevaroy Hills granulites recrystallized in the presence of an alkali-rich, low H₂O-activity fluid, probably a concentrated brine. It cannot be demonstrated at present whether the high oxidation states were set by initially oxidized protoliths or effected by the postulated fluids. The high correspondence of maximally Rb-depleted samples with the highest recorded oxidation states suggests that the Rb depletion event coincided with the oxidation event, probably during breakdown of biotite to orthopyroxene+K-feldspar. We speculate that these alterations were effected by exhalations from deep-seated alkali basalts, which provided both heat and high oxygen fugacity, low a_H2O fluids. It will be of interest to determine whether greatly Rb-depleted granulites in other Precambrian terranes show similar highly-oxidizing signatures.     

Lateglacial to Holocene relative sea‐level changes in the Stykkishólmur area,northern Snæfellsnes,Iceland

Comparatively little research has been undertaken on relative sea‐level (RSL) change in western Iceland. This paper presents the results of diatom, tephrochronological and radiocarbon analyses on six isolation basins and two coastal lowland sediment cores from the Stykkishólmur area, northern Snæfellsnes, western Iceland. The analyses provide a reconstruction of Lateglacial to mid‐Holocene RSL changes in the region. The marine limit is measured to 65–69 m above sea level (asl), with formation being estimated at 13.5 cal ka BP. RSL fall initially occurred rapidly following marine limit formation, until ca. 12.6 cal ka BP, when the rate of RSL fall decreased. RSL fell below present in the Stykkishólmur area during the early Holocene (by ca. 10 cal ka BP). The rates of RSL change noted in the Stykkishólmur area demonstrate lesser ice thicknesses in Snæfellsnes than Vestfirðir during the Younger Dryas, when viewed in the regional context. Consequently, the data provide an insight into patterns of glacio‐isostatic adjustment surrounding Breiðafjörður, a hypothesized major ice stream at the Last Glacial Maximum.     

Anatomy of a modern open-ocean carbonate slope: northern Little Bahama Bank

The open-ocean carbonate slope north of Little Bahama Bank consists of a relatively steep (4°) upper slope between water depths of 200 and 900 m, and a more gentle (1–2°) lower slope between depths of 900 and 1300+ m. The upper slope is dissected by numerous, small, submarine canyons (50–150 m in relief) that act as a line source for the downslope transport of coarse-grained carbonate debris. The lower slope is devoid of any well-defined canyons but does contain numerous, small (1–5 m) hummocks of uncertain origin and numerous, larger (5–40 m), patchily distributed, ahermatypic coral mounds. Sediments along the upper slope have prograded seaward during the Cenozoic as a slope-front-fill seismic facies of fine-grained peri-platform ooze. Surface sediments show lateral gradation of both grain size and carbonate mineralogy, with the fine fraction derived largely from the adjacent shallow-water platform. Near-surface sedimentary facies along the upper slope display a gradual downslope decrease in the degree of submarine cementation from well-lithified hardgrounds to patchily cemented nodular ooze to unlithified peri-platform ooze, controlled by lateral variations in diagenetic potential and/or winnowing by bottom currents. Submarine cementation stabilizes the upper part of the slope, allowing upbuilding of the platform margin, and controls the distribution of submarine slides, as well as the headward extent of submarine canyons. Where unlithified, sediments are heavily bioturbated and are locally undergoing dolomitization. Upper slope sediments are also ‘conditioned’eustatically, resulting in vertical, cyclic sequences of diagenetically unstable (aragonite and magnesian calcite-rich) and stable (calcite-rich) carbonates that may explain the well-bedded nature of ancient peri-platform ooze sequences. Lower slope sediments have prograded seaward during the Cenozoic as a chaotic-fill seismic facies of coarse-grained carbonate turbidites and debris flow deposits with subordinate amounts of peri-platform ooze. Coarse clasts are ‘internally’derived from fine-grained upper slope sediments via incipient cementation, submarine sliding and the generation of sediment gravity flows. Gravity flows bypass the upper slope via a multitude of canyons and are deposited along the lower slope as a wedge-shaped apron of debris, parallel to the adjacent shelf edge, consisting of a complex spatial arrangement of localized turbidites and debris flow deposits. A proximal apron facies of thick, mud-supported debris flow deposits plus thick, coarse-grained, Ta turbidites, grades seaward into a distal apron facies of thinner, grain-supported debris flow deposits and thinner, finer grained Ta-b turbidites with increasing proportions of peri-platform ooze. Both the geomorphology and sedimentary facies relationships of the carbonate apron north of Little Bahama Bank differ significantly from the classic submarine fan model. As such, a carbonate apron model offers an alternative to the fan model for palaeoenvironmental analysis of ancient, open-ocean carbonate slope sequences.     

THE SUBURBAN ENERGY BALANCE IN MIAMI, FLORIDA

Summertime measurements of local scale energy balance of a suburban site in west Miami, Florida, in 1995 are presented. All of the radiation and turbulent heat fluxes were measured directly. In addition several derived surface characteristics are calculated including the albedo, radiation temperature, emissivity, aerodynamic and canopy resistances, Bowen's ratio, Priestley‐Taylor and McNaughton‐Jarvis coefficients. The results are used to test parameterizations to calculate several heat fluxes. Most radiation fluxes can be calculated with simple schemes in cloudless conditions but the spatial and temporal variability of cloud degrades results greatly. This highlights the value of observing incoming solar radiation since it can form an excellent surrogate for daytime net all‐wave radiation in all sky conditions. The heat flux results for this warm, wet subtropical site demonstrate similarities with those from similarly developed locations in temperate climates. Interestingly this finding includes the fraction of energy used in evaporation. It is thought that this may be related to the relatively large heat storage in Miami which may reflect the presence of wet soils and free‐standing water, the persistently low vapor pressure deficits (7‐14 hPa) typical of this humid climate and the relatively poor coupling between the surface and the whole planetary boundary layer due to relatively low surface roughness.