Analysis of the spatial variation of heavy metals in the Guadiana Estuary sediments (SW Iberian Peninsula) based on GIS-mapping techniques

This work reveals the usefulness of the GIS (Geographic Information Systems) mapping techniques to show the distribution of pollutants along an estuarine environment, as the final stage of a thorough study. In the case of study, the environmental quality of the sediments in the Guadiana river estuary was determined by means of a complete geochemical characterization consisting on the calculation of enrichment factors for the most important metals and metalloids (compared with the local background of non-contaminated sediments). The obtained results were depicted in “enrichment distribution maps” which evidenced a distribution of the elements in two groups: Group-I, elements with natural origin (Al, Fe, Mn, Co, and Cr) distributed homogeneously along the basin, and Group-II, elements associated to anthropic origin (As, Cd, Cu, Pb, Ni and Zn) with clear punctual sources besides a high concentration all over the estuary. The enrichment factors for the elements of Group-II are indicative of the existence of a noticeable diffuse historical mining pollution associated with the acid mine drainage generated in the internal zones of the basin, which could overlap minor pollution inputs from other human activities. The obtained results lead us to a reconsideration of the traditionally thought “unpolluted” environment when it was compared to nearby estuaries.     

Local and landscape effects on spatial patterns of mangrove forest during wetter and drier periods: Moreton Bay,Southeast Queensland,Australia

Land use/cover and mangrove spatial changes were assessed for ten sites and their sub-catchments in Southeast Queensland, Australia. Two time periods were involved: 1972–1990, a period of relatively high rainfall, and 1990–2004, which was significantly drier. Aerial photographs and Landsat satellite imagery were used to map the inter-tidal wetlands and classify the land use/cover in the sub-catchments. A Maximum Likelihood Classification was used to map three types of land cover: agriculture, built-up and plantation forest. Mangroves (mainly Avicennia marina) were the focus as they have been recorded over recent decades encroaching into salt marsh. The Mangrove-Salt marsh Interface (MSI) Index was developed to quantify the relative opportunity for mangroves to expand into salt marshes, based on the shared boundary between them. The index showed a consistent relationship with mangrove expansion and change. To address problems of high dimensionality and multi-collinearity of predictor variables, a Partial Least Squares Regression (PLSR) model was used. A key finding of this research was that the contribution of environmental variables to spatial changes in the mangroves was altered following a reduction in rainfall. For example, agriculture had more influence on mangrove expansion and change during the wet period than during the dry period.     

Heat,volume and chemical fluxes from submarine venting: A synthesis of results from the Rainbow hydrothermal field, 36°N MAR

High-temperature hydrothermal activity occurs in all ocean basins and along ridge crests of all spreading rates. While it has long been recognized that the fluxes associated with such venting are large, precise quantification of their impact on ocean biogeochemistry has proved elusive. Here, we report a comprehensive study of heat, fluid and chemical fluxes from a single submarine hydrothermal field. To achieve this, we have exploited the integrating nature of the non-buoyant plume dispersing above the Rainbow hydrothermal field, a long-lived and tectonically hosted high-temperature vent site on the Mid-Atlantic Ridge. Our calculations yield heat and volume fluxes for high-temperature fluids exiting the seafloor of ～0.5 GW and 450 L s^?1, together with accompanying chemical fluxes, for Fe, Mn and CH₄ of ～10, ～1 and ～1 mol s^?1, respectively. Accompanying fluxes for 25 additional chemical species that are associated with Fe-rich plume particles have also been calculated as they are transported away from the Rainbow vent site before settling to the seabed. High-temperature venting has been found to recur at least once every ～100 km along all slow-spreading ridges investigated to-date, with half of all known sites on the Mid-Atlantic Ridge occurring as long-lived and tectonically hosted systems. If these patterns persist along all slow- and ultraslow-spreading ridges, high-temperature venting of the kind reported here could account for ～50% of the on-axis hydrothermal heat flux along ～30,000 km of the ～55,000 km global ridge crest.     

Composition and heterogeneity of the microbial community in a coastal microbial mat as revealed by the analysis of pigments and phospholipid-derived fatty acids

The beaches of the North Sea barrier island Schiermonnikoog (The Netherlands) are covered by microbial mats. Five types of microbial mats were distinguished based on a variety of characteristics, located along a transect perpendicular to the coast. Biomass abundance and composition of the microbial community were analyzed in these mats using pigments and phospholipid-derived fatty acids (PLFA) as biomarkers. Biomass per gram sediment increased more than six-fold from the mats at the low water mark to mats found at the edge of the dunes. Microscopic analysis revealed that the increase in biomass was accompanied by a change in species composition. Pigment- and PLFA composition reflected the changes in species composition. The PLFA data could be used to estimate the relative group abundance using the matrix factorization program CHEMTAX., whereas the pigment data were found not to be suitable for this purpose.     

Coastal observatory for long-term measurement and real time data processing of oceanological parameters

A coastal observatory for long-term continuous measurements of oceanological parameters and real-time data transfer via the Internet to remote users is described. The observatory was designed at the Shirshov Institute of Oceanology (SIO) and tested at its southern branch (SB) in the Black Sea. The architecture, components, and design principles of the observatory are discussed along with its application for solving problems of water dynamics in the coastal zone. Results of field tests are given.     

Element composition of ferromanganese concretions in the Black Sea

The ferromanganese concretions spread at the bottom of the shallow northwestern part of the Black Sea are mainly represented by Fe and Mn hydrate nodules on shells and substituted worm tubes. The element composition of these formations was found by the methods of chemical, atomic-absorbtion, neutron activation, and plasmic (ICP-MS) analyses. It is established that the content and the ratio of Fe and Mn in the concretions ranges within considerable limits, which controls the occurrence of several associated iron-free metals and microelements, some which have not been previously studied in the Black Sea concretions.     

Long-term changes in the meiobenthos of the eastern part of the Black Sea

The results of meiobenthic surveys undertaken in 1991, 1999, and 2005 off the Caucasian coasts of the Black Sea are presented. During the period of 1991 to 1999, the number of free-living nematodes increased significantly at all the sampling stations. The mean nematode abundance values grew from 85 ind./10 cm² in 1991 to 1167 ind./10 cm² in 1999. Proportionally, the total metazoan meiofauna density increased from 171 to 1283 ind./10 cm². The abundance of other meiofaunal groups including harpacticoid copepods did not change significantly. As a result of these changes, the ratio of nematodes to copepods (the nematodes-copepods index) increased from 2.5: 1 in 1991 to 26: 1 in 1999 and to 70: 1 in 2005. The number of foraminifers increased twofold. In 1991, they were found only at five stations out of 25. In 1999, foraminifers were presented at all ten stations with a mean density of 212 ind./10 cm². Such changes in the meiobenthic communities could have resulted from cascade transformations of the ecosystem leading to among other changes to a decline in the macrobenthos biomass and the release of nonutilized organic matter in the bottom ecosystems. The differences in the procedures of the sampling and the samples’ processing in the different years may be responsible for the 20–30% variation in the assessment of the meiobenthos’ number.     

Thermodynamic characteristics of water in natural water bodies with a high mineralization

To adequately describe the hydrophysical processes in water bodies with a high mineralization, it is necessary to take into account the dependence that the thermodynamic characteristics of water have on the amount of salts contained in it. This work investigates some widely known formulas for calculating a number of thermodynamic parameters of mineralized water. The density, freezing temperature, specific heat of evaporation, and relative pressure of saturated vapor over the surface are considered. The possibilities of using these formulas when modeling hydrophysical processes in water bodies with salinity in the range of 0–250 pro mille are analyzed. It is shown that the formulas under consideration should be used when the salinity does not exceed 100 pro mille. If the mineralization is higher, it is necessary to elaborate more suitable formulas on the basis of an approximation of in situ data or data from handbooks.     

Optical characteristics of coastal waters and atmosphere near the south coast of the crimea at the end of summer 2008

We present the results of measurements of optical characteristics of waters (the beam attenuation coefficient, volume scattering function, sea water reflectance, and Secchi depth) and optical characteristics of the atmosphere (aerosol optical thickness, content of vapors, and the ?ngstr?m exponent) carried out in September 2008 on the oceanographic platform near Katsiveli. We carried out the comparative analysis of hydrooptical characteristics measured in various years. The optical type of sea waters in the period of observations is determined.     

Circulation in the southwestern part of the Kara Sea in September 2007

During cruise 54 of the R/V Akademik Mstislav Keldysh to the southwestern Kara Sea (September 6 to October 7, 2007), a large amount of hydrophysical data with unique spatial resolution was obtained on the basis of measurements using different instruments. The analysis of the data gave us the possibility to study the dynamics and hydrological structure of the southwestern Kara Sea basin. The main elements of the general circulation are the following: the Yamal Current, the Eastern Novaya Zemlya Current, and the St. Anna Trough Current. All these currents are topographically controlled; they flow over the bottom slopes along the isobaths. The Yamal Current begins at the Kara Gates Strait and turns to the east as part of the cyclonic circulation. Then, it turns to the north and propagates along the Yamal coast over the 100-m isobath. The Eastern Novaya Zemlya Current (its core is located over the eastern slope of the Novaya Zemlya Trough) flows to the northeast. Near the northern edge of Novaya Zemlya, it encounters the St. Anna Trough Current, separates from the coast, and flows practically to the east merging with the continuation of the Yamal Current. A strong frontal zone is formed in the region where the two currents merge above the threshold that separates the St. Anna Trough from the Novaya Zemlya Trough and divides the warm and saline Arctic waters from the cooler and fresher waters of the southwestern part of the Kara Sea. This threshold, whose depth does not exceed 100–150 m, is a barrier that prevents the spreading of the Barents Sea and Arctic waters to the southwestern part of the Kara Sea basin through the St. Anna Trough.