Modeling of deep-seated high-alumina parageneses on the basis of the stability fields of corundum- and spinel-normative assemblages of the system CaO–MgO–Al2O3–SiO2

To elaborate physicochemical models for the origin of crystalline rocks, experimental studies of the field of high-alumina assemblages of the system CaO–MgO–Al₂O₃–SiO₂ were carried out at 10–30 kbar and 1250–1535 °C. We have determined the phase relations between the melt (L) and An, Sp, Cpx, Cor, and Ga, the slope of the rays of the monovariant reactions An + Sp = Cpx + Cor + (Ga) and L = Cpx +Ga + Cor + Sp, the position of the nonvariant point (An, Sp, Cpx, Cor, Ga, L), and the compositions of phases participating in these reactions. Based on a topological analysis of the studied segment of the system CaO–MgO–Al₂O₃–SiO₂, we have substantiated that “eclogitization” must follow the reaction Opx + An + Sp = Cpx + Ga. A fundamental continuous series of eutectic monovariant equilibria was observed: L = Cpx + Opx + Fo + An, L = Cpx + Opx + An + Sp, L = Cpx (+ Ga) + An + Sp, and L = Cpx + Cor (+ Ga) + An. A change in the melt composition in this series of eutectic reactions depending on pressure must reflect the most likely magma genesis trend in nature. Comparision of the composition fields in which the above series of reactions is observed with the composition fields of the rocks of magmatic formations showed that this series is most similar to the alkali-earth series of rocks. The mineralogical compositions of cumulates and phenocrysts found in the effusive and dike varieties of these rocks correspond to unique sets of subsolidus phase associations and individual subsolidus phases crystallizing in this fundamental eutectic series.     

Evolution and Spectrum of the Radio Emission of Tycho’s Supernova Remnant

The radio spectrum of Tycho’s Supernova Remnant is constructed at frequencies 12.6–143 000 MHz for epoch 2010.3, taking into account the secular decrease in the radio flux density of the remnant at the rate d = ?(0.46 ± 0.03)%/year:

$$S_\nu ^{3C10} (t = 2010.3) = (43.1 \pm 1.8 Jy)(\nu [GHz])^{ - (0.592 \pm 0.019) + (0.041 \pm 0.012)\log (\nu [GHz])} .$$

The spectrum has positive curvature. The presence of a low-frequency turnover in the spectrum of the radio source 3C10 with its maximum at 7.7 MHz is predicted, due to absorption in the interstellar medium in the direction toward the source.

     

Unusual spatial-temporal dynamics of geomagnetic disturbances during the main phase of the extremely strong magnetic storm of November 7–8, 2004

The spatial dynamics of geomagnetic variations and pulsations, auroras, and riometer absorption during the development of the main phase of the extremely strong magnetic storm of November 7–8, 2004, has been studied. It has been indicated that intense disturbances were observed in the early morning sector of auroral latitudes rather than in the nighttime sector, as usually takes place during magnetic storms. The unusual spatial dynamics was revealed at the beginning of the storm main phase. A rapid poleward expansion of disturbances from geomagnetic latitudes of 65°–66° to 74°–75° and the development of the so-called polar cap substorm with a negative bay amplitude of up to 2500 nT, accompanied by precipitation of energetic electrons (riometer absorption) and generation of Pi2–Pi3 pulsations, were observed when IMF B _z was about ?45 nT. The geomagnetic activity maximum subsequently sharply shifted equatorward to 60°–61°. The spatial dynamics of the westward electrojet, Pi2–Pi3 geomagnetic pulsations, and riometer absorption was similar, which can indicate that the source of these phenomena is common.     

Variations of global water exchange under changing climate

Variations of Global Sea Level are considered as an integral indicator of global water exchange. The results of analysis of Global Sea Level variations over past 140 years are estimated from tide-gauge data. Level trend in the XX century is shown to amount to 1.8 mm/year. The contributions of various factors to the formation of Global Sea Level trend are discussed. The interannual variations of evaporation and precipitation over the World Ocean are estimated for the first time, and their difference is shown to significantly contribute to the level trend, especially in the recent decade. Moreover, the significant rise in Global Sea Level is associated with the thermosteric level variations and, possibly, with the bottom melting of Antarctic shelf glaciers.     

The First Results of U–Pb Isotope Dating of Detrital Zircons from the Upper Mesoproterozoic Gulliksenfellet Quartzite (Southern Part of Wedel Jarlsberg Land,Southwest Spitsbergen)

The first results of U–Pb isotopic dating (LA–ICP–MS) of detrital zircons from metasedimentary rocks of the pre-Devonian basement of the SW part of western Spitsbergen (from Upper Mezoproterozoic Gulliksenfellet quartzite) showed ages ranging from 1700 ± 25 to 2948 ± 27 Ma.     

Simulating future Caspian sea level changes using regional climate model outputs

We report on simulations of present-day climate (1961–1990) and future climate conditions (2071–2100, Special Report on Emissions Scenario A2) over the Caspian sea basin with a regional climate model (RCM) nested in time-slice general circulation model (GCM) simulations. We also calculate changes (A2 scenario minus present-day) in Caspian sea level (CSL) in response to changes in the simulated hydrologic budget of the basin. For the present-day run, both the GCM and RCM show a good performance in reproducing the water budget of the basin and the magnitude of multi-decadal changes in CSL. Compared to present-day climate, in the A2 scenario experiment we find an increase in cold season precipitation and an increase in temperature and evaporation, both over land and over the Caspian sea. We also find a large decrease of CSL in the A2 scenario run compared to the present-day run. This is due to increased evaporation loss from the basin (particularly over the sea) exceeding increased cold season precipitation over the basin. Our results suggest that the CSL might undergo large changes under future climate change, leading to potentially devastating consequences for the economy and environment of the region.     

Removal of Selenium by Adsorption onto Granular Activated Carbon (GAC) and Powdered Activated Carbon (PAC)

The present work involves the study of Se(IV) adsorption onto granular activated carbon (GAC) and powdered activated carbon (PAC). The adsorbents are coated with ferric chloride solution for the effective removal of selenium. The physico-chemical characterization of the adsorbents is carried out using standard methods, e. g., proximate analysis, scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FTIR), thermo-gravimetric (TGA) and differential thermal analysis (DTA), etc. The FTIR spectra of the GAC and PAC indicate the presence of various types of functional groups, e. g., free and hydrogen bonded OH groups, silanol groups (Si-OH), alkenes, and CO group stretching from aldehydes and ketones on the surface of adsorbents. Batch experiments are carried out to determine the effect of various factors such as adsorbent dose (w), initial pH, contact time (t), and temperature (T) on the adsorption process. The optimum GAC and PAC dosage is found to be 10 g/L and 8 g/L, respectively, for Se(IV) removal with C₀ = 100 mg/L. The percent removal of Se(IV) increases with increasing adsorbent concentration, while removal per unit weight of adsorbent increases with decreasing adsorbent concentration. Se(IV) adsorption onto both the GAC and PAC adsorbents is high at low pH values, and decreases with increased initial pH. The results obtained are analyzed by various kinetic models. The parameters of pseudo-first order, pseudo-second order kinetics, and Weber-Morris intra particle kinetics are determined. It is seen that the sorption kinetics of Se(IV) onto GAC and PAC can be best represented by the pseudo-second order kinetic model.     

Variations in the geomagnetic field and auroras during the main phase of a large magnetic storm of November 20, 2003

The substorm characteristics during the main phase of a large magnetic storm of November 20, 2003, are studied based on the data of TV observations of auroras and auroral absorption at Tixie Bay station and at the global network of magnetic stations. The contribution of auroral particles, responsible for the emission of discrete auroras, has been estimated based on an analysis of the spatial-time variations in the auroral luminosity intensity. This contribution accounted for ～40% of the total luminous flux, which is approximately twice as large as was previously observed in substorm disturbances. Responses of the solar wind and IMF parameters in substorms and variations in the magnetic indices, characterizing geomagnetic activity in the northern polar cap and ring current (PCN, ASY-H and SYM-H), have been detected. The spatial-time distribution of the equivalent ionospheric currents has been constructed, and the total value of these currents along the meridian has been determined based on the [Popov et al., 2001] method and using the IMAGE magnetic data. It has been obtained that the maximal total equivalent ionospheric current in the premidnight sector (～2000 MLT) leads the minimal value of the SYM-H index by ～1.5 h.     

Numerical simulation of a low-lying barrier island's morphological response to Hurricane Katrina

Tropical cyclones that enter or form in the Gulf of Mexico generate storm surge and large waves that impact low-lying coastlines along the Gulf Coast. The Chandeleur Islands, located 161 km east of New Orleans, Louisiana, have endured numerous hurricanes that have passed nearby. Hurricane Katrina (landfall near Waveland MS, 29 Aug 2005) caused dramatic changes to the island elevation and shape. In this paper the predictability of hurricane-induced barrier island erosion and accretion is evaluated using a coupled hydrodynamic and morphodynamic model known as XBeach. Pre- and post-storm island topography was surveyed with an airborne lidar system. Numerical simulations utilized realistic surge and wave conditions determined from larger-scale hydrodynamic models. Simulations included model sensitivity tests with varying grid size and temporal resolutions. Model-predicted bathymetry/topography and post-storm survey data both showed similar patterns of island erosion, such as increased dissection by channels. However, the model under predicted the magnitude of erosion. Potential causes for under prediction include (1) errors in the initial conditions (the initial bathymetry/topography was measured three years prior to Katrina), (2) errors in the forcing conditions (a result of our omission of storms prior to Katrina and/or errors in Katrina storm conditions), and/or (3) physical processes that were omitted from the model (e.g., inclusion of sediment variations and bio-physical processes).