Energy transfer among Pb, Ce and Mn in fluorescent calcite from Kuerle, Xinjiang, China

Natural calcite from Kuerle, Xinjiang, China, shows orange-red fluorescence when exposed to short-wave ultraviolet (UV) light (Hg 253.7 nm). Photoluminescence (PL) emission and excitation spectra of the calcite are observed at room temperature in detail. The PL emission spectrum under 208 nm excitation consists of three bands: two UV bands at 325 and 355 nm and an orange-red band at 620 nm. The three bands are ascribed to Pb²⁺, Ce³⁺ and Mn²⁺, respectively, as activators. The Pb²⁺ excitation band is observed at 243 nm, and the Ce³⁺ excitation band at 295 nm. The Pb²⁺ excitation band is also observed by monitoring the Ce³⁺ fluorescence, and the Pb²⁺ and Ce³⁺ excitation bands, in addition to six Mn²⁺ excitation bands, are also observed by monitoring the Mn²⁺ fluorescence. These indicate that four types of the energy transfer can occur in calcite through the following processes: (1) Pb²⁺ → Ce³⁺, (2) Pb²⁺ → Mn²⁺, (3) Ce³⁺ → Mn²⁺ and (4) Pb²⁺ → Ce³⁺ → Mn²⁺.     

Long-term variations in the asymmetry of the magnetic field of the sun and heliosphere

The asymmetry of the magnetic field of the Sun and its manifestation in the interplanetary magnetic field (IMF) are studied. The dominant magnetic polarity of the radial component of the IMF alternates from cycle to cycle, but with an overall systematic dominance of polarity directed toward the Sun. The global asymmetry is also manifest in the component of the IMF perpendicular to the plane of the solar equator. The dominance of positive values of B _z together with an appreciable linear trend in the cumulative sum of this quantity is interpreted as a manifestation of a relic solar magnetic field. The strength of this relic magnetic field near the Earth is estimated to be 0.048 ± 0.015 nT, based on the growth of the linear component of the cumulative sum of B _z . Time intervals, in which negative values of the B _z component of the IMF dominate and enhanced geomagnetic activity is observed, are identified. Our analysis of solar and heliospheric magnetic fields in an integrated representation has enabled us to compare various types of measurements and estimate their stability.     

Hydrothermal sulfide deposits of the Lucky Strike vent field, Mid-Atlantic Ridge

Several hydrothermal sulfide structures were sampled using Mir manned submersibles in the relatively shallow Lucky Strike vent field, Mid-Atlantic Ridge; the bathymetric position of these structures varies by approximately 100 m. The investigation of the chemical and mineral compositions of hydrothermal ore occurrences led to the conclusion that the initial high-temperature ore-bearing solution ascending toward the surface became unstable and experienced phase separation beneath the ocean floor. The phase separation was responsible for the bathymetric control of hydrothermal ore formation in the ocean.     

The correlation of Mesozoic gold ore districts at the Sino-Korean and Aldan-Stanovoi shields

The geological structure and gold ore potential of the activized Aldan-Stanovoi and Sino-Korean shields of East Asia are compared. These two regions show similar tendencies in their geological evolution during the Archean, Proterozoic, and Phanerozoic epochs but differ in types of tectonic structure and associations of ore deposits. According to recent studies by Russian and Chinese geologists, the Mesozoic complexes of these shields possess higher gold ore potential than was suggested before. As a result of these studies, the amount of conditions favoring the formation of large gold districts and deposits in the activized shields has strongly increased. Some of these deposits are polychronic and polygenetic (the Bam deposit), others are associated with J-K alkaline magmatism (the Central Aldan district), a third group of deposits are related to granites of the same age (the East Shandong district), and a fourth group includes stratiform deposits in the lower part of the udokan series (Ugui district). The various Mesozoic hydrothermal ore deposits of the northern framework of the Sino-Korean Shield are especially interesting. The study of problems of gold metallogeny was initiated in Russian geological science by Yu.A. Bilibin (1935–1940) in the central part of the Aldan Shield. Some new data concerning the gold ore potential of the Sino-Korean Shield extend our knowledge of gold ore districts in East Asia and make clear the necessity of more careful and systematic study of the gold ore potential of the Aldan-Stanovoi Shield.     

Decarbonation reaction of magnesite in subducting slabs at the lower mantle

High-pressure and temperature experiments (28–62 GPa, and 1,490–2,000 K, corresponding to approximately 770–1,500 km depth in the mantle) have been conducted on a MgCO₃ + SiO₂ mixture using a laser-heated diamond anvil cell combined with analytical transmission electron microscope observation of the product phases to constrain the fate of carbonates carried on the subducting basalt into the lower mantle. At these conditions, the decarbonation reaction MgCO₃ (magnesite) + SiO₂ (stishovite) → MgSiO₃ (perovskite) + CO₂ (solid) has been recognized. This indicates that above reaction takes place as a candidate for decarbonation of the carbonated subducting mid ocean ridge basalts in the Earth’s lower mantle.