Eruptive history and petrologic evolution of the Albano multiple maar (Alban Hills, Central Italy)

A comprehensive volcanological study of the Albano multiple maar (Alban Hills, Italy) using (i) ⁴⁰Ar/³⁹Ar geochronology of the most complete stratigraphic section and other proximal and distal outcrops and (ii) petrographic observations, phase analyses of major and trace elements, and Sr and O isotopic analyses of the pyroclastic deposits shows that volcanic activity at Albano was strongly discontinuous, with a first eruptive cycle at 69±1 ka producing at least two eruptions, and a second cycle with two peaks at 39±1 and 36±1 ka producing at least four eruptions. Contrary to previous studies, we did not find evidence of magmatic or hydromagmatic eruptions younger than 36±1 ka. The activity of Albano was fed by a new batch of primary magma compositionally different from that of the older activity of the Alban Hills; moreover, the REE and ⁸⁷Sr/⁸⁶Sr data indicate that the Albano magma originated from an enriched metasomatized mantle. According to the modeled liquid line of descent, this magma differentiated under the influence of magma/limestone wall rock interaction. Our detailed eruptive and petrologic reconstruction of the Albano Maar evolution substantiates the dormant state of the Alban Hills Volcanic District. Electronic Supplementary Material Supplementary material is available for this article at Editorial responsibility: J. Donnelly-Nolan An erratum to this article can be found at     

A REMOTE SENSING METHOD FOR DETERMINING HEAT FLUX AT THE OCEAN-ATMOSPHERE BOUNDARY LAYER

Results of experiments in the measurement of heat flux at the ocean-atmosphere boundary layer are described. More specifically, an algorithm is presented for the calculation of the different components of total heat flux (from the ocean into the atmosphere) based on estimates of water temperature, wind velocity, and cloud cover obtained from remote sensing imagery. Use of the algorithm yields values for total heat flux which, when averaged over a ten-day period, are only 10% less accurate than those obtained according to traditional methods (research vessels, buoys, offshore platforms). Translated from: Izvestiya vysshykh uchebnykh zavedeniy, Geodezlya i aerofotos”yemka, 1986, No. 5, pp. 117-120.     

The kinetic studies of the cobalt ion removal from aqueous solutions by dolomite-based sorbent

The kinetics of Co(II) ions adsorption on thermally activated dolomite was studied with respect to the calcination temperature of natural dolomite. The sorption of Co(II) onto all samples is reasonably fast: The first 30–35 min accounts for approximately 70–80 % of Co(II) removal from feed solutions. In order to select the main rate-determining step in the overall uptake mechanism, a series of experiments were performed and data obtained were interpreted in terms of film diffusion control, intraparticle diffusion, pseudo-first-order and pseudo-second-order models. From the modeling of kinetic data, it can be concluded that adsorption of Co(II) ions from aqueous solution by heat-treated dolomite is a complex phenomenon and occurs in a mixed diffusion mode—the kinetic data are well described by the pseudo-second-order equation. The possible multistage sorption mechanism involving film diffusion and intraparticle diffusion control steps as well as chemical interaction between Co(II) ions and calcined dolomite is proposed.     

Sundararajan transform—an application to geophysical data analysis

An integral transform, called in this study as Sundararajan transform, has been used to estimate the parameters of vertical magnetic effect of a fault structure. It differs from the well-known Hilbert transform in the property of phase shift as it yields a phase shift of 270° unlike the Hilbert transform, which is a 90° phase shifter. Other properties of the Sundararajan transform remain almost the same as the Hilbert transform. The transform has been tested on synthetic data and a field example of Lachlan Foldbelts, New South Wales, Australia. The results of this technique agree with the one published in the literature. The noise analysis has been examined and showed that it still provides acceptable results. The application of this transform to geophysical interpretation illustrates its potentiality, and it may be widely applied in various disciplines mainly in the field of communication engineering, signal, and image processing. An interesting property of this transform is that two successive transforms of a function return it to its original form unlike the Hilbert transform, which returns it to the negative of the original form. The procedure discussed may be automated.     

First record of a Cretaceous cheilostome bryozoan from Hokkaido, Japan

A small collection of recrystallised, encrusting colonies of a single species from the Mikasa Formation (lower Middle Cenomanian), represents the first record of cheilostome (malacostegan or anascan) bryozoans from Hokkaido, Japan.     

Thick and thin models of the evolution of carbon dioxide on Mars

We present results from a new simulation code that accounts for the evolution of the reservoirs of carbon dioxide on Mars, from its early years to the present. We establish a baseline model parameter set that produces results compatible with the present (i.e., Patm?6.5 mbar with permanent CO₂ ice cap) for a wide range of initial inventories. We find that the initial inventory of CO₂ broadly determines the evolutionary course of the reservoirs of CO₂. The reservoirs include the atmosphere, ice cap, adsorbed CO₂ in the regolith, and carbonate rocks. We track the evolution of the free inventory: the atmosphere, ice cap and regolith. Simulations begin at 4.53 Gyr before present with a rapid loss of free inventory to space in the early Noachian. Models that assume a relatively small initial inventory (?5 bar) have pronounced minima in the free inventory of CO₂ toward the end of the Noachian. Under baseline parameters, initial inventories below ∼4.5 bar result in a catastrophic loss of the free inventory to space. The current free inventory would be then determined by the balance between outgassing, sputtering losses and chemical weathering following the end of the late bombardment. We call these “thin” models. They generically predict small current free inventories in line with expectations of a small present CO₂ ice cap. For “thick” models, with initial inventories ?5 bar, a surplus of 300-700 mbar of free CO₂ remains during the late-Noachian. The histories of free inventory in time for thick models tend to converge within the last 3.5 Gyr toward a present with an ice cap plus atmospheric inventory of about 100 mbar. For thick models, the convergence is largely due to the effects of chemical weathering, which draws down higher free inventories more rapidly than the low. Thus, thick models have ?450 mbar carbonate reservoirs, while thin models have ?200 mbar. Though both thick and thin scenarios can reproduce the current atmospheric pressure, the thick models imply a relatively large current CO₂ ice cap and thin models, little or none. While the sublimation of a massive cap at a high obliquity would create a climate swing of greenhouse warming for thick models, under the thin model, mean temperatures and pressures would be essentially unaffected by increases in obliquity.     

On the simulation of multidimensional cyclic loading with intergranular strain

A sample of soil is subjected to multidimensional cyclic loading when two or three principal components of the stress or strain tensor are simultaneously controlled to perform a repetitive path. These paths are very useful to evaluate the performance of models simulating cyclic loading. In this article, an extension of an existing constitutive model is proposed to capture the behavior of the soil under this type of loading. The reference model is based on the intergranular strain anisotropy concept and therefore incorporates an elastic locus in terms of a strain amplitude. In order to evaluate the model performance, a modified triaxial apparatus able to perform multidimensional cyclic loading has been used to conduct some experiments with a fine sand. Simulations of the extended model with multidimensional loading paths are carefully analyzed. Considering that many cycles are simulated (\(N>30\)), some additional simulations have been performed to quantify and analyze the artificial accumulation generated by the (hypo-)elastic component of the model. At the end, a simple boundary value problem with a cyclic loading as boundary condition is simulated to analyze the model response.     

Ecology of the bottom fauna and bioaccumulation of trace metals along the Lena River–Laptev Sea transect

The first data on ecology and trace metal (As, Cd, Cr, Cu, Fe, Mn, Ni, Pb) bioaccumulation by macrozoobenthic organisms in area along the 130°E meridional transect from shallow water near the Lena River’s delta till the 78°N are presented. At the newly discovered methane seeps in the shallow Laptev Sea areas (72 m depth), a higher total abundance and biomass compared with background stations were recorded. In carbonate shells and soft tissues of Bivalvia Portlandia arctica and Astarte borealis, the high concentrations of Mn, Fe, Pb, Ni and Co were detected that varied in dependence from sampling site. In the dominating taxa of brittle stars (Ophiuroidea), there were found no significant differences between majority of trace metal content in organisms inhabiting the seeps area and background ones. An elevated content of some metals was detected in the Asteroidea bodies that may be attributed to its trophic behavior (deposit feeder).