Spatial and seasonal variations in depth profile of trace metals in saltmarsh sediments from Sapelo Island, Georgia, USA

This study was undertaken to elucidate the impact of early diagenetic processes on the accumulation of trace metals in Sapelo Island saltmarsh sediments as a function of time, space and sediment properties. Samples were collected from three sites in summer (May 1997) and winter (January 1998) along a transect from an unvegetated Creek Bank through a vegetated Tidal Levee to the vegetated midmarsh with evident lateral heterogeneity caused by hydrologic regime, macrophytes and microbial and macrofaunal activities. A suite of trace metals (As, Ba, Cr, Co, Cu, Cd, Mo, Ni, Pb, Th, Ti, U, V, Zn and Zr) was analyzed to obtain their depth-distribution at the three sites. Spatially marked differences were observed, that were primarily related to hydraulic flushing of trace metals away from the sites in high-energy regimes, rapid downward mixing and reworking of sediment via bioturbation, and below-ground degradation and production of Spartina biomass. Although sulfate reduction and the formation of acid volatile sulfide and pyrite were dominant processes throughout the marsh, the trace metal scavenging role of sulfides was not apparent. However, possible sulfurization of organic matter, leading to enhanced trapping of trace metals with organic carbon, may have played an important role in sequestration of trace metals.No similarity was observed visually between the depth trends of trace metals and sediment properties (grain size, iron-oxyhydroxide content, acid volatile sulfides and pyrite content) that are known to play a major role in trace metal partitioning. Only organic carbon content closely followed the trace metal profiles at all the three sites. Minor variation in depth-integrated sediment trace metal content was observed seasonally at each of the three sites. Furthermore, the depth trend of profiles of individual trace metals also did not vary significantly over the seasons either.     

Foregrounds for redshifted 21-cm studies of reionization: Giant Meter Wave Radio Telescope 153-MHz observations

Foreground subtraction is the biggest challenge for future redshifted 21-cm observations to probe reionization. We use a short Giant Meter Wave Radio Telescope (GMRT) observation at 153 MHz to characterize the statistical properties of the background radiation across ∼1° to subarcmin angular scales, and across a frequency band of 5 MHz with 62.5 kHz resolution. The statistic we use is the visibility correlation function, or equivalently the angular power spectrum   C _l   . We present the results obtained from using relatively unsophisticated, conventional data calibration procedures. We find that even fairly simple-minded calibration allows one to estimate the visibility correlation function at a given frequency   V ₂( U , 0)  . From our observations, we find that   V ₂( U , 0)  is consistent with foreground model predictions at all angular scales except the largest ones probed by our observations where the model predictions are somewhat in excess. On the other hand, the visibility correlation between different frequencies  κ( U , Δν)  seems to be much more sensitive to calibration errors. We find a rapid decline in  κ( U , Δν)  , in contrast with the prediction of less than 1 per cent variation across 2.5 MHz. In this case, however, it seems likely that a substantial part of the discrepancy may be due to limitations of data reduction procedures.     

Characterization of diurnal cycles in ZTD from a decade of global GPS observations

The diurnal cycle of the tropospheric zenith total delay (ZTD) is one of the most obvious signals for the various physical processes relating to climate change on a short time scale. However, the observation of such ZTD oscillations on a global scale with traditional techniques (e.g. radiosondes) is restricted due to limitations in spatial and temporal resolution. Nowadays, the International GNSS Service (IGS) provides an important data source for investigating the diurnal and semidiurnal cycles of ZTD and related climatic signals. In this paper, 10 years of ZTD data from 1997 to 2007 with a 2-hour temporal resolution are derived from global positioning system (GPS) observations taken at 151 globally distributed IGS reference stations. These time series are used to investigate diurnal and semidiurnal oscillations. Significant diurnal and semidiurnal oscillations of ZTD are found for all GPS stations used in this study. The diurnal cycles (24 hours period) have amplitudes between 0.2 and 10.9 mm with an uncertainty of about 0.5 mm and the semidiurnal cycles (12 h period) have amplitudes between 0.1 and 4.3 mm with an uncertainty of about 0.2 mm. The larger amplitudes of the diurnal and semidiurnal ZTD cycles are observed in the low-latitude equatorial areas. The peak times of the diurnal cycles spread over the whole day, while the peak value of the semidiurnal cycles occurs typically about local noon. These GPS-derived diurnal and semidiurnal ZTD signals are similar with the surface pressure tides derived from surface synoptic pressure observations, indicating that atmospheric tides are the main driver of the diurnal and semidiurnal ZTD variations.     

Observations of the gamma-ray flux from the galaxy Mk 501

We present two-year-long observations of the flux of very-high-energy (～10¹² eV) gamma rays from the active galactic nucleus Mk 501 performed with a Cherenkov detector at the Crimean Astrophysical Observatory. A gamma-ray flux from the object was shown to exist at confidence levels of 11 and 7 standard deviations for 1997 and 1998, respectively. The flux varied over a wide range. The mean flux at energies >10¹² eV, as inferred from the 1997 and 1998 data, is (5.0±0.6)×10^?11 and (3.7±0.6)×10^?11 cm^?2 s^?1, respectively. The errors are the sum of statistical observational and modeling errors. The mean power released in the form of gamma rays is ～2×10⁴³ erg s^?1 sr^?1.     

Biodegradation of <Emphasis Type="Italic">Enteromorpha</Emphasis> polysaccharides by intestinal micro-community from <Emphasis Type="Italic">Siganus oramin</Emphasis>

Micro-communities are supposed to have more potential functions of biodegradation of polysaccharides than single strain; however, the intestinal micro-communities involved in the biodegradation of Enteromorpha polysaccharides (EP) were seldom reported. In order to obtain the EP-degrading micro-community, the intestines of Siganus oramin was obtained to isolate the micro-communities, which were enriched by 0.3% of EP as the sole carbon source. A stable micro-community with EP degradative capability was achieved after seven generations of subculture, named H1. Results showed that H1 was able to degrade 75% of EP within 24 hours, and the activity of EP lyases reached 500 U mL^?1 in 32 hours. With denaturing gradient gel electrophoresis (DGGE) and 16S rRNA gene clone library analysis, ten bacteria closely related to Marinomonas pontica, Microbacterium sp., Leucobacter chironomi, Cyclobacterium sp., Algoriphagus winogradskyi, Pseudoalteromonas sp. and Vibrio sp. were determined. Furthermore, compared with the DGGE bands sequence and the clone library analysis, the dominant bacteria of the EP-biodegrading micro- community were Pseudoalteromonas sp. and Vibrio sp., with the respective proportion of 38% and 46%, and they should play an important role in EP degradation together with other degrading bacteria in the micro-community H1.     

Determination of the isotopic composition of molybdenum in the bottom sediments of freshwater basins

This paper presents the results of measurements of the Mo isotopic composition in the bottom sediments (BS) of freshwater basins. Mo isotopic ratios were measured using a multicollector inductively coupled plasma mass spectrometer (MC ICP MS). Efficient methods were used in this study for Mo separation from the elements of the sample matrix and correction for instrumental mass discrimination. This allowed us to achieve a high accuracy of 0.06, 0.08, and 0.14‰ (2 σ) for the measurement of ⁹⁷Mo/⁹⁵Mo, ⁹⁸Mo/⁹⁵Mo, and ¹⁰⁰Mo/⁹⁵Mo, respectively. The range of variations in Mo isotope ratios observed in the collected BS columns was ～2.2‰ in terms of δ⁹⁷Mo/⁹⁵Mo. The results obtained here suggest that geochemical processes occurring during Mo migration with land water can change the isotopic composition of Mo. It is pointed out that the potential use of Mo isotopic systematics for reconstructions of redox conditions in seawater over the geologic past requires the quantification of isotopic effects of Mo accompanying its migration on land and the extent of possible variations in the isotopic composition of Mo entering the ocean.     

Improving Scatterometry Retrievals of Wind in Hurricanes Using Non-Simultaneous Passive Microwave Estimates of Precipitation and a Split-Step Advection/Convection Model

One of the current problems in the accurate estimation of over-ocean wind from scatterometry observations is the proper accounting for precipitation. Specific cases such as hurricanes are particularly difficult, because precipitation in the eye wall and rain bands can be quite heavy, and therefore, affect the scatterometer signatures so drastically that a category-4 hurricane can appear, to the scatterometer, to have category-1 winds. We have developed an approach to infer and account for the signature of the precipitation from non-simultaneous passive-microwave measurements of rain, with the help of geostationary IR measurements. In this note, we describe the basic approach, and the results of applying it to the data taken by the Tropical Rainfall Measurement Mission Microwave Imager measurements several hours before and after the QuikSCAT observation of Hurricane Rita in September 2005. We also describe how we are enhancing the approach with more realism in the assimilation of the IR information.     

Nonlinear Atmospheric and Climate Dynamics in China （2003-2006）： A Review

Recent advances in the study of nonlinear atmospheric and climate dynamics in China （2003 2006） are briefly reviewed. Major achievements in the following eight areas are covered： nonlinear error dynamics and predictability; nonlinear analysis of observational data; eddy-forced envelope Rossby soliton theory; sensitivity and stability of the ocean＇s thermohaline circulation; nonlinear wave dynamics; nonlinear analysis on fluctuations in the atmospheric boundary layer; the basic structures of atmospheric motions; some applications of variational methods.     

Dynamic river–groundwater exchange in the presence of a saline,semi‐confined aquifer

Understanding groundwater–surface water exchange in river banks is crucial for effective water management and a range of scientific disciplines. While there has been much research on bank storage, many studies assume idealized aquifer systems. This paper presents a field‐based study of the Tambo Catchment (southeast Australia) where the Tambo River interacts with both an unconfined aquifer containing relatively young and fresh groundwater (<500 μS/cm and <100 years old) and a semi‐confined artesian aquifer containing old and saline groundwater (electrical conductivity > 2500 μS/cm and >10 000 years old). Continuous groundwater elevation and electrical conductivity monitoring within the different aquifers and the river suggest that the degree of mixing between the two aquifers and the river varies significantly in response to changing hydrological conditions. Numerical modelling using MODFLOW and the solute transport package MT3DMS indicates that saline water in the river bank moves away from the river during flooding as hydraulic gradients reverse. This water then returns during flood recession as baseflow hydraulic gradients are re‐established. Modelling also indicates that the concentration of a simulated conservative groundwater solute can increase for up to ~34 days at distances of 20 and 40 m from the river in response to flood events approximately 10 m in height. For the same flood event, simulated solute concentrations within 10 m of the river increase for only ~15 days as the infiltrating low‐salinity river water drives groundwater dilution. Average groundwater fluxes to the river stretch estimated using Darcy's law were 7 m³/m/day compared with 26 and 3 m³/m/day for the same periods via mass balance using Radon (²²²Rn) and chloride (Cl), respectively. The study shows that by coupling numerical modelling with continuous groundwater–surface water monitoring, the transient nature of bank storage can be evaluated, leading to a better understanding of the hydrological system and better interpretation of hydrochemical data. Copyright © 2015 John Wiley & Sons, Ltd.