Late Carboniferous porphyry copper mineralization at La Voluntad,Neuquén,Argentina: Constraints from Re–Os molybdenite dating

The La Voluntad porphyry Cu–Mo deposit in Neuquén, Argentina, is one of several poorly known porphyry-type deposits of Paleozoic to Early Jurassic age in the central and southern Andes. Mineralization at La Voluntad is related to a tonalite porphyry from the Chachil Plutonic Complex that intruded metasedimentary units of the Piedra Santa Complex. Five new Re–Os molybdenite ages from four samples representing three different vein types (i.e., quartz–molybdenite, quartz–sericite–molybdenite and quartz–sericite–molybdenite ± chalcopyrite–pyrite) are identical within error and were formed between ~312 to ~316 Ma. Rhenium and Os concentrations range between 34 to 183 ppm and 112 to 599 ppb, respectively. The new Re–Os ages indicate that the main mineralization event at La Voluntad, associated to sericitic alteration, was emplaced during a time span of 1.7 ± 3.2 Ma and that the deposit is Carboniferous in age, not Permian as previously thought. La Voluntad is the oldest porphyry copper deposit so far recognized in the Andes and indicates the presence of an active magmatic arc, with associated porphyry style mineralization, at the proto-Pacific margin of Gondwana during the Early Pennsylvanian.     

Spatial control of groundwater contamination,using principal component analysis

A study on the geochemistry of groundwater was carried out in a river basin of Andhra Pradesh to probe into the spatial controlling processes of groundwater contamination, using principal component analysis (PCA). The PCA transforms the chemical variables, pH, EC, Ca²⁺, Mg²⁺, Na⁺, K⁺, HCO \(_3^- \) , Cl^?, SO \(_4^{2-} \) , NO \(_3^-\) and F^?, into two orthogonal principal components (PC1 and PC2), accounting for 75% of the total variance of the data matrix. PC1 has high positive loadings of EC, Na⁺, Cl^?, SO \(_4^{2-} \) , Mg²⁺ and Ca²⁺, representing a salinity controlled process of geogenic (mineral dissolution, ion exchange, and evaporation), anthropogenic (agricultural activities and domestic wastewaters), and marine (marine clay) origin. The PC2 loadings are highly positive for HCO \(_3^- \) , F^?, pH and NO \(_3^- \) , attributing to the alkalinity and pollution controlled processes of geogenic and anthropogenic origins. The PC scores reflect the change of groundwater quality of geogenic origin from upstream to downstream area with an increase in concentration of chemical variables, which is due to anthropogenic and marine origins with varying topography, soil type, depth of water levels, and water usage. Thus, the groundwater quality shows a variation of chemical facies from Na⁺ > Ca²⁺ > Mg²⁺ > K⁺: HCO \(_3^- \) > Cl^? > SO \(_4^{2-}>\) NO \(_3^- \) > F^?at high topography to Na⁺ > Mg²⁺ > Ca²⁺ > K⁺: Cl^? > HCO \(_3^- \) > SO \(_4^{2-}>\) NO \(_3^- \) > F^? at low topography. With PCA, an effective tool for the spatial controlling processes of groundwater contamination, a subset of explored wells is indexed for continuous monitoring to optimize the expensive effort.     

Time-temperature-transformation (TTT) analysis of cation disordering in omphacite

The kinetics of cation disordering in a natural ordered (P2/n) omphacite have been followed at P=18 and 30 kb, T= 750–1,260° C, for times of between 1.5 min and 16 days in a piston-cylinder apparatus. Time-temperature-transformation (TTT) analysis of the experimental data, using the presence or absence of the 11¯1 reflection in single crystal X-ray precession photographs to indicate the extent of reaction, yields an equilibrium order/disorder temperature (T _ord) of 865±10° C, an activation enthalpy (1 bar) of 71±6 kcal mole^–1 and an activation volume of 9±4 cm³ mole^–1 (plus and minus figures represent the precision of a best fit between experimental data and TTT theory rather than absolute errors). The activation volume is consistent with a vacancy mechanism of cation diffusion. H₂O, added in the form of oxalic acid, appears to speed the process up slightly. The overall transformation mechanism is continuous, involving neither the nucleation of a disordered phase nor a change in antiphase-domain distribution. This is consistent with both first- and non-first-order character for the C2/cP2/n transformation, though a range of ordered states below T _ord is indicated by the weakening of h+k=odd reflections. A simple extrapolation of the disordering rates to geological conditions leads to the first estimate of how long disordered omphacites would take to order in nature, ranging from less than one year at T800° C to more than 10⁷ years at T<350° C.     

Cretaceous deformation of the southern Central Andes: synorogenic growth strata in the Neuquén Group (35° 30′–37° S)

The Neuquén Group is an Upper Cretaceous continental sedimentary unit exhumed during the latest Miocene contractional phase occurred in the southern Central Andes, allowing a direct field observation and study of the depositional geometries. The identification of growth strata on these units surrounding the structures of the frontal parts of the Andes, sedimentological analyses and U–Pb dating of detrital components, allowed the definition of a synorogenic unit that coexisted with the uplift of the early Andean orogen since ca. 100 Ma, maximum age obtained in this work, compatible with previous assignments and constrained in the top by the deposition of the Malargüe Group, in the Maastrichtian (ca. 72 Ma). The definition of a wedge top area in this foreland basin system, where growth strata were described, permitted to identify a Late Cretaceous orogenic front and foredeep area, whose location and amplitude contrast with previous hypotheses. This wedge top area was mostly fed from the paleo‐Andes with small populations coming from sources in the cratonic area that are interpreted as a recycling in Jurassic and Lower Cretaceous sections, which contrasts with other analyses performed at the foredeep zone that have mixed sources. In particular, Permian sources are interpreted as coming directly from the cores of the basement structures, where Neopaleozoic sections are exposed, next to the synorogenic sedimentation, implying a strong incision in Late Cretaceous times with an exhumation structural level similar to the present. The maximum recognised advance for this Late Cretaceous deformation in the study area is approximately 500 km east of the Pacific trench, which constitutes an anomaly compared with neighbour segments where Late Cretaceous deformations were found considerably retracted. The geodynamic context of the sedimentation of this unit is interpreted as produced under the westward fast moving of South America, colliding with two consecutive mid‐ocean ridges during a period of important plate reorganisation. The subduction of young, anhydrous, buoyant lithosphere would have produced changes in the subduction geometry, reflected first by an arc waning/gap and subsequently by an arc migration that coexisted with synorogenic sedimentation. These magmatic and deformational processes would be the product of a shallow subduction regime, following previous proposals, which occurred in Late Cretaceous times, synchronous to the sedimentation of the Neuquén Group.     

School vulnerability to disaster: examination of school closure,demographic, and exposure factors in Hurricane Ike’s wind swath

Damage and destruction to schools from climate-related disasters can have significant and lasting impacts on curriculum and educational programs, educational attainment, and future income-earning potential of affected students. As such, assessing the potential impact of hazards is crucial to the ability of individuals, households, and communities to respond to natural disasters, extreme events, and economic crises. Yet, few studies have focused on assessing the vulnerability of schools in coastal regions of the USA. Using Hurricane Ike’s tropical storm wind swath in the State of Texas as our study area, we: (1) assessed the spatial distribution patterns of school closures and (2) tested the relationship between school closure and vulnerability factors (namely physical exposure and school demographics) using zero-inflated negative binomial regression models. The regression results show that higher probabilities of hurricane strikes, more urbanized school districts, and school districts located in coastal counties on the right side of Ike’s path have significant positive associations with an increase in the number of school closure days. Socioeconomic characteristics were not significantly associated with the number of days closed, with the exception of proportion of Hispanic youth in schools, a result which is not supported by the social vulnerability literature. At a practical level, understanding how hurricanes may adversely impact schools is important for developing appropriate preparedness, mitigation, recovery, and adaptation strategies. For example, school districts on the right side of the hurricane track can plan in advance for potential damage and destruction. The ability of a community to respond to future natural disasters, extreme events, and economic crises depends in part on mitigating these adverse effects.     

Calcium carbonate dissolution in deep sea sediments: reconciling microelectrode, pore water and benthic flux chamber results

We report the benthic fluxes of O₂, titration alkalinity (TA), Ca²⁺, NO₃⁻, PO₄³⁻, and Si(OH)₄ from in situ benthic flux chamber incubations on the Ceara Rise and Cape Verde Plateau and compare them to previously published results. We find within analytical uncertainty that the TA flux is twice the calcium flux, suggesting that dissolution/precipitation of CaCO₃ is the principal mechanism controlling benthic TA and Ca²⁺ fluxes. At sites where the sediments contain significant (>35%) CaCO₃ and the overlying waters are supersaturated with respect to CaCO₃, the ratios of the total dissolution rate to the remineralization rate are significantly less than at all other study sites. We propose that these observations can be explained by precipitation of fresh CaCO₃ at the supersaturated sediment surface followed by redissolution deeper in the sediments because of metabolically-produced CO₂. A numerical simulation is presented to demonstrate the feasibility of this explanation. In addition, surface exchange reactions in high-CaCO₃ sediments coupled with high rates of particle mixing may also impact rates of metabolic dissolution and depress chamber-derived estimates of carbonate alkalinity and calcium benthic fluxes. These results suggest that at supersaturated, high CaCO₃ locations, previous models of sediment diagenesis may have overestimated the impact of metabolic dissolution on the preservation of CaCO₃ deposited on the sea floor.     

Well placement optimization subject to realistic field development constraints

This work considers the well placement problem in reservoir management and field development optimization. In particular, it emphasizes embedding realistic and practical constraints into a mathematical optimization formulation. Such constraints are a prerequisite for the wider use of mathematical optimization techniques in well placement problems, since constraints are a way to incorporate reservoir engineering knowledge into the problem formulation. There are important design limitations that are used by the field development team when treating the well placement problem, and these limitations need to be articulated and eventually formalized within the problem before conducting the search for optimal well placements. In addition, these design limitations may be explicit or implicit. In this work, various design limitations pertaining to well locations have been developed in close collaboration with a field operator on the Norwegian Continental Shelf. Moreover, this work focuses on developing constraint-handling capability to enforce these various considerations during optimization. In particular, the Particle Swarm Optimization (PSO) algorithm is applied to optimize for the well locations, and various practical well placement constraints are incorporated into the PSO algorithm using two different constraint-handling techniques: a decoder procedure and the penalty method. The decoder procedure maps the feasible search space onto a cube and has the advantage of not requiring parameter tuning. The penalty method converts the constrained optimization problem into an unconstrained one by introducing an additional term, which is called a penalty function, to the objective function. In contrast to the penalty method, only feasible solutions are evaluated in the decoder method. Through numerical simulations, a comparison between the penalty method and the decoder technique is performed for two cases. We show that the decoder technique can easily be implemented for the well placement problem, and furthermore, that it performs better than the penalty method in most of the cases.     

GMOS spectroscopy of the S0 galaxy NGC 3115

We present Gemini Multi-Object Spectrograph longslit spectroscopy of the isolated S0 galaxy NGC 3115. We have determined kinematical data and Lick/IDS absorption line-strength indices for the major axis out to around 9 kpc and for the minor axis out to around 5 kpc (around 2R _e ). Using stellar population models which include the effects of variable [α/Fe] ratios, we derive metallicities, abundance ratios and ages for the stellar population of NGC 3115. We find that [α/Fe] remains fairly constant with increasing radius at around  [α/Fe]= 0.17  for the major axis but increases rapidly for the minor axis to around  [α/Fe]= 0.3  . We also find that to first order, this behaviour can be explained by a simple spheroid + disc model, where the spheroid has  [α/Fe]= 0.3  and the disc shows close to solar abundance ratios. The disc also appears considerably younger than the spheroid, having an age of around 6 Gyr compared to 12 Gyr for the spheroid. We compare these results to those previously presented for the globular cluster system of NGC 3115.