Interactions among metals in the spectrochemical determination of trace amounts of cadmium in marine mussels

The determination of trace amounts of inorganic elements by electrothermal atomic absorption spectrophotometry (ETA-AAS) or inductively coupled plasma atomic emission spectrometry (ICP-AES) suffers from some kinds of interference due to the inorganic fraction of the matrix of many environmental samples. The ratio between a major matrix element and the analyzed trace element plays an important role in the spectrochemical behaviour of the latter. The resulting enhancing or depressing effect also gives rise to severe faults when the well known standard addition method (SAM) is used. The present work shows the interactions due to the presence of elements such as calcium, sodium, potassium, magnesium and iron during the spectrochemical determinations of trace amounts of cadmium in marine mussels. A possible liquid anion exchange extraction is suggested for the analysis of cadmium by ETA-AAS.     

Tectonics of short-offset,slow-slipping transform zones in the FAMOUS area,Mid-Atlantic Ridge

ANGUS photographs and ALVIN observational data from Fracture Zones A and B on the Mid-Atlantic Ridge near 37°N were examined for structural and sedimentological indications of the area's tectonics. Both transform fault zones are characterized by volcanic rubble, breccias, chalks, and undisturbed sediments typical of slow-slipping transforms.The photographic data consist of 16 camera-sled traverses from the FAMOUS Expedition using the ANGUS deep-towed camera system. These data cover several different morphotectonic provinces along the strike of both slow-slipping (2 cm yr^-1) fracture zones. ALVIN data come from two dives in the central part of Fracture Zone B. The two fracture zones differ in their distribution of fractured and sheared chalks which indicate regions of strike-slip deformation along the transform. Evidence of shearing is confined to a very narrow region in the center of FZ A, whereas the zone of shear deformation is as much as 6 km wide across FZ B. Other differences include the morphology and depth of the transform valleys and their contiguous nodal basins and the extent of exposures of fresh-looking volcanic ridges in the nodal basin.     

Monitoring the status of a mechanical cable while in operation by means of the acoustic emission method

The mechanical cable is an essential element in towing operations, remote control of equipment, salvage operations, civil engineering applications, etc.Failure of these cables can result in loss of life and loss of equipment worth hundreds of thousands of dollars. Obviously then, sensors that can indicate the condition of these cables so that the risk to their continued use and their remaining safe life can be determined when in operation are very important from the point of view of commercial and military interest.This paper presents a brief review of research into failure mechanisms of various cables and the acoustic emission signatures of the various cables under simulated loading. The development of a specific operational monitor for a towed cable system is also given.     

Field Placement and Evaluation of Stabilized Dredged Material (SDM) from the New York/New Jersey Harbor

Since the 1997 local ban on ocean dumping of dredged sediments, the States of New York and New Jersey have pursued a policy of environmentally sound solutions to the management of dredged material, including beneficial use of stabilized dredged material (SDM) in transportation applications. A pilot study was initiated in 1998 to evaluate the use of SDM in the construction of highway embankments. Utilizing 80,000 cubic yards of dredged material, two embankments were constructed from SDM on a commercial development area adjacent to the Harbor. Geotechnical properties and handling of SDM were evaluated both during and one year post - construction. This article presents the evaluation of the embankments themselves, including constructability and performance. The results demonstrate that SDM satisfies most of the geotechnical criteria for fill construction, except those for durability, requiring proper coverage and protection similar to that provided for fills constructed on cohesive soils. This same characteristic precludes long term stockpiling of SDM prior to final placement, limiting applications to those that have schedules overlapping with dredging projects. Increased costs for the use of SDM can be as high as $8 per cubic yard over traditional fills; however, this cost may be recouped through management fees collected from dredging projects.     

Condition of coastal mesoplankton communities in the northeastern area of the Black Sea in 2005

The structure and distribution of mesoplankton in the northeastern part of the Black Sea along 6-mile and 100-mile sections in the area off Golubaya Bay (near the city of Gelendzhik) were analyzed. The studies were performed from R/V Akvanavt and the boat Ashamba. The observations were carried out during the vegetation season from the beginning of June to the first half of October 2005. Samples of mesoplankton were collected with use of a BSD net with an opening of 0.1 m² and a mesh size of 180 μm. Both the total (over the entire water column) and layer-by-layer (separately for the upper quasi-homogeneous layer, the seasonal thermocline, and the subthermocline layer) hauls were performed down to the bottom (at sea depths of less than 200 m) or down to the upper boundary of the hydrogen sulfide waters. The particular hydrophysical conditions that were observed in 2005 resulted in an approximately one-month advance of the phenological condition of the planktonic community as compared to the usual pattern. Beroe ovata appeared in the plankton at the end of July, the mass development of Mnemiopsis leidyi was suppressed, and the duration of its influence on edible zooplankton was essentially reduced. As a result, the total mesoplankton biomass in August–October 2005 was 1.5–2 times as great as that in 2004. The abundance of Acartia clausi increased approximately 4–5 times and the quantity of Sagitta setosa also considerably increased. At selected stations, Mnemiopsis leidyias, the main predator in the community, was replaced by Sagitta setosa.     

Adaptive optimal control of an autonomous underwater vehicle in the dive plane using dorsal fins

In this paper, adaptive control of low speed bio-robotic autonomous underwater vehicles (BAUVs) in the dive plane using dorsal fins is considered. It is assumed that the model parameters are completely unknown and only the depth of the vehicle is measured for feedback. Two dorsal fins are mounted in the horizontal plane on either side of the BAUV. The normal force produced by the fins, when cambered, is used for the maneuvering. The BAUV model considered here is non-minimum phase. An indirect adaptive control system is designed for the depth control using the dorsal fins. The control system consists of a gradient based identifier for online parameter estimation, an observer for state estimation, and an optimal controller. Simulation results are presented which show that the adaptive control system accomplishes precise depth control of the BAUV using dorsal fins in spite of large uncertainties in the system parameters.     

Numerical Simulation of Wind Currents and Propagation of Impurities in the Balaklava Bay

We present the results of numerical experiments aimed at the simulation of the circulation of waters and transport of impurities in the Balaklava Bay for typical wind conditions established on the basis of the analysis of the data of in-situ measurements. The currents are computed by using the nonlinear σ-coordinate model. The specific features of the integral circulation and three-dimensional structure of the current field are investigated. The statistical characteristics of currents are estimated on the basis of the in-situ data on winds and model calculations. Possible scenarios of propagation of impurities from the coastal sources are analyzed for various hydrodynamic conditions. It is shown that the localized eddy structures in the current fields (in combination with the zones of intense vertical motion) can result in a complex character of the transport of substances in the bay and lead to the formation of local regions of maximum concentrations of impurities on the boundary of the north and central parts of the bay. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 4, pp. 43–58, July–August, 2005.