Field scale heterogeneity of redox conditions in till-upscaling to a catchment nitrate model

Point scale studies in different settings of glacial geology show a large local variation of redox conditions. There is a need to develop an upscaling methodology for catchment scale models. This paper describes a study of field-scale heterogeneity of redox-interfaces in a till aquitard within an area of 600?×?600 m. The results showed significant variation of the depths to the redox-interface and thickness of the aquitard. Nitrate was present above the redox-interface but reduced to non-detectable levels a few metres below the interface. An upscaling approach for an area of 92 km² is proposed. Two models are proposed to predict the depth to the redox-interface in the aquitard and the resulting nitrate recharge concentrations to an underlying aquifer. The first model assumes that the depth to the redox-interface reflects the hydraulic head in the aquitard, and the second model assumes that the depth of the redox-interface is randomly distributed according to a log-normal probability distribution function. The upscaling approach using the random redox model estimated recharge concentrations comparable to the observed concentration in the underlying aquifer. The presented upscaling approach is applicable in distributed catchment models where sub-grid variability cannot be represented by the large grids.     

New data on the present-day active fluid regime of fractured zones of crystalline basement and sedimentary cover in the eastern part of Volga-Ural region

The study area is the South Tatarstan Arch located in the Volgo-Ural Region, which is an enigmatic crustal segment occupying one third of the East European Platform. Monitoring studies have shown that fluid discharge processes are still active and time-dependent. This paper presents an integrated review of the geological, geophysical, hydrochemical and geochemical studies of the crystalline basement of Tatarstan. These studies are based on the stratigraphic and compositional schemes within the crystalline basement, the drilling of deep wells, the geodynamic activity of the fractured zones of the crystalline basement and the presence of fluids therein. Furthermore, the changes in the chemical composition of the basement waters are taken into account.     

Groundwater flow modeling for effective implementation of landslide stability enhancement measures

This paper deals with groundwater hydrology at a prominent fracture zone landslide slope (Nuta–Yone landslides) in Japan with an objective to explore an efficient method for the application of landslide stability enhancement measures. The correlation analyses between the hydrological parameters and ground surface movement data at this landslide resulted in low correlation values indicating that the geological formation of the area is extremely complex. For the purpose of understanding the groundwater flow behavior in the landslide area, a three-dimensional transient groundwater flow model was prepared for a part of the landslide slope, where the levels of effectiveness of applied landslide stability enhancement measures (in the form of multilayered deep horizontal drains) are different, and was calibrated against the measured water surface elevations at different piezometer locations. The parameter distributions in the calibrated model and the general directions of the groundwater flow in terms of flow vectors and the results of particle tracking at the model site were interpreted to understand the reasons for variations in effectiveness of existing landslide stability enhancement measures and to find potentially better locations for the implementation of future landslide stability enhancement measures. From the modeling results, it was also understood that groundwater flow model can be effectively used in better planning and locating the landslide stability enhancement measures.     

Nutrient Mass Flux between Florida Bay and the Florida Keys National Marine Sanctuary

There is a net discharge of water and nutrients through Long Key Channel from Florida Bay to the Florida Keys National Marine Sanctuary (FKNMS). There has been speculation that this water and its constituents may be contributing to the loss of coral cover on the Florida Keys Reef tract over the past few decades, as well as speculation that changes in freshwater flow in the upstream Everglades ecosystem associated with the Comprehensive Everglades Restoration Plan may exacerbate this phenomenon. The results of this study indicate that although there is a net export of approximately 3,850 (±404) ton N year^?1 and 63 (±7) ton P year^?1, the concentrations of these nutrients flowing out of Florida Bay are the same as those flowing in. This implies that no significant nutrient enrichment is occurring in the waters of the FKNMS in the vicinity of Long Key Channel. Because of the effect of restricted southwestward water flow through Florida Bay by shallow banks and small islands, the volume of relatively high-nutrient water from central and eastern portions of the bay exiting through the channel is small compared to the average tidal exchange. Nutrient loading of relatively enriched bay waters is mediated by tidal exchange and mixing with more ambient concentrations of the western Florida Bay and Hawk Channel. System-wide budgets indicate that the contribution of Florida Bay waters to the inorganic nitrogen pool of the Keys coral reef is small relative to offshore inputs.     

Sediment Organic Carbon in Todos Santos Bay, Baja California, Mexico

Sediment grain size and organic carbon (OC) data collected over the past 50 years, together with δ¹³C values of OC in recently collected samples, were analyzed to improve understanding of sediment OC distribution and abundance in Todos Santos Bay. Sediments in the submarine canyon at the mouth of the bay and in quiet-water locations along the shore are fine grained, high in OC, and have generally low δ¹³C values; sediments in high-energy environments are low in OC and have high δ¹³C values. A bivariate isotopic mixing model indicates that none of the sediments contain >50% terrigenous OC (average ~30%), and that the terrigenous OC content of the sediments is a small proportion of the OC content of local soils. Sediment OC composition is apparently controlled by energy-related sorting and deposition, oxidation of much of the original terrigenous OC, and replacement of some terrigenous OC by marine OC.     

A New Algorithm for Wind-Vector Retrieval From Scatterometers

A new efficient algorithm for retrieving wind-vector solutions from scatterometers is developed based on a criterion of minimum normalized standard deviation (NSD) of wind speed derived from backscatter measurements using a geophysical model function (GMF). Its performance has been evaluated through simulations using QSCAT-1 GMF and the QuikSCAT observational geometry. The present algorithm, named the NSD algorithm, is found to be computationally more efficient (two to three times) besides being at par with the maximum-likelihood estimator (MLE) algorithm in terms of retrieval skill, retrieval errors, and distribution of solutions, on the basis of simulations as well as comparison of limited QuikSCAT-data-derived winds with National Centers for Environmental Prediction and European Centre for Medium-Range Weather Forecasts model winds. Simulation results and analysis of sample QuikSCAT data are presented.      

Transient and spatial modeling and simulation of polybrominated diphenyl ethers reaction and transport in air, water and soil

The release of the wastes containing polybrominated diphenyl ethers into the environment is a worldwide major concern. Investigation of spatial and temporal variations of polybrominated diphenyl ethers concentrations due to different factors, especially the transport of these species between air and water as well as between air and soil is the purpose of present research. A model was developed and solved using the methods of finite difference and lines. Simulations were implemented for three dimensions of width, length, and height and also time for the air compartment, whereas for the soil and water compartments, variations were considered only with respect to height and time. Transport between water and soil was disregarded for simplicity at this stage. Vancouver’s landfill was considered as a case study. Lower concentrations in air and higher concentrations in water at the interface show that these pollutants tend to diffuse from air to water. Concentrations of all four pollutants decrease near the interface in soil as time passes, but they are predicted to be almost constant at other levels.     

Modeling study of the effects of the coagulation kernel with van der Waals forces and turbulence on the particle size distribution

In this study, variations in the size distributions due to different assumptions for the coagulation kernel are investigated. In order to evaluate how the coagulation kernel influences the form of the particle size distribution and to describe the process of the Brownian coagulation, the Brownian coagulation kernel, including the van der Waals forces, is compared with the most frequently used coagulation coefficients. Retardation should be considered for interparticle interactions for particles larger than 1μm radius. However, for particle sizes larger than 0.1 μm, the Brownian kernel is not dominant, so the retardation effect can be ignored. The inclusion of the van der Waals forces in the Brownian coagulation kernel caused a faster coagulation process in the small particle size range. Taking account of the turbulent coagulation kernel, the turbulent coagulation kernel becomes more important when the turbulent intensity is higher. The turbulent coagulation kernel affects the large particle size range and ignoring the turbulent coagulation kernel will lead to overestimation of particle number concentration in model simulation. The results of this study indicate that the inclusion of van der Waals forces or the turbulent coagulation kernel in the total coagulation kernel impacts on the modeled particle size distributions and total particle number concentration.     

First finds of Late Tithonian and middle-late Albian radiolarian assemblages in volcanogenic-siliceous rocks of the Amur River right lower reaches and their tectonic significance

The lithological-stratigraphic study of volcanogenic-siliceous rocks developed on the left side of the Machtovaya River, a right tributary of the Amur River, yielded the first radiolarian assemblages of the late Late Tithonian, the late Late Tithonian-early Valanginian, and the middle-late Albian age. It is established that the stratigraphic succession of volcanogenic-siliceous rocks in this area is composed of upper Tithonian-Valanginian dark red to red-brown cherts with basalts in the lower part of the section and Albian dark gray clayey cherts, olive-gray siliceous-tuffaceous argillites, and tufaceous siltstones in its upper part. The replacement of cherts by their clayey varieties likely occurred in the Aptian. The composition, structure, and age of these strata and the rocks constituting the Kiselevka-Manoma accretionary complex are different, which indicates their different tectonic origin.