Chemical processes and interactions involving marine organic matter

The concepts which have guided our thinking about chemical processes and interactions of organic matter in seawater are identified and their utility assessed. Some recommendations for the future are made.     

Estimation of the oxygen and CO2 mean exchange between the ocean and the atmosphere in key areas of the ocean

Current estimations of gas exchange between the ocean and the atmosphere are based on the concepts about diffusive gas transfer across the interface and about a stationary character of the processes; however, under a strong wind, these concepts are invalid. Transfer equations for gas constitutents of the air are incorporated into a numerical model of a nonstationary upper layer of the ocean. These equations contain the source function—gas transfer by bubbles, which becomes noticeable even at a wind speed of 8–10 m/s. The fluxes of oxygen and CO₂ are calculated at a specified wind speed, dependences of these fluxes on the wind speed are constructed, and estimates for the average annual fluxes are obtained for several areas of the Gulf Stream and Kuroshio. A substantial change in the difference of the air-water gas contents under a strong wind, caused by the turbulent exchange growth and appreciably affecting the gas exchange, is noted. The influence of the carbonate system of seawater on the CO₂ transfer during a storm is estimated. The results obtained are compared to the estimates based on the traditional approach.     

Problems of modeling climate and climate change

The properties of the climate system as a physical object are considered. Major concepts of the mathematical theory of climate are stated, and the problems of constructing mathematical climate models are discussed. The results of reproducing the present-day climate are analyzed, and the sensitivity of the climate system to changes in the content of greenhouse gases is considered. Major directions are formulated in which the development of the mathematical theory of climate and of modeling climate and climate change is possible.     

A low level supplementary heating system for free divers

A simple and effective method of heating divers in extreme cold water has been developed. The local heating concept utilizes a uniformly distributed granular mixture of magnesium and iron particles packed in small sachets. Upon activation by sea water, the two metal mixture behaves as a multitude of short-circuited electrolytic cells, producing thermal energy rather than electrical energy. The 45 mm-square sachets may be placed where heating is required on the diver's body, thus giving rise to the term “local heating”, obviously, the heating system requires no pumping device, or distribution network. Heating rate and duration of output of the sachets are controlled by particle size, and mixture ratio of the constituent Mg and Fe particles.This paper described the development, testing and performance of the heating sachets. Results of live tests in different dive situations are also presented and discussed.     

Current-influenced depositional provinces, continental margin off Cape Hatteras, identified by petrologic method

Analyses of DSRV “Alvin” core samples on the Cape Hatteras margin indicate major textural and compositional changes at depths of about 1000 and well below 2500 m. The distribution patterns of petrologic parameters correlate well with water mass flow and suspended-sediment plumes measured on this margin by other workers. Our study also shows: (a) vigorous erosion and sediment transport at depths of less than 400 m resulting from the NE-trending Gulf Stream flow; (b) deposition, largely planktonic-rich sediment released from the Gulf Stream, on the upper- to mid-slope, to depths of about 800–1200 m; (c) winnowing, resuspension and deposition induced by periodically intensified slope currents on the mid-slope to uppermost rise, between about 1000 and 2500 m; and (d) prevailing deposition on the upper rise proper (below 2500 m), from transport by the SW-trending Western Boundary Undercurrent. Sediments moved by bottom currents have altered the composition and distribution patterns of material transported downslope by offshelf spillover; this mixing of gravity-emplaced and bottom-current-transported sediment obscures depositional boundaries. Moreover, reworking of the seafloor by benthic organisms alters physical properties and changes erodability of surficial sediments by bottom currents. Measurement of current flow above the seafloor and direct observation of the bottom are insufficient to delineate surficial sediment boundaries. Detailed petrologic analyses are needed to recognize the long-term signature of processes and define depositional provinces.     

Effects of water-borne copper on metallothionein and lipid peroxidation in the marine amphipod Gammarus locusta

The aim of the current work was to determine over 10 days the effects of water-borne exposure of the marine amphipod Gammarus locusta to 4 microgCu l(-1) on the metallothionein (MT; measured by differential pulse polarography) protection system and lipid peroxidation (LP: thiobarbituric acid-reactive malondialdehyde equivalents) as a measure of oxidative damage. MT levels in exposed animals increased significantly at day 2 (36% > control; P < 0.001) and remained high at days 6 and 10 (55 and 38%, respectively, P < 0.001). The maximum level of MT at day 6 coincided with the highest Cu body-burden. LP increased within I day of exposure, indicative of Cu as an oxidative stressor. However, in contrast to MT, the highest LP level was seen at day 4 (68% > control, P < 0.001) before returning to control values by day 6, indicating a protective role of MT against the pro-oxidant effects of Cu.     

Evaluation of long-term extreme response statistics of jack-up platforms

This paper is concerned with the models appropriate for the dynamic assessment of jack-ups, concentrating particularly on the long-term response due to random ocean waves and on work-hardening plasticity models used for spud-can response. A methodology for scaling of short-term statistics, calculated using a Constrained NewWave technique, is shown in a numerical experiment for an example jack-up and central North Sea location. The difference in long-term extreme response statistics due to various footing assumptions is emphasised. Results for two environmental load conditions are described (one excluding and one including wind and current effects) and the role of sea-state severity in the variation of short-term extreme response statistics is also highlighted.     

Filters for linear sea-wave prediction

Deterministic sea-wave prediction (DSWP) models are appearing in the literature designed for quiescent interval prediction in marine applications dominated by large swell seas. The approach has focused upon spectral methods which are straightforward and intuitively attractive. However, such methods have the disadvantage that while the sea is aperiodic in nature, the standard discrete spectral processing techniques force an absolutely periodic structure onto the resulting sea surface prediction models. As it is the shape of the sea surface that is important in such applications, particularly near the end of the domain which is important, the standard windowing techniques used in signal processing work to reduce leakage artifacts cannot be employed. This has necessitated the use of end matching methods that can be both inconvenient and may reduce the fraction of the time for which legitimate predictions are available. As a result, an investigation has been undertaken of the use of finite impulse response prediction filters to provide the necessary dispersive phase shifting required in DSWP systems. The present work examines the theoretical basis for such filters and explores their properties together with their application to both long and short crested swell seas. It is shown that wide band forms of such filters are only convergent in the sense of distributions having both infinite duration impulse responses and asymptotically divergent first derivatives. However, appropriate band limitation can produce useful finite impulse responses allowing implementation via standard discrete convolution methods. It is demonstrated that despite the prediction filters having a non-causal impulse response such filters can be used in practice due to a combination of the asymmetric nature of the impulse response and the fundamental nature of the prediction process. The findings are confirmed against actual sea-wave data.