Spectrophotometric determination of pH in seawater off Taiaroa Head,Otago, New Zealand: Full-spectrum modelling and prediction of pCO2 levels

Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25].     

Stratigraphy and inversion tectonics in the St. Georges Channel area off SW Wales,U.K.

Transgressive Upper Cretaceous Chalk terminates (between SW Wales and SE Ireland) at approximately latitude 52°N as thinly bedded marginal facies; while the Tertiary sequences, previously considered to extend uninterrupted into both the South Celtic Sea area and the Nymphe Bank basin are preserved as isolated subcrops separated by Jurassic. The distinct subsidence history of St. Georges Channel basin, as compared to the Nymphe Bank basin which both belong to the North Celtic Sea graben, is attributed to inversion activity with the final phase occurring during the Paleogene.     

Geochemical variation in ferromanganese nodules and associated sediments from the Pacific Ocean

The major and minor element compositions of a suite of abyssal sea-floor ferromanganese nodules and associated sediments from the eastern central Pacific have been used to examine inter-element relationships and the mineralogy of the nodules, the relationship between the composition of nodules and their associated sediments and regional variations in composition with respect to likely modes of formation of such deposits. Apart from Mn and Fe, significant proportions of the total Ti, Ca, Mg, K, Ba, Sr, Th and Y and almost all the P, As, Ce, Co, Cu, Mo, Ni, Pb, Zn and Zr are present in the oxide fractions of the nodules. The Mg, Ba, Cu, Mo, Ni and Zn contents are significantly correlated with the Mn content, while Ti, P, As, Pb, Sr, Y and Zr are similarly correlated with the total Fe content.Nodules from the northeastern tropical Pacific have Mn/Fe ratios higher than those in the oxide fractions of their associated sediments, todorokite as the principal Mn phase and relatively high concentrations of minor elements associated with Mn. Nodules from the south central Pacific have Mn/Fe ratios similar to those in the oxide fractions of the associated sediments, δ-MnO₂ as the only Mn-phase, and relatively high concentrations of minor elements associated with Fe. There appears to be a smooth gradation in composition in the tropical Pacific between these two end members.The regional compositional variation is interpreted as a reflection of different sources of metals for, and different growth mechanisms of, sea-floor nodules. The oxide precipitate from sea water consists of δ-MnO₂, has a relatively low Mn/Fe ratio and minor element contents related to the total Fe and Mn(δ-MnO₂) content. The oxide precipitate forming in areas of very low sedimentation as a result of diagenetic remobilisation in the surface sediment consists of todorokite, and has a high Mn/Fe ratio and enhanced metal content in the Mn-(todorokite)phase. Available information on the morphology and compositional variation of individual nodules from the tropical Pacific corroborates these contrasting metal sources and suggests that they can be resolved on the scale of an individual oxide concretion.     

Stellar flare statistics — Physical consequences

The observational data permit us to establish clear statistical correlations between different parameters of stellar flare activity and the characteristics of quiet stars. These relations are:

1. between energies and frequencies of flares on stars of different luminosities;
2. between total radiation energies of flares and quiet stars both in X-ray and Balmer emission lines;
3. between flare decay rates just after the maxima and flare luminosities at maxima.

     

Motions in the field of two rotating magnetic dipoles. III: Zero-velocity curves and surfaces

The zero-velocity curves and surfaces created by two parallel or antiparallel magnetic dipoles moving on concentric circles are computed. It is found that for all combinations of values of the mass parameter µ and the ratio of the magnitudes of the magnetic moments of the two dipoles, there exist closed regions inside of which charged particles are permanently trapped.     

Optical interferometric observations of a transient event of 1986 March 13 in the coma of Comet Halley

During the recent apparition of Comet Halley in 1985-86 a transient ionic event in the form of a blob of H₂ O⁺ emission was recorded in thecoma at ～ 0^h UT on 1986 March 13. Observations were carried out using a special IHW filter for H₂ O⁺ emission at 7000 å/175 å, a 35 cm telescope, a Fabry-Perot interferometer and an image intensifier camera from Gurushikhar, Mt Abu. (24?39’N,72? 47’E). A Fabry-Perot inter-ferogram in Ha taken a few minutes later at the same location reveals strong hydrogen emission (Hα) associated with the blob. The velocity field in the blob is structured with relative velocities upto ～ 35km s^?1. The event is interpreted as arising due to the sector boundary crossing of the interplanetary magnetic field by the comet     

The University of Durham Southern Hemisphere VHE gamma ray telescope

The design of very high energy (VHE) gamma ray telescopes is discussed and it is shown that a triple-mirror telescope operating in threefold fast coincidence provides an effective instrument. The design, construction and operation of a large VHE gamma ray telescope with an energy threshold of 300 GeV (at the zenith) and incorporating several novel features is described. The use of a coincidence guard ring technique is shown to result in the rejection of about 50% of the off-source (proton) events which form a high background and limit the sensitivity of such telescopes.     

Photometry of the bright stars inside and outside associations in the spiral arm S5 of the andromeda galaxy

Photometry of more than 1000 bright stars of 20 associations and some fields in its vicinity is made, usingUBV plates taken with a 2-m Ritchey-Chrétien telescope of the National Observatory at the Bulgarian Academy of Sciences with limited magnitudes of about 20.6 inU andV, 21.6 inB. The colour-magnitudes of about 20.6 inU andV, 21.6 inB. The colour-magnitude and colour-colour diagrams of 12 associations and 8 fields are constructed and the brightest blue and red stars colour excesses, ages, and integrated luminosities of the associations are determined. The composite diagrams for all association and nonassociation measured stars are constructed too. Inside associations bright stars as well as non-stellar objects occur more often than outside. The brightest stars in S5 are withM _v7 and do not differ considerably from the brightest ones in the spiral arm S4 of M31. Approximately the same are the absolute magnitudes of the brightest stars in our Galaxy and M33. A small difference between the brightest stars of the latter galaxy with those of M31 is possible because the stars in M33 are younger. This is in agreement with the concept that Sc galaxies (for example M33) are younger than Sb ones (for example M31). The same could be the reason for the smaller ratio of blue to red supergiants in M33 than in M31. The age estimations of the associations in S5 together with those in S4 in M31 show that they are older than the associations in M33 which is in agreement with the above mentioned concept.     

Studies on post-flare loop prominence of 1981 April 27

By use of the H observations of the Astrophysical Observatory in Catania, Italy and the Purple Mountain Observatory in Nanking, China as well as hard X-ray and gamma-ray burst data from the Solar Maximum Mission (SMM) Gamma-Ray Spectrometer (GRS), a major eruptive loop prominence was studied during the limb solar flare event of 1981 April 27.Our preliminary analysis shows that there seems to exist a second abrupt energy release for this event, almost 20 min after the end of the impulsive phase of the flare. This energy release is probably associated with the rapidity in upward motion or activation of the loop prominence.A possible candidate for such a process could be the reconnection of the old magnetic field with a newly emerging magnetic field.A theoretical gross estimate for the energy release and particle acceleration has also been made in this work. It appears that the proposed model for charged particle acceleration is very efficient.     

The U.S. National 8 m telescope project

The National Optical Astronomy Observatories (NOAO) are planning to buld two 8 m telescopes, one for Mauna Kea, Hawaii, the other for a site in Chile. Optical configurations, primary mirror systems, and the telescope mounting are discussed. A new optical testing method is outlined. The system imaging goal is 0.25 FWHM. Construction could begin in the early 1990's.Paper presented at the Symposium on the JNLT and Related Engineering Developments, Tokyo, November 29–December 2, 1988.Operated by the Association of Universities for Research in Astronomy Inc., under contract with the National Science Foundation.