Trends in the solubility of iron,aluminium, manganese and phosphorus in aerosol collected over the Atlantic Ocean

The solubility of iron, aluminium, manganese and phosphorus has been determined in aerosol samples collected between 49°N and 52°S during three cruises conducted in the Atlantic Ocean as part of the European Union funded IRONAGES programme. Solubilities (defined at pH 4.7) determined for Fe and Al in samples of Saharan dust were significantly lower (medians 1.7% and 3.0%, respectively) than the solubilities of these metals in aerosols from other source regions (whole dataset medians 5.2% and 9.0%, respectively). Mn solubility also varied with aerosol source, but the median solubility of Mn in Saharan dust was very similar to the median for the dataset as a whole (55% and 56%, respectively). The observed solubility of aerosol P was ∼ 32%, with P solubility in Saharan aerosol perhaps as low as 10%. Laboratory studies have indicated that aerosol Fe solubility is enhanced by acid processing. No relationship could be found between Fe solubility and the concentrations of acid species (non-seasalt SO₄²⁻, NO₃⁻) nor the net acidity of the aerosol, so we are unable to confirm that this process is significant in the atmosphere. In terms of the supply of soluble Fe to oceanic ecosystems on a global scale, the observed higher solubility for Fe in non-Saharan aerosols is probably not significant because the Sahara is easily the dominant source of Fe to the Atlantic. On a smaller scale however, higher solubility for aerosol Fe may alter our understanding of Fe cycling in regions such as the remote Southern Ocean.     

Experimental study of the breaking limit of multi-directional random waves passing over an impermeable submerged breakwater

This study investigates experimentally the breaking wave height of multi-directional random waves passing over an impermeable submerged breakwater. Experiments have been conducted in a three-dimensional wave basin equipped with a multi-directional random wave generator. A special type of wave gauge has been newly devised to record the water surface elevations in the breaker zone as accurately as possible. The records are analyzed to estimate the location and limit of wave breaking. Comparisons have also been made with the results of regular waves. The influence of the incident wave conditions on the breaking wave height normalized by the breakwater dimensions has been investigated. Empirical formulae have been presented to estimate the breaking limit of multi-directional random waves based on the experimental records. The formulae have been tested and found to work well not only for multi-directional random waves, but for regular waves as well.     

Study of macroaggregate composition using FT-IR and H-NMR spectroscopy

Mucous macroaggregates, recently observed in the northern Adriatic in summer of 1997 and late spring of 2000, are primarily the product of phytoplankton (diatom) exudates during favourable environmental conditions in late spring, and can be viewed as macrogels. The FT-IR and ¹H-NMR spectra of macroaggregate samples from the northern Adriatic, collected in different formation stages in July 1997, August 1997, September 1997 and June 2000, as well as of cultured diatom Skeletonema costatum, showed that they are similar and composed of aliphatic components and polysaccharides bonded through carboxylic and amide groups, and organosilicon compounds. The stability of macrogels of macroaggregates is, according to FT-IR and X-ray analyses, most probably enhanced by interactions with entrapped particles of calcite, quartz and clay minerals. These organic-mineral associations seem to be important for mucous phenomena. According to ¹H-NMR spectra, the temporal differences in macroaggregate composition show a relative increasing percentage of organosilicon compounds and aliphatic components bonded to carbohydrates through ester and amide groups, and an increasing ratio between aliphatic structures and carbohydrates. This indicates that aliphatic chains bonded to Si and carbohydrates may contribute to the persistence and stability of macroaggregates in the summer stratified waters in the northern Adriatic, while the temporal decrease of carbohydrate content is most probably due to microbial and photochemical degradation of algal reserve polysaccharides.     

Geochemical cycling in the Hooghly estuary, India

U–Th decay series isotopes, δ¹⁸O and Si measurements in the river estuarine waters and sediments of the polluted Hooghly estuary as well as the surface waters of the Bay of Bengal, its high salinity end member, are reported. Dissolved Si indicates that there are probably two mixing regimes, dissolved U behaviour is nonconservative and δ¹⁸O behaves conservatively in the overall estuarine region. Isotopes of reactive elements, viz. ²³⁴Th and ²¹⁰Po, are removed from the estuarine waters in <2 days and <1 month, respectively, which is due to high suspended matter (30–301 mg l⁻¹). ²²⁸Ra and ²²⁶Ra are profusely released into the estuarine waters in the low to mid-salinity regions.As expected, the opposite trend is observed in the case of estuarine sediments and suspended matter. Reactive isotopes of Th, ²¹⁰Pb and ²¹⁰Po are enriched, whereas Ra isotopes are depleted with respect to their parent nuclides in the estuarine sediments and suspended matter. ²³²Th/Al ratio appears well suited to study the distribution and mixing of the bed load sediments of the Ganga–Brahmaputra (G–B) and the Hooghly rivers with those from other rivers on the Bay of Bengal floor.     

The abyssal bounty fan and lower Bounty Channel: evolution of a rifted-margin sedimentary system

The Bounty Channel and Fan system provides the basis for a model for deep-sea channel and fan development in a rifted continental margin setting. The sedimentary system results from an interplay between tectonics (fan location; sediment source), turbidity currents (sediment supply), geostrophic currents (sediment reworking and distribution) and climate (sea level, and hence sediment supply and type). Today, sediment is shed from the collisional Southern Alps, part of the Pacific/Indo-Australian plate margin, and passes east across the adjacent shelf and into the Otago Fan complex at the head of the Bounty Trough. Paths of sediment supply, and locations of sediment deposition, are controlled by the bathymetry of the Bounty Trough, with axial slopes as high as 37 m/km (2°) towards the trough head, diminishing to around 3.5 m/km (0.2°) along the trough axis. The Bounty Fan is located 800 km further east, where the Bounty Channel debouches onto abyssal oceanic crust at the mouth of the Bounty Trough. The Bounty Fan comprises a basement controlled fan-channel complex with high leveed banks exhibiting fields of mud waves, and a northward-elongated middle fan. Channel-axis gradients diminish from 6 m/km (0.35°) or more on the upper fan to less than 1 m/km (<0.06°) on the lower fan. Parts of the left bank levee and almost the entire middle fan are being eroded and re-entrained within a Deep Western Boundary Current (DWBC), which passes along the eastern New Zealand margin at depths below 2000 m. The DWBC is the prime source of deep, cold water flow into the Pacific Ocean, with a volume of ca. 20 Sv and velocities up to 4 cm/s or greater. The mouth of the Bounty Channel, at a depth of 4950 m at the south end of the middle fan, acts as a point source for an abyssal sediment drift entrained northward under the DWBC at depths below 4300 m. The Bounty Fan probably originated in the early to middle Neogene, but has mostly been built during the last 3 Myr (Plio-Pleistocene), predominantly as climate-controlled sedimentary couplets of terrigenous, micaceous mud (acoustically reflective; glacial) and biopelagic ooze (acoustically transparent; interglacial), deposited under the pervasive influence of the DWBC.     

Investigation of the electromagnetic fields induced by sea wave motion

This paper discusses a theoretical model of the electromagnetic field induced by internal waves of baric origin. Comparison of thein situ data on the differences between the horizontal electrical field potentials conditioned by internal waves in some Black Sea and tropical Atlantic areas and of the results of calculations of the model electrical field's intensity in those areas shows their good agreement. The dependences of the electromagnetic field component amplitudes on the internal waves parameters and sea-bed rock conductivity are considered. Translated by Vladimir A. Puchkin.     

Propulsive performance of three naturally occurring oscillating propeller planforms

A numerical method, the quasi-vortex-lattice method (QVLM), was applied to predict the propulsive performance of three naturally occurring oscillating propellers. These were cetacean flukes for a fin whale (Balaenoptera physalus); white-sided dolphin (Lagenorhynchus acutus); and white whale (Delphinapterus leucas). The fin whale's flukes had the highest aspect ratio (6.1) and moderate sweep angle (31°); the white-sided dolphin's flukes had the highest sweep angle (47°) and lowest aspect ratio (2.7); and the white whale's flukes had moderate aspect ratio (3.3) and the lowest sweep angle (28°). In the numerical simulations, the planforms were assumed to be rigid both in chordwise and spanwise directions, and to be oscillating harmonically in an irrotational, incompressible fluid. Calculation and comparisons of propulsive efficiency and thrust coefficient vs advance ratio for each of the planforms were made in three cases: varied heave amplitude; different pitching axis positions; and varied angular amplitude of pitch.