Source depletion and extent of melting in the Tongan sub-arc mantle

The fluid immobile High Field Strength Elements (HFSE) Nb and Ta can be used to distinguish between the effects of variable extents of melting and prior source depletion of the Tongan sub-arc mantle. Melting of spinel lherzolite beneath the Lau Basin back-arc spreading centres has the ability to fractionate Nb from Ta due to the greater compatibility of the latter in clinopyroxene. The identified spatial variation in plate velocities and separation of melt extraction zones, combined with extremely depleted lavas make Tonga an ideal setting in which to test models for arc melt generation and the role of back-arc magmatism.We present new data acquired by laser ablation-ICPMS of fused sample glasses produced without the use of a melt fluxing agent. The results show an arc trend towards strongly sub-chondritic Nb/Ta (< 17) with values as low as 7.2. Melting models show that large degree melts of depleted MORB mantle fail to reproduce the observed Nb/Ta. Alternatively, incorporation of residual back-arc mantle that has undergone less than 1% melting into the sub-arc melting regime reproduces arc values. However, the extent of partial melting required to produce the composition of the Lau Basin back-arc basalts averages 7%. This apparent discrepancy can be explained if only the lowermost 4 km of the residua from the mantle melt column beneath the back-arc is added to the source of arc magmas. We have identified that the degree of arc/back-arc coupling displayed in the rock record provides an index of the depth of hydrous melting beneath the arc. In this case, this would imply a depth of ~ 75 km for generation of arc magmas, indicating that hydrous melting in the mantle wedge is triggered by the breakdown of hydrous phases in the subducting slab.     

The prospects for modernizing very broadband seismometers

This paper considers the possibilities for modernizing the KSESh broadband seismic station developed earlier at the IPE AS USSR. The goal of the modernization was to extend the frequency and dynamic ranges and to decrease nonlinear distortions. The ways and concrete methods for improving the mechanical construction and electronic components of the station are shown and the intermediate results are described. As preliminary estimates show, there is an opportunity to build devices with the velocimeter response up to 520–540 s periods on the basis of this pendulum.     

Spatial and seasonal distribution of bacterial physiological groups in two reservoirs with different trophic levels

The spatial and seasonal distribution of the viable heterotrophic population and three heterotrophic physiological groups, i.e. ammonifyers, nitrate reducers and sulphate reducers, were studied in two reservoirs in the province of Vizcaya (Spain). Using indicative parameters, both reservoirs were classified as warm monomictics, one hypereutrophic and the other mesotrophic. A direct relation between the size of the bacterial populations and the trophic levels of the reservoirs was observed. Likewise, the distributions of the bacterial populations in the water column are basically different. In the hypereutrophic lake there is a direct relationship between the bacterial distribution and the physical-chemical environment of the reservoir that cannot be observed in the mesotrophic lake.     

Adsorption und Hydrolyse von Methylparathion an Aktivkohle und Adsorberharz Adsorption and Hydrolysis of Methyl Parathion (MPT) on Activated Carbon and Adsorption Resin

Investigating adsorption of methyl parathion on the activated carbons Filtrasorb 400 and F 44 and on the adsorption polymer Wofatit Y 77 we found a stronger adsorption on the carbons at smaller concentration whereas the resin has the larger capacity at higher concentration. Adsorbents were regenerated through hydrolysis of the pesticide at pH = 11.7. The velocity of hydrolysis in the adsorbed state is reduced to a tenth of that in solution. However, a transport resistance in the pores of adsorbents seems to be negligible as may be concluded from the very small measured particle diameter dependence of the velocity constants. In adsorption-regeneration measurements the capacity of the adsorbents stabilized at about 70% of that of the fresh adsorbents.     

A synthetic model for daily streamflow

This paper presents a model for synthesising daily average streamflow data that is suitable for most rivers in Great Britain. The method is based on a linear interpolation of the logorithms of 5-day average flows. The 5-day average flows are produced using N.T. Kottegoda's statistical model (Thesis, Univ. of Birmingham, 1970). The 5-day model preserves the long-term statistical characteristics of the daily data, while the short-term characteristics such as hydrograph shape are imposed by the interpolation method.

A stochastic error term is superimposed on the interpolated daily flows. This term represents the non-deterministic component of the daily time series. The analysis of the observed error terms represents an important part of this paper.

The riverflow in the Severn at Bewdley is used to demonstrate both the analysis of actual data and the generation of synthetic data. The technique is then applied to data from two other rivers with widely differing characteristics to demonstrate the range of the method.     

Phosphorus accumulation rates in metalliferous sediments on the East Pacific Rise

Based on phosphorus, iron and manganese analyses in 16 cores (5 dated) from the crest and flanks of the East Pacific Rise and the Bauer Deep we estimate that phosphorus is being deposited about 20 times faster in metalliferous sediments near the rise crest than in adjacent flank deposits, and about 40 times faster on the crest than in the Bauer Deep. Almost all of the phosphorus on the rise crest is contained in poorly crystallized hydrothermal iron oxyhydroxides, supporting Berner's (1973) proposal of phosphate sorption by these phases. The phosphate is probably derived from seawater, but some hydrothermal contribution cannot be excluded at this time. Flux estimates indicate that metalliferous sedimentation could remove 15–40% of the pre-agricultural river input of dissolved phosphate.     

Helium isotopes in the earth's interior and in the atmosphere: A degassing model of the earth

A first-order degassing model was applied to describe the evolution of helium content and isotope composition in the earth and in the atmosphere. The main events described by the model are: (1) the earth-trapped primordial rare gases at the moment of its accretion; (2) later, the solid earth lost primordial and radiogenic rare gases, and (3) they were accumulated in the atmosphere; (4) in addition,³He was formed in the atmosphere due to cosmic irradiation, accretion from solar wind, etc.; (5)³He and⁴He dissipated into space at different loss rates.Study of this model confirms the concept that some of primordial helium is retained in the interior of the earth; terrestrial helium (³He/⁴He～ 2 × 10^?5) was most probably formed as a mixture of primordial (³He/⁴He= 3 × 10^?4) and radiogenic (³He/⁴He～ 3 × 10^?8) helium. For achondritic concentrations of heavy radioactive elements (U= 2.25 × 10^?8g/g) the calculated⁴He flux from the earth is equal to 5.7 × 10⁶ at cm^?2 sec^?1. The corresponding³He flux is about 114 at cm^?2 sec^?1. In discussing the aeronomic problem of helium it is necessary to take into account that the earth is the main source of the light helium isotope.