The impact of the Laacher See Volcano (11 000 yr B.P.) on terrestrial vegetation and diatoms

Late-glacial lake sediments containing the Laacher See Tephra (LST, 11 000 yr B.P.) have been analyzed for their pollen and diatom content at three sites at varying distances from the volcano and on different bedrock geologies. The aim was to test the null hypothesis that this major volcanic eruption had no effect on terrestrial pollen or aquatic diatom assemblages. The pollen spectra at all sites show a short-lived increase in grass pollen following the LST. Partial redundancy analysis and associated Monte Carlo permutation tests suggest, however, that the LST had no statistically significant effect at two sites but it had a statistically significant impact on the pollen assemblages at the site nearest (60 km) to the volcano.The diatom assemblages at the three sites changed individualistically after the LST deposition, with increases inAchnanthes minutissima at one site, an expansion ofAulacoseira species at another, and an increase ofAsterionella formosa andFragilaria brevistriata at the third site. Partial redundancy analysis and associated permutation tests suggest a statistically significant change in diatoms in relation to the LST and associated changes in sediment lithology at the one site situated on acidic bedrock. No significant impacts were found at the sites on volcanic or calcareous rocks. Due to the interaction between tephra and sediment lithology, it is not possible to conclude if the statistically significant diatom changes were a direct result of the LST deposition or an indirect result of lithological changes following LST deposition.This is the first paper in a series of papers published in this issue on high-resolution paleolimnology. These papers were presented at the Sixth International Paeolimnology Symposium held 19–21 April, 1993 at the Australian National University, Canberra, Australia. Dr A. F. Lotter and Dr. M. Sturm served as guest editors for these papers.     

Derivation of density and temperature from the Cassini–Huygens CAPS electron spectrometer

In this paper we present two methods to derive electron fluid parameters from the CAPS–ELS spectrometer on board the Cassini spacecraft currently in orbit around Saturn. In the first part of the paper we give a basic overview of the instrument and describe the challenges inherent in the derivation of density and temperature values using these techniques. We then describe a method to calculate electron moments by integrating the particle distribution function. We also describe a second technique in which we fit the electron energy spectrum with a Gaussian curve and use the peak energy of this curve to derive density and temperature values. We then compare the two methods with particular emphasis on their application to Cassini SOI observations in the saturnian environment and point out the limitations of the two techniques. We will show that results from the two very different methods are in agreement when the physical properties of the environment and of the observed electron populations have been inferred from inspection of the raw data. Finally we will suggest future developments that will remove these limitations.     

Variation in the flare activity of the star UV Ceti

This is an analysis of the dependence of the flare activity of the well known flare star UV Ceti on the linear distance between the components of this binary system. It is shown that its flaring activity clearly depends on the mutual distance of the components, while this kind of variability is not seen in isolated flare stars.     

Can the unresolved X-ray background be explained by the emission from the optically-detected faint galaxies of the GOODS project?

The emission from individual X-ray sources in the Chandra Deep Fields and XMM – Newton Lockman Hole shows that almost half of the hard X-ray background above 6 keV is unresolved and implies the existence of a missing population of heavily obscured active galactic nuclei (AGN). We have stacked the 0.5–8 keV X-ray emission from optical sources in the Great Observatories Origins Deep Survey (GOODS; which covers the Chandra Deep Fields) to determine whether these galaxies, which are individually undetected in X-rays, are hosting the hypothesized missing AGN. In the 0.5–6 keV energy range, the stacked-source emission corresponds to the remaining 10–20 per cent of the total background – the fraction that has not been resolved by Chandra . The spectrum of the stacked emission is consistent with starburst activity or weak AGN emission. In the 6–8 keV band, we find that upper limits to the stacked X-ray intensity from the GOODS galaxies are consistent with the ∼40 per cent of the total background that remains unresolved, but further selection refinement is required to identify the X-ray sources and confirm their contribution.     

Large-scale solar magnetic field: Latitudinal dependence

Large-scale solar magnetic fields in the latitude range 50° S–50° N are analyzed in detail for a long time interval (1915–1990). We are primarily concerned with the two types of large-scale fields forming the two-and four-sector patterns on the Sun. The rotation parameters of these structures are obtained for all latitudes considered. The contribution of the two-sector structure grows and that of the four-sector structure decreases toward high latitudes. The magnetic field is activated simultaneously over a wide latitude range. Since both magnetic-field systems exhibit quasi-rigid rotation, their current systems must either be concentrated in a narrow latitude range or be situated beneath the convection zone, where rotation is only weakly differential. A period of about three years is manifest in the difference between the rotation periods for the two types of magnetic field. Physically, this may imply that these oscillations are external with respect to any level, and there is some phase delay due to their propagation from one level to another. We can conclude with a fair degree of certainty that as the activity level rises, the rotation speed decreases, and vice versa.     

The use of acidimetric titration as a novel approach to study particulate trace metal speciation and mobility: Application to sediments of the Scheldt estuary

The study of trace metal speciation has benefited from a great deal of interest leading to the development and the diversification of sequential extraction schemes (SES), which triggered the need for harmonization by the standard, measurements and testing programme (SM & T). However, some uncertainties still persist in the application of the harmonized 3-step protocol, because of the difficulty in conceptualizing a technique that can be applied to environmental samples irrespective of their nature. The alternative method proposed in this study is based on the solubility of the sample components progressively dissolved during the course of an acidimetric titration by 1 mol L⁻¹ HCl. The major HCl-reactive mineralogical components are identified using mass balance calculation of H⁺ consumed by their dissolution together with the amount of major elements released into solution. The speciation of minor and trace elements is investigated by comparing their titrations to those of the major elements. This approach is much simpler than SES because it uses simple non-selective H⁺ at room temperature instead of a complex experimental design of so-called specific reagents. The different mineral components of the solid are no longer operationally defined and the problem of selectivity is irrelevant to the titration approach. The method was applied to several sediment samples from the Scheldt estuary and the particulate phase was further examined by Scanning Electron Microprobe and X-ray Diffraction techniques. The nearly complete consumption of H⁺ in the suspension is balanced by the total dissolution of carbonates and Fe-oxyhydroxides. In contrast to the speciation inferred from the Tessier SES, the acidimetric titration has demonstrated that the carbonate phase does not significantly contain trace metals with the exceptions of 40% of the Mn and 30% of the Co. In contrast, the Fe-oxyhydroxides seem to play a major role and account for 70% of Pb and 20% of Cr, in addition to 60% of P and additional amounts of 20% Co and 40% Mn. 70% of the Cu also occur in the oxyhydroxide phase, more likely coprecipitated with gibbsite. 90% of the Cd and 85% of Zn can be attributed to the Acid Volatile Sulfide (AVS) phase as evidenced from S titration. The acidimetric titration method not only provides information on the speciation of trace metals but also allows the quantification of their reactivity and mobility, if one considers that the titration roughly mimics pH changes that may occur as a result of chemical disequilibrium in the environment. The results demonstrate the potential of the acidimetric titration as an alternative to SES protocols in geochemical and environmental regulation studies. This method is applicable to a wide variety of environmental materials with little or minor adjustments.