Reservoirs of atmospheric chlorine: Prospects for HOCl revisted

We have re-examined the prospects of HOCl as an inert reservoir for atmospheric chlorine in the light of new theoretical calculations and available experimental measurements of its photodissociation cross-sections. The theoretical calculations and most recent laboratory studies imply that the broad maxima 3200 Å observed in two other experimental spectra may not belong to HOCl. On the basis of this implication HOCl could have a long lifetime against photodissociation in the stratosphere, and could, thereby, become a reservoir for atmospheric chlorine comparable to ClONO₂ or even HCl. In this capacity HOCl could reduce the predicted ozone destruction due to any given level of total chlorine burden. We have also examined the difficulties in laboratory measurements of the HOCl absorption spectrum with particular emphasis on identifying the impurities which may be present in the experimental system. It appears that specialized new experiments are needed to clearly establish the nature and strength of HOCl absorption in the neighbourhood of 3200 Å. Some refinements in the theoretical calculations also seem desirable. In view of the difficulties involved in the laboratory determination of HOCl photodissociation cross-sections, it is suggested that a search for possible stratospheric HOCl by atmospheric spectroscopists would be worthwhile.     

On the dissociation of nitrogen by electron impact and by E.U.V. photo-absorption

The dissociation of N₂ by electron impact and by e.u.v. photo-absorption is studied, and it is shown that the forbidden predissociation of the numerous ¹Π_u and ¹Σ_u⁺ valence and Rydberg states of N₂ in the 11–24eV energy range is the dominant mechanism for N atom production. By measuring the absolute emission cross sections for the e.u.v. singlet bands of N₂ and by using the generalized oscillator strength data of Lassettre (1974), it has been possible to construct a detailed model of the total N₂ dissociation cross section which is in good agreement with the measurements of Winters (1966) and Niehaus (1967) and provides some insights into the maximum possible $\text{N(}{}^2\text{D)}$ yield from dissociative excitation. The total cross section for exciting N₂ e.u.v. radiation in the 800Å–1100Å wavelength range has been measured and found to have a value of 3.4 ×10^?17 cm² at 100 eV under optically thin conditions. Although this result implies that large fluxes of e.u.v. photons should be excited in auroral substorms and in the airglow, they are not observed, and we show that this development is a consequence of radiation entrapment and predissociation. The total cross section for dissociating N₂ by electron impact is given for optically thin and thick media. And some questions concerning the energy budget of a magnetospheric storm which are raised by these results, are discussed.     

The spectral reflectivity of select areas on Europa

The July 12, 1973, occultation of Europa by Io was observed in 30 wavelength channels in the spectral region λλ3200-11, 000 Å with the 200-inch Hale telescope and a multichannel spectrometer. The data are presented in absolute units above the Earth's atmosphere. The data are analyzed to obtain the spectral reflectivity of seven localized areas on the disk of Europa centered on 324°W longitude. The equatorial material is confirmed to be darker than the eastward-skewed bright north polar cap and a hint is evident that the darker material as well may be somewhat redder than the cap material.     

The atmosphere of Io from Pioneer 10 radio occultation measurements

The occultation of the Pioneer 10 spacecraft by Io (JI) provided an opportunity to obtain two S-band radio occultation measurements of its atmosphere. The dayside entry measurements revealed an ionosphere having a peak density of about 6 × 10⁴ elcm^?3 at an altitude of about 100 km. The topside scale height indicates a plasma temperature of about 406 K if it is composed of Na⁺ and 495 K if N₂⁺ is principal ion. A thinner and less dense ionosphere was observed on the exit (night side), having a peak density of 9 × 10³ elcm^?3 at an altitude of 50 km. The topside plasma temperature is 160 K for N₂^? and 131 K for Na⁺. If the ionosphere is produced by photoionization in a manner analogous to the ionospheres of the terrestrial planets, the density of neutral particles at the surface of Io is less than 10¹¹?10¹² cm³, corresponding to a surface pressure of less than 10^?8 to 10^?9 bars. Two measurements of its radius were also obtained yielding a value of 1830 km for the entry and 192 km for the exit. The discrepancy between these values may indicate an ephemeris uncertainty of about 45 km. The two measurements yield an average radius of 1875 km, which is not in agreement with the results of the Beta Scorpii stellar occultation.     

Geopotential harmonics of order 15 and odd degree from analysis of resonant orbits

We have analysed the variations of inclination in 13 satellite orbits as they pass slowly, under the action of air drag, through 15th-order resonance with the geopotential, when successive equatorial crossings are 24° apart and the ground track repeats after 15 rev. The size and form of the change in inclination are determined mainly by the values of the geopotential harmonics of 15th order and odd degree, $\text{C}\text{?}{}_{\mathrm{l,15}}$ and $\text{S}\text{?}{}_{\mathrm{l,15}}$ (with l = 15, 17, 19, …) in the usual notation. Our analysis gives values of these coefficients up to l = 33 as follows:

     

187.

Phytofulgurites: A new type of geological formations     

A. Yu. Lysyuk  G. A. Yurgenson  N. P. Yushkin 《Doklady Earth Sciences》2006,411(2):1431-1434

     

188.

Particulate material composition in the Lena River-Laptev Sea system: Scales of heterogeneities     

O. V. Dudarev  I. P. Semiletov  A. N. Charkin 《Doklady Earth Sciences》2006,411(2):1445-1451

     

189.

Geological structure and indicators of hydrothermal ore-bearing activity at the junction of the southern rift segment and the Doldrums Transform Fracture Zone, Central Atlantic     

S. G. Skolotnev  A. A. Peive  V. Yu. Lavrushin  T. A. Demidova  S. S. Abramov  A. E. Eskin  D. I. Krinov  V. V. Petrova  N. V. Razdolina  N. N. Turko  N. V. Tsukanov  N. L. Chaplygina  E. V. Sharkov 《Doklady Earth Sciences》2006,407(2):361-365

     

190.

Up-temperature flow of surface-derived fluids in the mid-crust: the role of pre-orogenic burial of hydrated fault rocks   总被引：1，自引：0，他引：1  

C. CLARK  M.  HAND  K.  FAURE  A. SCHMIDT MUMM 《Journal of Metamorphic Geology》2006,24(5):367-387

The Walter‐Outalpa shear zone in the southern Curnamona Province of NE South Australia is an example of a shear zone that has undergone intensely focused fluid flow and alteration at mid‐crustal depths. Results from this study have demonstrated that the intense deformation and ductile shear zone reactivation, at amphibolite facies conditions of 534 ± 20 °C and 500 ± 82 MPa, that overprint the Proterozoic Willyama Supergroup occurred during the Delamerian Orogeny (c. 500 Ma) (EPMA monazite ages of 501 ± 16 and 491 ± 19 Ma). This is in contrast to the general belief that the majority of basement deformation and alteration in the southern Curnamona Province occurred during the waning stages of the Olarian Orogeny (c. 1610–1580 Ma). These shear zones contain hydrous mineral assemblages that cut wall rocks that have experienced amphibolite facies metamorphism during the Olarian Orogeny. The shear zone rock volumes have much lower δ¹⁸O values (as low as 1‰) than their unsheared counterparts (7–9‰), and calculated fluid δ¹⁸O values (5–8‰) consistent with a surface‐derived fluid source. Hydrous minerals show a decrease in δD_(H2O) from ?14 to ?22‰, for minerals outside the shear zones, to ?28 to ?40‰, for minerals within the shear zones consistent with a contribution from a meteoric source. It is unclear how near‐surface fluids initially under hydrostatic pressure penetrate into the middle crust where fluid pressures approach lithostatic, and where fluid flow is expected to be dominantly upward because of pressure gradients. We propose a mechanism whereby faulting during basin formation associated with the Adelaidean Rift Complex (c. 700 Ma) created broad hydrous zones containing mineral assemblages in equilibrium with surface waters. These panels of fault rock were subsequently buried to depths where the onset of metamorphism begins to dehydrate the fault rock volumes evolving a low δ¹⁸O fluid that is channelled through shear zones related to Delamerian Orogenic activity.     

[首页] « 上一页 [14] [15] [16] [17] [18] 19 [20] [21] [22] [23] [24] 下一页 » 末  页»

l	109C?l,15	109S?l,15
15	?23.5 ± 0.8	?7.7 ± 0.8
17	6.3 ± 1.5	5.6 ± 1.5
19	?25.1 ± 2.5	?7.3 ± 2.3
21	27.8 ± 3.6	?0.7 ± 3.4
23	17.1 ± 4.1	13.9 ± 4.8
25	?1.1 ± 3.0	8.5 ± 4.2
27	10.0 ± 3.3	6.7 ± 2.7
29	?9.4 ± 3.5	0.1 ± 4.7
31	10.1 ± 5.4	3.8 ± 5.6
33	1.1 ± 5.7	3.1 ± 5.8

Up-temperature flow of surface-derived fluids in the mid-crust: the role of pre-orogenic burial of hydrated fault rocks

The Walter‐Outalpa shear zone in the southern Curnamona Province of NE South Australia is an example of a shear zone that has undergone intensely focused fluid flow and alteration at mid‐crustal depths. Results from this study have demonstrated that the intense deformation and ductile shear zone reactivation, at amphibolite facies conditions of 534 ± 20 °C and 500 ± 82 MPa, that overprint the Proterozoic Willyama Supergroup occurred during the Delamerian Orogeny (c. 500 Ma) (EPMA monazite ages of 501 ± 16 and 491 ± 19 Ma). This is in contrast to the general belief that the majority of basement deformation and alteration in the southern Curnamona Province occurred during the waning stages of the Olarian Orogeny (c. 1610–1580 Ma). These shear zones contain hydrous mineral assemblages that cut wall rocks that have experienced amphibolite facies metamorphism during the Olarian Orogeny. The shear zone rock volumes have much lower δ¹⁸O values (as low as 1‰) than their unsheared counterparts (7–9‰), and calculated fluid δ¹⁸O values (5–8‰) consistent with a surface‐derived fluid source. Hydrous minerals show a decrease in δD_(H2O) from ?14 to ?22‰, for minerals outside the shear zones, to ?28 to ?40‰, for minerals within the shear zones consistent with a contribution from a meteoric source. It is unclear how near‐surface fluids initially under hydrostatic pressure penetrate into the middle crust where fluid pressures approach lithostatic, and where fluid flow is expected to be dominantly upward because of pressure gradients. We propose a mechanism whereby faulting during basin formation associated with the Adelaidean Rift Complex (c. 700 Ma) created broad hydrous zones containing mineral assemblages in equilibrium with surface waters. These panels of fault rock were subsequently buried to depths where the onset of metamorphism begins to dehydrate the fault rock volumes evolving a low δ¹⁸O fluid that is channelled through shear zones related to Delamerian Orogenic activity.