Intrusive Stratification of the Gulf-Stream Frontal Zone According to the Results of Investigations Performed during Cruise 43 of the R/V Akademik Vernadskii

We analyze the data of investigation of the intrusive structure of the Gulf-Stream frontal zone obtained in making frequent drift sections with the help of an MGI-8102 probing complex, study the regularities of variation of temperature, salinity, and density along separate intrusions, and present a series of results connected with the specific features of initiation and development of intrusions and the types of exchange processes determining their transformations. It is shown that the T-diagrams of all intrusions are well separated into segments with different slopes. Moreover, by comparing the slopes and locations of these segments with each other and with the T-diagrams of the Gulf Stream and slope waters, we can fairly reliably attribute the corresponding segments of intrusions to one of the following four types: initial dynamic folds of the frontal zone, layers of domestic water separating the intrusive segments of foreign water from each other, intrusive segments characterized by the penetration of ambient water, and segments not intrusive initially but getting the required slope as a result of interaction with upper and lower intrusive segments. For segments of the last two types, it is possible to specify the predominant type of exchange.     

An alternative approach to the structural motion analysis of wedge-beam offshore structures supporting a load

For convenience of dynamic analysis, some offshore structures such as fixed-type platforms are often modeled as the wedge beams supporting tip lumped masses. It is well-known that, due to the effect of the surrounding water, the natural frequencies of a beam in air (or dry beam) are different from those of the same beam immersed in water (or wet beam). However, if the natural frequencies and the associated mode shapes of a dry beam are calculated by taking account of the “added mass” for the immersed beam, then the last natural frequencies and mode shapes will be equal to the corresponding ones of the wet beam. Based on the last concept, the closed form solutions for natural frequencies and the associated mode shapes of the dry beam were determined first, then the partial differential equation of motion for the wet beam was transformed into a matrix equation by using the expansion theorem and the foregoing closed form solutions of free vibration responses for the dry beam. Solving the last matrix equation will give the required natural frequencies and the associated mode shapes of the wet beam. The formulation of this paper is available for the fully or partially immersed double tapered beams with either circular, square or rectangular cross-sections. The taper ratio for width and that for depth may be equal or unequal. The numerical results of this paper were compared with the existing results or the finite-element-method results and good agreement was achieved.     

Statistical Modeling of Monthly Anomalies of Atmospheric Precipitations for the Region of the Ukraine and Black Sea

The data array accumulated for the period 1946–1995 is used to select the most significant predictor of monthly anomalies of precipitation in the region of the Ukraine and Black Sea, namely, a large-scale circulation in a sector covering the North Atlantic and Europe. Three large-scale predictors (geopotential at a level of 500GPa, sea-level pressure, and the difference between the geopotentials at levels of 500 and 1000GPa) give almost identical results: their correlation with anomalies of precipitation is equal to 0.7–0.8 in winter and 0.4–0.5 in summer. The predominant mechanism of the influence of circulation on precipitations at low frequencies is the response of the trajectories of European cyclones to changes in the upper-tropospheric jet currents in the Atlantic-European sector described as the superposition of the North-Atlantic oscillation and the Eurasian mode. The decomposition of the fields of precipitations and circulation in the eigenmodes of the canonical correlation analysis opens a possibility of direct computation of the monthly average fields of precipitations for the entire territory of the Ukraine and Black Sea region according to the large-scale geopotential fields.     

Release into the environment of metals by two vascular salt marsh plants

Metals in contaminated salt marshes are mainly locked in the anaerobic layer of sediments, where they are tightly bound as sulfides and organic complexes. Vascular plants survive in saturated soils in part by pumping O2 into their root zones, changing their microenvironment to an oxic one. This, along with chelating exudates, mobilizes metals, allowing uptake by the roots. We compared the common reed Phragmites australis and cordgrass Spartina alterniflora in lab and field studies for ways in which they handle trace metals. Both plants store most of their metal burden in their roots, but some is transported to aboveground tissues. Spartina leaves contain approximately 2-3 x more Cr, Pb, and Hg than Phragmites leaves, but equivalent Cu and Zn. Furthermore, Spartina leaves have salt glands, so leaf excretion of all metals is twice that of Phragmites. In-depth studies with Hg indicate that Hg excretion correlates with Na release but not with transpiration, which is 2.2 x higher in Phragmites; and that more Hg accumulates in early-appearing leaves than in upper (i.e. later) leaves in both species. Spartina thus makes more metals available to salt marsh ecosystems than Phragmites by direct excretion and via dead leaves which will enter the food web as detritus.     

The expression of CYP1A,vitellogenin and zona radiata proteins in Atlantic salmon (Salmo salar) after oral dosing with two commercial PBDE flame retardant mixtures: absence of short-term responses

The short-term effects of the commercial PBDE flame retardant mixtures Penta-BDE and cta-BDE on the expression of cytochrome P450 1A (CYP1A), vitellogenin (Vtg) and zona radiata proteins (Zrp) were investigated in juvenile salmon (Salmo salar). For this purpose, groups of fish were dosed twice (oral intake at days I and 4) with 10 and 50 mg/kg body weight of both commercial mixtures. The fishes were sacrificed at day 7 (n = 5 for each group) and 14 (n = 6 for each group), and blood, liver, fillet, and brain were collected. Blanks and positive controls were also part of the experiment. The expressions of Vtg, Zrp, and CYPIA were measured with several techniques (EROD, ELISA, Western, Northern and Slot Blot). The values in the groups of fish treated with Penta-BDE or Octa-BDE did not significantly differ from the reference group for any of the parameters tested. In contrast, the positive control groups treated with estradiol-17beta for Vtg and Zrp expression, and beta-naphthoflavone for CYP1A expression did show a significant response, indicating the potential sensitivity of the fishes for the parameters measured. Since the results of the chemical analyses showed concentrations of a number of PBDE congeners in liver, fillet, and brain that were about three orders of magnitude above those of fish from the North Sea, it is concluded that the short-term toxicity of both commercial PBDE mixtures for these endpoints was low.     

Evaluation of toxicity in tributaries of the Mersey estuary using the isopod Asellus aquaticus (L.)

Increasing numbers of industrial, agricultural and natural chemicals are present in sewage effluent and are known to elicit toxic effects in laboratory exposures, but little is known of their combined sub-lethal effect in the field. In this study, a combination of esterase activity and ventilation rate assays was performed to determine the neurological and physiological function of the freshwater crustacean Asellus aquaticus (L.) at sites above and below a sewage treatment works (STW). Cholinesterase and carboxylesterase activities were significantly inhibited (n=8, P<0.05) and ventilation rates increased (n=8, P=0.0001) in A. aquaticus at STW sites compared to those from reference sites, indicating a decrease in neurological and physiological function. The ecological relevance of these findings for the population dynamics of the organisms in the field is discussed.     

Burial and scour around short cylinder under progressive shoaling waves

The results of a laboratory experimental program aimed at better understanding the scour around and burial of heavy cylindrical objects under oscillating flow on a sandy bed are described. This study was motivated by its application to the dynamics of isolated cobbles/mines on a sandy floor under nonlinear progressive waves, such as that occur in shallow coastal waters beyond the wave-breaking region. In the experiments, nonlinear progressive waves were generated in a long wave tank of rectangular cross-section with a bottom slope. Model mines (short cylinders) were placed on the sandy bottom and the temporal evolution of the bed profile and the velocity field in the near field of the object were observed. Experiments were conducted at relatively high Reynolds numbers for a range of flow conditions, which can be characterized by the Keulegan–Carpenter number and Shields parameter. Depending on the values of these parameters, four different scour regimes around the cylinder including periodical burial of cylinder under migrating sand ripples were observed; they were classified as: (i) no scour/burial, (ii) initial scour, (iii) expanded scour, and (iv) periodic burial cases. A scour regime diagram was developed and the demarcation criteria between different regimes were deduced. Semi-empirical formulae that permit estimation of the scour depth with time, the equilibrium maximum scour depth and length, and conditions necessary for the burial of the cylinder as a function of main external parameters are also proposed.     

Spatial and seasonal variations in depth profile of trace metals in saltmarsh sediments from Sapelo Island, Georgia, USA

This study was undertaken to elucidate the impact of early diagenetic processes on the accumulation of trace metals in Sapelo Island saltmarsh sediments as a function of time, space and sediment properties. Samples were collected from three sites in summer (May 1997) and winter (January 1998) along a transect from an unvegetated Creek Bank through a vegetated Tidal Levee to the vegetated midmarsh with evident lateral heterogeneity caused by hydrologic regime, macrophytes and microbial and macrofaunal activities. A suite of trace metals (As, Ba, Cr, Co, Cu, Cd, Mo, Ni, Pb, Th, Ti, U, V, Zn and Zr) was analyzed to obtain their depth-distribution at the three sites. Spatially marked differences were observed, that were primarily related to hydraulic flushing of trace metals away from the sites in high-energy regimes, rapid downward mixing and reworking of sediment via bioturbation, and below-ground degradation and production of Spartina biomass. Although sulfate reduction and the formation of acid volatile sulfide and pyrite were dominant processes throughout the marsh, the trace metal scavenging role of sulfides was not apparent. However, possible sulfurization of organic matter, leading to enhanced trapping of trace metals with organic carbon, may have played an important role in sequestration of trace metals.No similarity was observed visually between the depth trends of trace metals and sediment properties (grain size, iron-oxyhydroxide content, acid volatile sulfides and pyrite content) that are known to play a major role in trace metal partitioning. Only organic carbon content closely followed the trace metal profiles at all the three sites. Minor variation in depth-integrated sediment trace metal content was observed seasonally at each of the three sites. Furthermore, the depth trend of profiles of individual trace metals also did not vary significantly over the seasons either.