低硼氢氧化镁的制备及热分解动力学参数

本文以水合氯化镁、工业氨水为原料制备出了低硼含量的纯度 >99%的氢氧化镁和氧化镁。利用差热 -热重 (DTA- TG)、X-射线衍射 (XRD)、透射电子显微镜 (TEM)等手段 ,对氢氧化镁的热稳定性、相结构、表观状态以及脱水动力学参数进行了分析。结果为 :氢氧化镁以束状纤维和片状粉末共存 ,在 6 2 3K基本完成脱水反应生成氧化镁 ,其脱水反应的表观活化能 E为135 .4 k J· mol-1,指前因子 A为 5 .15× 10 10 ,反应级数 n为 1.10     

Numerical study of the influence of Kuroshio Current on the thermocline in the sea area around Taiwan Island

1 INTsoDUcrIONTemperature is one of the most impoFtant essential factors of ocean, and its verticalstructure, especially the phenomenon ofthermocline, is concerned by military and manufacturepractices at all times. There are two classes of research methods for thermocIine, statisticmethod and numerical method. In recent years, more attention has been paid to the latterwhich becomes the primary development direction. Since Munk et al (1948) pot forward1-D model of thermocline at steady sta…     

Design of Mooring System for Oil Storage Vessels

The floating oil storage system has been proposed as a new facility for Strategic Petroleum Reserve (SPR) in China. Mooring is one of the key technologies to ensure the safety, reliability, and performance of the oil storage system. This paper describes the concept, analysis, design and reliability of the mooring system. For mooring system design of these oil vessels, analysis is essential of the behavior of the vessel in connection with mooring facilities of nonlinear resilience. A nonlinear mathematical model for analyzing a moored vessel is established and solved. Some results of numerical simulations are presented. Assessment of the safety regarding the mooring system in terms of failure probability is carried out. Another simulation model for calculating the failure probability of the mooring system is proposed. The design parameters that have an influence on the characteristics of the failure probability have been identified. The simulation results show that the mooring system has an annual reliab     

Water mass formation variability in the intermediate layer of the east sea

Long-term variability in the intermediate layer of the eastern Japan Basin has been investigated to understand the variability of water mass formation in the East Sea. The simultaneous decrease of temperature at shallower depths and oxygen increasing at deeper depths in the intermediate layer took place in the late 1960’s and the mid-1980’s. Records of winter sea surface temperatures and air temperatures showed that there were cold winters that persisted for several years during those periods. Therefore, it was assumed that a large amount of newly-formed water was supplied to the intermediate layer during those cold winters. Close analysis suggests that the formation of the Upper Portion of Proper Water occurred in the late 1960’s and the Central Water in the mid-1980’s.     

The Structure of A Turbulent Jet in A Crossflow-Effect of Jet-Crossflow Velocity

A comprehensive numerical study on the three-dimensional structure of a turbulent jet in crossflow is performed. The jet-to-crossflow velocity ratio (R) varies in the range of 2 - 16; both vertical jets and inclined jets without excess streamwise momentum are considered. The numerical results of the Standard two-equation k-ε model show that the turbulent structure can be broadly categorised according to the jet-to-crossflow velocity ratio. For strong to moderate jet discharges, i.e. R> 4, the jet is characterized by a longitudinal transition through a bent-over phase during which the jet becomes almost parallel with the main freestream, to a sectional vortex-pair flow with double concentration maxima; the computed flow details and scalar mixing characteristics can be described by self-similar relations beyond a dimensionless distance of around 20-60. The similarity coefficients are only weakly dependent on R. The cross-section scalar field is kidney-shaped and bifurcated, vvith distinct double concentr     

Estimation of Water Particle Velocities by Empirical Transfer Function

-In previous and this studies it appears that the linear and nonlinear wave theory can notaccurately and easily predict the water particle velocities.Therefore,different from the theoretical consider-ations,in this study we have attempted to determine the transfer function empirically.Laboratory experi-ments were performed under various wave conditions.The empirical formulas of the transfer function ofthe wave height,angular frequency and water particle velocity were obtained on the basis of these test databy dimensional analysis and regression analysis.In intermediate and deep water depth conditions,thetransfer function was only a function of a nondimensional parameter which is composed of the angular fre-quency,the depth of the velocity gauge under the still water level,water depth and the acceleration of grav-ity.Finally,the empirical formulas were compared with experimental data and observational data formpresent and Cavaleri's(1978)studies.The empirical formulas were found to be in sufficient correl     

Effect of the Twin Jetties as A Regulating Structure at the Tao-er Estuary

The phase one project of the twin jetties at the Tao-er Estuary yields no effect on the flow, and there is a large area of deposition. A numerical model is employed to simulate the flow field, and the scouring and silting in the channel be-tween the two jetties are analyzed. The results show that the effective tidal flux between the two jetties is reduced due to the notch located at the heel of the east jetty, and the effect of contraction-flush is not obvious. As for the regulation of this kind of estuary under the tide action, the capability of tidal flux should be fully used.     

江西省永平铜矿西部排土场极限堆载高度确定

国内外对排土场极限堆载高度的理论计算缺乏研究,目前尚无成熟的统一理论计算方法。文章结合永平铜矿西部排土场的工程实例,在进行边坡工程地质条件勘察与排土场岩土物理力学性质试验研究的基础上,采用数值计算方法对排土场进行了分层堆载数值模拟计算。通过对计算结果的分析,得到位移、塑性区与安全系数随堆载高度的变化规律,并确定了该排土场的极限堆载高度。