Palaeomagnetic investigation of Cenozoic volcanic rocks bordering the North Anatolian Fault Zone,Reşadiye and Koyulhisar Districts,central-east Anatolia,Turkey

A palaeomagnetic study is reported from the lavas of Eocene, Miocene and Pliocene age cropping out immediately to the north of the North Anatolian Fault Zone (NAFZ) in the Re?adiye–Mesudiye region of central-eastern Anatolia. Rock magnetic investigations identify a high percentage of multi-domained magnetite as the dominant ferromagnet in these rocks and this probably accounts for a relatively poor response to alternating field and thermal demagnetisation. Thirty of 37 units yielded acceptable groupings of characteristic magnetisation directions. An earlier study indicated small anticlockwise crustal block rotation in this region since Upper Cretaceous times (D/I?=?347/50°), and our study indicates that this was overtaken by clockwise rotation in Eocene times (D/I?=?40/47°), although sample size control from the Palaeogene is poor. Results from later Miocene (D/I?=?2/62°) and Pliocene (D/I?=?0/53°) volcanic rocks indicate that no significant tectonic rotation has occurred in the north of the NAFZ in Neogene times. This contrasts with rotations in the weaker crust comprising the Anatolian collage south of the NAFZ, where differential and sometimes large anticlockwise rotations occurred during the latter part of the Neogene.     

Interpreting a Pumping Test Influenced by Another Well in an Anisotropic Aquifer

In confined aquifers the influence of neighboring active wells is often neglected when interpreting a pumping test. This can, however, lead to an erroneous interpretation of the pumping test data. This article presents simple methods to evaluate the transmissivity tensor and storativity of an anisotropic confined aquifer when there is an interfering well in the neighborhood of the tested well. Two methods have been developed depending on whether the tested well or the interfering well is the first in operation. These new methods yield better estimates of the hydraulic parameters than when the influence of the interfering well is neglected. These methods have then been used on data obtained from numerical models with an interfering well and the results have been compared to an analytical method that neglects the influence of the interfering well. The methods require knowledge of the pumping rate of the interfering well and the time elapsed since the pumping started in each well. If the interfering well started pumping before the tested well, the method does not require knowledge of the aquifer piezometric level at the beginning of the test, which is often unknown in this case. As for the method without interference, at least three monitoring wells (MWs) are needed, the position of which influences the accuracy of the estimated parameters. Some recommendations concerning MWs position have been given to get more accurate results according to the sought parameter.     

Magnetostratigraphic correlation of the Oxfordian–Kimmeridgian boundary

A magnetic polarity pattern for Boreal and Sub-Boreal ammonite zones of the Upper Oxfordian to Lower Kimmeridgian was established and confirmed in four British sections, including the proposed Global Boundary Stratotype Section and Point (GSSP) on the Isle of Skye (Scotland) to define the base of the international Kimmeridgian Stage. A coeval pattern for Sub-Mediterranean ammonite zones was compiled from seven sections in Poland, one German section and multi-section composites from France and Spain. The mean paleopole for the European Craton (excluding Spain) at the Oxfordian–Kimmeridgian boundary is 74.2°N, 181.3°E (Α₉₅ = 3.8°). The common magnetic polarity scale enables inter-correlation of ammonite subzones among these three faunal provinces and to the marine magnetic-anomaly M-Sequence. The proposed GSSP at the base of the Pictonia baylei Zone is near the base of an extended interval dominated by reversed polarity, which is interpreted to be Chron M26r. This GSSP level projects to the lower to middle part of the Epipeltoceras bimammatum Subzone, which is the middle subzone of this E. bimammatum Zone in the Sub-Mediterranean standard zonation. In contrast, the traditional placement of the Oxfordian–Kimmeridgian boundary in that Sub-Mediterranean standard zonation (base of Sutneria platynota Zone) is at the base of Chron M25r, or nearly 1 million years younger.     

Selective Solid Phase Extraction for Separation and Preconcentration of Palladium from Gold Ore and Anode Slime after Complexation with a N4O2 Mixed Donor Ligand Derivative

A selective and sensitive method for the preconcentration, separation, and determination of palladium with flame atomic absorption spectrometry using 4,15‐bis[(4‐methylphenyl)sulfonyl]‐20,21‐dinitro‐2,3,4,5,6,7,9,10,12,13,14,15,16,17‐tetradecahydro‐8,11‐ethano‐1,18,4,8,11,15‐benzodioxa tetraaza cycloicosine (TNACIN) on XAD‐2010 was developed. TNACIN–Pd(II) complex formed acidic aqueous solution (0.075–0.100 M HNO₃) was accumulated on XAD‐2010 and then eluted with 1 M HCl in acetone. The effects of some analytical parameters including pH, TNACIN amount, sample volume, eluent type, and concentration, sample flow rate and matrix ions were studied for optimization of the method. Detection limit and precision were calculated for Pd(II). This method was also verified with CRM and internal standard, and satisfactory results were obtained.     

The significance of transparent exopolymeric particles in the vertical distribution of bacteria and heterotrophic nanoflagellates in Lake Pavin

The abundance, size distribution, and bacterial colonization of Transparent Exopolymeric Particles (TEP) were examined in two consecutive years during the spring diatom development throughout the water column of the deep meromictic Lake Pavin, France. TEP concentrations ranged from 1.9 to 13.4 × 10⁵ particles l⁻¹ and their distribution and size spectra indicated that these particles are the main factor in governing the transport of diatoms to the deep hypolimnion of the lake. The majority of TEP was colonized by bacteria that constituted 0.4–8.9% of total DAPI-stained bacteria. The intensity of bacterial colonization was strongly related to temperature and decreased with particle size. A more important colonization of small particles in the hypolimnion during thermal stratification suggested that bacterial colonisation also increased with the age of the particle. The abundance of heterotrophic nanoflagellates (HNF) was more significantly related to the density of particles than to the density of total bacteria and the intensity of bacterial colonization of TEP. Our results therefore suggest that TEP are a more important factor for HNF development than attached and free bacteria. We conclude that TEP are involved not only in sedimentation processes but also in the dynamics of bacteria and protozoa in freshwater pelagic environments.     

A discontinuous finite element baroclinic marine model on unstructured prismatic meshes

We describe the time discretization of a three-dimensional baroclinic finite element model for the hydrostatic Boussinesq equations based upon a discontinuous Galerkin finite element method. On one hand, the time marching algorithm is based on an efficient mode splitting. To ensure compatibility between the barotropic and baroclinic modes in the splitting algorithm, we introduce Lagrange multipliers in the discrete formulation. On the other hand, the use of implicit–explicit Runge–Kutta methods enables us to treat stiff linear operators implicitly, while the rest of the nonlinear dynamics is treated explicitly. By way of illustration, the time evolution of the flow over a tall isolated seamount on the sphere is simulated. The seamount height is 90% of the mean sea depth. Vortex shedding and Taylor caps are observed. The simulation compares well with results published by other authors.     

Site classification of Turkish national strong-motion stations

Since 1973, the General Directorate of Disaster Affairs of Turkey has deployed several strong-motion accelerographs at selected sites. Within the framework of the project entitled Compilation of National Strong Ground Motion Database in Accordance with International Standards, site conditions were investigated within the upper 30-m depth by surface seismic and standard penetration tests. Preliminary characterization of the sites is made by making use of both geophysical and geotechnical criteria of NEHRP Provisions and Eurocode-8 site classification systems. The liquefaction susceptibility of those sites which comprise saturated cohesionless deposits is also determined. Mean shear-wave velocity, mean penetration resistance, site class, and liquefaction susceptibility of each site are tabulated. The Turkish strong-motion database supplemented by detailed information on site conditions is a valuable source of information particularly for those studies that put emphasis on the relationship between site conditions and strong-motion parameters.     

Hydrochemical behaviour of dissolved nitrogen and carbon in a headwater stream of the Canadian Shield: relevance of antecedent soil moisture conditions

This paper examines the impact of contrasting antecedent soil moisture conditions on the hydrochemical response, here the changes in dissolved nitrogen (NO₃^?, NH₄⁺ and dissolved organic nitrogen (DON)) and dissolved organic carbon (DOC) concentrations, of a first‐order stream during hydrological events. The study was performed in the Hermine, a 5 ha forested watershed of the Canadian Shield. It focused on a series of eight precipitation events (spring, summer and fall) sampled every 2 or 3 h and showing contrasted antecedent moisture conditions. The partition of the eight events between two groups (dry or wet) of antecedent moisture conditions was conducted using a principal component analysis (PCA). The partition was controlled (first axis explained 86% of the variability) by the antecedent streamflow, the streamflow to precipitation ratio Q/P and by the antecedent groundwater depth. The mean H⁺, NO₃^?, NH₄⁺, total dissolved nitrogen and DOC concentrations and electrical conductivity values in the stream were significantly higher following dry antecedent conditions than after wetter conditions had prevailed in the Hermine, although the temporal variability was high (17 to 138%). At the event scale, a significantly higher proportion of the changes in DON, NO₃^?, and DOC concentrations in the stream was explained by temporal variations in discharge compared with the seasonal and annual scales. Two of the key hydrochemical features of the dry events were the synchronous changes in DOC and flow and the frequent negative relationships between discharge and NO₃^?. The DON concentrations were much less responsive than DOC to changes in discharge, whereas NH was not in phase with streamflow. During wet events, the synchronicity between streamflow and DON or NO₃^? was higher than during dry events and discharge and NO₃^? were generally positively linked. Based on these observations, the hydrological behaviour of the Hermine is conceptually compatible with a two‐component model of shallow (DON and DOC rich; variable NO₃^?) and deep (DON and DOC poor; variable NO₃^?) subsurface flow. The high NO₃^? and DOC levels measured at the early stages of dry events reflected the contribution from NO₃^?‐rich groundwaters. The contribution of rapid surface flow on water‐repellent soil materials located close to the stream channel is hypothesized to explain the DOC levels. An understanding of the complex interactions between antecedent soil moisture conditions, the presence of soil nutrients available for leaching and the dynamics of soil water flow paths during storms is essential to explain the fluxes of dissolved nitrogen and carbon in streams of forested watersheds. Copyright © 2007 John Wiley & Sons, Ltd.