Siderophile element constraints on the formation of metal in the metal-rich chondrites Bencubbin, Weatherford, and Gujba

Laser ablation inductively coupled plasma mass spectrometry was used to measure abundances of P, Cr, Fe, Co, Ni, Cu, Ga, Ge, As, Mo, Ru, Rh, Pd, Sn, Sb, W, Re, Os, Ir, Pt, and Au in metal grains in the Bencubbin-like chondrites Bencubbin, Weatherford, and Gujba to determine the origin of large metal aggregates in bencubbinites. A strong volatility-controlled signature is observed among the metal grains. The refractory siderophiles Ru, Rh, Re, Os, Ir, and Pt are unfractionated from one another, and are present in approximately chondritic relative abundances. The less refractory elements Fe, Co, Ni, Pd, and Au are fractionated from the refractory siderophiles, with a chondritic Ni/Co ratio and a higher than chondritic Pd/Fe ratio. The moderately volatile siderophile elements Ga, Ge, As, Sn, and Sb are depleted in the metal, relative to chondritic abundances, by up to 3 orders of magnitude. The trace siderophile element data are inconsistent with the following proposed origins of Bencubbin-Weatherford-Gujba metal: (1) condensation from the canonical solar nebula, (2) oxidation of an initially chondritic metal composition, and (3) equilibration with a S-rich partial melt. A condensation model for metal-enriched (×10⁷ CI) gas is developed. Formation by condensation or evaporation in such a high-density, metal-enriched gas is consistent with the trace element measurements. The proposed model for generating such a gas is protoplanetary impact involving a metal-rich body.     

Lithologic mapping of a forested montane terrain from Landsat 5 TM image

Thick forest cover and poor infrastructures are the major hindrances for detailed lithologic mapping in an inaccessible montane landscape. To overcome these limitations, we utilize a Landsat 5 TM image to map lithology using vegetation and drainage pattern as an indicator of underlying rock types in a heavily forested region of the Chittagong Hill Tracts area located in southeastern Bangladesh. We use supervised and unsupervised classifiers for a vegetation-based approach while on-screen digitization is used for drainage patterns-based mapping. Field observations were used for mapping lithology and evaluating accuracy. Overall, our results agree well with the current geologic map and improve it by providing a more spatially detailed distribution of the sandstone and shale. The performances of all approaches are good at the inner and outer flanks of anticlines located in the study area while the drainage pattern mapping performs best at the mid-flank area.     

Automatic filtering and 2D modeling of airborne laser scanning building point cloud

This article suggests a new approach to automatic building footprint modeling using exclusively airborne LiDAR data. The first part of the suggested approach is the filtering of the building point cloud using the bias of the Z‐coordinate histogram. This operation aims to detect the points of roof class from the building point cloud. Hence, eight rules for histogram interpretation are suggested. The second part of the suggested approach is the roof modeling algorithm. It starts by detecting the roof planes and calculating their adjacency matrix. Hence, the roof plane boundaries are classified into four categories: (1) outer boundary; (2) inner plane boundaries; (3) roof detail boundaries; and (4) boundaries related to the missing planes. Finally, the junction relationships of roof plane boundaries are analyzed for detecting the roof vertices. With regard to the resulting accuracy quantification, the average values of the correctness and the completeness indices are employed in both approaches. In the filtering algorithm, their values are respectively equal to 97.5 and 98.6%, whereas they are equal to 94.0 and 94.0% in the modeling approach. These results reflect the high efficacy of the suggested approach.     

An experimental test of Henry's Law in solid metal‐liquid metal systems with implications for iron meteorites

Abstract— Experimental solid metal‐liquid metal partition coefficients have been used to model the crystallization of magmatic iron meteorites and understand the evolution of asteroid cores. However, the majority of the partitioning experiments have been conducted with trace elements doped at levels that are orders of magnitude higher than measured in iron meteorites. Concern about Henry's Law and the unnatural doping levels have been cited as one reason that two recent iron meteorite studies have dismissed the experimental partition coefficients in their modeling. Using laser ablation ICP‐MS analysis, this study reports experimentally determined solid metal‐liquid metal trace element partition coefficients from runs doped down to the levels occurring in iron meteorites. The analyses for 12 trace elements (As, Co, Cr, Cu, Ga, Ge, Ir, Os, Pd, Pt, Re, and W) show no deviations from Henry's Law, and these results support decades of experimental work in which the partition coefficients were assumed to be independent of trace element concentration. Further, since our experiments are doped with natural levels of trace elements, the partitioning results are directly applicable to iron meteorites and should be used when modeling their crystallization. In contrast, our new Ag data are inconsistent with previous studies, suggesting the high Ag‐content in previous studies may have influenced the measured Ag partitioning behavior.     

Application of electrical resistivity to map the stratigraphy and salinity of fluvio-deltaic aquifers: case studies from Bangladesh that reveal benefits and pitfalls

Fluvio-deltaic aquifers are the primary source of drinking water for the people of Bangladesh. Such aquifers, which comprise the Ganges-Brahmaputra-Meghna Delta, are hydrogeologically heterogeneous. Because of widespread groundwater quality issues in Bangladesh, it is crucial to know the hydrostratigraphic architecture and hydrochemistry, as some aquifer units are contaminated, whereas others are safe. Geophysical methods provide a potentially effective and noninvasive method for extensive characterization of these aquifers. This study applies and investigates the limitations of using electrical resistivity imaging (ERI) for mapping the hydrostratigraphy and salinity of an aquifer-aquitard system adjacent to the Meghna River. Some electrical resistivity (ER) sections showed excellent correlation between resistivity and grain size. These suggest that ERI is a powerful tool for mapping internal aquifer architecture and their boundaries with finer-grained aquitards which clearly appear as low-ER zones. However, in parts of some ER sections, variations in electrical properties were determined by porewater resistivity. In these cases, low ER was indicative of brine and did not indicate the presence of finer-grained materials such as silt or clay. Accordingly, the following hydrostratigraphic zones with different resistivities were detected: (1) aquifers saturated with fresh groundwater, (2) a regional silt/clay aquitard, and (3) a deeper brine-saturated formation. In addition, shallow silt/clay pockets were detected close to the river and below the vadose zone. ERI is thus a promising technique for mapping aquifers versus aquitards; however, the observations are easily confounded by porewater salinity. In such cases, borehole information and groundwater salinity measurements are necessary for ground-truthing.

     

Geo-spatial dynamics of snowcover and hydro-meteorological parameters of Astore basin,UIB, HKH Region,Pakistan

Snowcover dynamics and associated accumulation and depletion of snowcover along with its spatial and temporal scale mainly constitute hydrological phenomena of the given basin and are mostly controlled by the local climate variables. Snow accumulation and melting time and duration determine the cyclic volume of water resources and downstream availability. In this study, snowcover area (SCA) was extracted from remotely sensed Moderate Resolution Imaging Spectroradiometer (MODIS) snow products (MOD10A2) for the period 2000–2016. Data for hydro-meteorological parameters was obtained from relevant departments acquired through their field stations. The analysis of 16-year satellite data shows that there is a slight increase in cryospheric area at high altitude. In Astore basin, the study concluded that 15–20% of the basin area is covered by glacier and snowcover may reach around 90–95% of the basin area due to accumulation of seasonal snow from the westerly wind circulation. Analysis of hydro-meteorological parameters showed significant correlation between temperatures (T_max, T_min) and river runoff while no significant correlation was observed between river runoff and rainfall. Similarly, significant inverse correlation was found between river runoff and Astore mean snowcover. At sub-altitudinal zone level (zones 1, 2, 3), river runoff has significant correlation with snowcover. Analysis of 20-year climate data along with river runoff depicts that river runoff is a general phenomenon of snowmelt when minimum temperature starts to rise above 4 °C during mid of April. The study highlights the importance and interdependence of meteorological parameters and snowcover dynamics in determining the hydrological characteristics of Astore Basin.     

Temporal analysis of air pollution and its relationship with meteorological parameters in Bahrain, 2006–2012

The objective of this paper is to analyze temporal and seasonal trends of air pollution in Bahrain between 2006 and 2012 by utilizing datasets from five air quality monitoring stations. The non-parametric and robust Theil-Sen approach is employed to study quantitatively temporal variations of particulate matter (PM₁₀ and PM_2.5), nitrogen dioxide (NO₂), sulfur dioxide (SO₂), and ozone (O₃). The calculated annual concentrations for PM₁₀ and PM_2.5 in Bahrain were substantially higher than recommended World Health Organization (WHO) guideline standards. Results showed increasing trends for PM₁₀, PM_2.5, and SO₂ whereas O₃ and its precursor NO₂ showed decreasing behavior. The general increase in air pollution trends is in agreement with prediction of air pollution models for Middle East region due to economic growth, industrialization, and urbanization. The significances of long-term trends were examined. Additional to actual (unadjusted) trends, meteorological adjusted (deseasonalized) trends and seasonal trends were quantified. The box-plot analysis visually illustrated monthly variations of key air pollutants. It showed that only PM₁₀ and PM_2.5 exhibited seasonal pattern, and their concentrations increased during summer and decreased during winter. The effects of ambient air temperature, relative humidity, wind speed, and rainfall on particulate matter (PM) concentrations were further investigated. The Spearman correlation coefficient results demonstrated significant negative correlation between relative humidity and PM concentrations (??0.595 for PM₁₀ and ??0.526 for PM_2.5) while significant positive correlation was observed between temperature and PM concentrations (0.420 for PM₁₀ and 0.482 for PM_2.5).     

LA-ICP-MS U-Pb zircon geochronology and Hf isotope,geochemistry and kinetics of the Daxigou anorthosite from Kuruqtagh block,NW China

Kuruqtagh block is the best area for Precambrian geology in Xinjiang Autonomous Region, NW China, since it exposed complete Precambrian lithology units. The study of this ancient base will deepen the understanding of the Precambrian evolution of the Tarim Basin. In this paper, we studied the petrology, geochemistry, zircon LA-ICPMS U-Pb chronology and zircon Hf isotope of Daxigou anorthosite （DA） which is located at the northem margin of Tarim craton and discussed the rock formation, tectonic and geological significance. Zircons from the intrusions display oscillatory zoning and high Th/U ratios （0.39-1.35）, implying their magmatic origin. Zircon LA-ICP-MS U-Pb dating results indicate that they formed during the Paleoproterozoic age with the weighted 2~6pb/238U average age of 1818~9 Ma, which is significantly different from former＇s Neoproterozoic age, and is co- incidentally identical with its associated syenite granite age within the error range. Studies on petrogeochemistry suggest that DA belongs to medium-sodium peraluminous alkaline type, rich in Pb, La, Th and LILE, and poor in HFSE （Gd, Nd, and Ta）. The chondrite-normalized REE pattern is slightly to the right form. The average Y~REE is 317.2~ 10-6; HREE show moderate fractionation [average LREE/HREE is 14.71, average （La/Yb）N is 24.77; average （LaJSm）N is 3.85, and average （Gd/Yb）y is 3.46]; and the 6Eu and 8Ce are not obvious. Their initial Hf isotope ratios and Hf two-stage model ages range from -6.6 to -4.43 and 2.63 to 2.74 Ga, respectively. Taken together, it is sug- gested that Daxigou anorthosite is a typical volcanic anorthosite and its primary magma could be contaminated by the partial melt Neoarchaean crust and mainly formed in the arc environment, which recoded the tectonic-magma activities response of the Tarim refers to the amalgamation of the supercontinent Columbia.     

The cause of unproportionately large higher mode contributions in the inelastic seismic responses of high‐rise core‐wall buildings

In the conventional seismic design of high‐rise reinforced concrete core‐wall buildings, the design demands such as design shear and bending moment in the core wall are typically determined by the response spectrum analysis procedure, and a plastic hinge is allowed to form at the wall base to limit the seismic demands. In this study, it is demonstrated by using a 40‐story core‐wall building that this conventional approach could lead to an unsafe design where the true demands—the maximum inelastic seismic demands induced by the maximum considered earthquake—could be several times greater than the design demands and be unproportionately dominated by higher vibration modes. To identify the cause of this problem, the true demands are decomposed into individual modal contributions by using the uncoupled modal response history analysis procedure. The results show that the true demands contributed by the first mode are reasonably close to the first‐mode design demands, while those contributed by other higher modes are much higher than the corresponding modal design demands. The flexural yielding in the plastic hinge at the wall base can effectively suppress the seismic demands of the first mode. For other higher modes, however, a similar yielding mechanism is either not fully mobilized or not mobilized at all, resulting in unexpectedly large contributions from higher modes. This finding suggests several possible approaches to improve the seismic design and to suppress the seismic demands of high‐rise core‐wall buildings. Copyright © 2012 John Wiley & Sons, Ltd.     

Geomorphology of the Alluvial Sediments and Bedrock in an Intermontane Basin: Application of Variogram Modeling to Electrical Resistivity Soundings

The study describes a methodology used to integrate legacy resistivity data with limited geological data in order to build three-dimensional models of the near subsurface. Variogram analysis and inversion techniques more typically found in the petroleum industry are applied to a set of 1D resistivity data taken from electrical surveys conducted in the 1980s. Through careful integration with limited geological data collected from boreholes and outcrops, the resultant model can be visualized in three dimensions to depict alluvium layers as lithological and structural units within the bedrock. By tuning the variogram parameters to account for directionality, it is possible to visualize the individual lithofacies and geomorphological features in the subsurface. In this study, an electrical resistivity data set collected as part of a groundwater study in an area of the Peshawar basin in Pakistan has been re-examined. Additional lithological logs from boreholes throughout the area have been combined with local outcrop information to calibrate the data. Tectonic activity during the Himalayan orogeny has caused uplift in the area and generated significant faulting in the bedrock resulting in the formation of depressions which are identified by low resistivity values representing clays. Paleo-streams have reworked these clays which have been eroded and replaced by gravel–sand facies along paleo-channels. It is concluded that the sediments have been deposited as prograding fan-shaped bodies and lacustrine deposits with interlayered gravel–sand and clay–silt facies. The Naranji area aquifer system has thus been formed as a result of local tectonic activity with fluvial erosion and deposition and is characterized by coarse sediments with high electrical resistivities.