Geosynthesis of dibenzothiophene and alkyl dibenzothiophenes in crude oils and sediments by carbon catalysis

Sediment extracts and crude oils have been shown to contain methyl substituted biphenyls and dibenzothiophenes, with isomer distributions suggesting a geochemical relationship between the two compound classes. Laboratory simulation experiments have shown that carbon catalyses the reaction between surface adsorbed sulfur and biphenyl to form dibenzothiophene. Similarly, the methyl substituted biphenyls reacted to yield corresponding methyl dibenzothiophenes. We suggest that the widespread distribution of dibenzothiophene and alkylated dibenzothiophenes in sediments and crude oils is the result of a catalytic reaction of biphenyl ring systems and surface-adsorbed sulfur on the surface of carbonaceous material.     

Large scale mass movements triggered by the Kashmir earthquake 2005, Pakistan

The SPOT image analysis in Muzaffarabad Azad Kashmir,northwest Himalayas,Pakistan reveals that the Kashmir earthquake 2005 triggered a number of coseismic mass movements along the hanging wall block of the Muzaffarabad Fault.The Neelidandi and Langarpura rock falls have been identified as two major reactivated mass movements with an estimated volume of 3.1 × 106m3and 5.76 × 106m3,respectively.The Neelidandi and Langarpura mass movements were initiated during earthquake in the direction of northwest-southeast extension and northeastsouthwest directed thrusting,respectively.The Neelidandi rock fall occurred in sheared cherty dolomites and limestones of the Cambrian Muzaffarabad Formation,whereas the Langarpura rock fall occurred in alternating clays,shales,claystones,siltstones and sandstones of the Miocene Murree Formation.These rock units along the fault are highly fractured and jointed.The geotechnical maps and geological longitudinal profiles show the relationship between the geometrical characteristics and mechanism of these mass movements.Their characteristics were analyzed according to the role of topographic,seismic,geological and tectonic factors.The steep topography,sheared rocks,lithology,coseismic uplift and strong ground shaking of the hanging wall block along Muzaffarabad Fault facilitated the gravity collapse of these mass movements.     

Electrostatic solitons in rotating dusty plasmas with anisotropic ion pressure

The Zakharov-Kuznetsov (ZK) equation is derived for electrostatic wave in a rotating magnetoplasma with anisotropic ion pressure and in the presence of stationary charged dust particles. The anisotropic ion pressure is defined using double adiabatic Chew-Golberger-Low (CGL) theory. The reductive perturbation method is employed to study the dynamics of obliquely propagating low frequency ion acoustic wave with adiabatic ions. It is found that the ion pressure anisotropy, polarity, density of the dust particles and rotational frequency have significant effects on the formation nonlinear structures in rotating magnetized dusty plasmas. The numerical results are also presented for illustration.     

Landslide inventory and susceptibility modelling using geospatial tools,in Hunza-Nagar valley,northern Pakistan

A comprehensive landslide inventory and susceptibility maps are prerequisite for developing and implementing landslide mitigation strategies. Landslide susceptibility maps for the landslides prone regions in northern Pakistan are rarely available. The Hunza-Nagar valley in northern Pakistan is known for its frequent and devastating landslides. In this paper, we have developed a landslide inventory map for Hunza-Nagar valley by using the visual interpretation of the SPOT-5 satellite imagery and mapped a total of 172 landslides. The landslide inventory was subsequently divided into modelling and validation data sets. For the development of landslide susceptibility map seven discrete landslide causative factors were correlated with the landslide inventory map using weight of evidence and frequency ratio statistical models. Four different models of conditional independence were used for the selection of landslide causative factors. The produced landslides susceptibility maps were validated by the success rate and area under curves criteria. The prediction power of the models was also validated with the prediction rate curve. The validation results shows that the success rate curves of the weight of evidence and the frequency models are 82% and 79%, respectively. The prediction accuracy results obtained from this study are 84% for weight of evidence model and 80% for the frequency ratio model. Finally, the landslide susceptibility index maps were classified into five different varying susceptibility zones. The validation and prediction result indicates that the weight of evidence and frequency ratio model are reliable to produce an accurate landslide susceptibility map, which may be helpful for landslides management strategies.     

Petrography,geochemistry and provenance of the sediments of the Early Cretaceous Yanguoxia Formation,Lanzhou-Minhe Basin,Northwest China

Lanzhou-Minhe Basin is situated on the middle Qilian orogenic belt. Yanguoxia Formation contains abundance of maroon siltstones, mudstones and red sandstones of the lake facies. These sedimentary rocks recorded the process of the tectonic uplift of Qilian Mountains during the Early Cretaceous. We discovered plentiful dinosaur footprints, worm burrows, bird footprints, worm tracks-trails, ripple marks and cross lamination in the Yanguoxia site. Integrated petrographic studies classified sandstones of Yanguoxia Formation as feldspathic litharenite. All plots in the QFL (Q or Qt, total quartz; F, feldspar; L, lithic grains) and QmFLt (Qm, monocrystalline quartz; Lt, lithic grains plus polycrystalline quartz) diagrams fall in the recycled orogen provenance field and quartzose recycled field, respectively, implying the source occurred the tectonic activity. Furthermore, geochemical study indicates that the Yanguoxia standstone was formed in an unstable continental setting due to the northwards movement of Indian Plate triggered the collision between the Qilian fold belt and the Qinling fold belt. These sediments were derived from a mixed source and then deposited in the Lanzhou-Minhe Basin. Most of the felsic components were derived from the granitoid rocks of the Qilian Mountains due to the rapid and intense uplift during the Early Cretaceous while the mafic components were contributed by the basic and ultrabasic rocks of the rapidly rising ophiolite in the Qilian Mountain area. Bivariant log-log plot of Qp/(F+L) (Qp, polycrystalline quartz) against Q/(F+L) shows that Yanguoxia Formation was deposited in the semi-humid and semi-arid. Moreover, the pollen also exhibits that the environmental condition during the deposition of Yanguoxia Formation was warm and wet, which affirm such environment was benefit to dinosaur survival. Geochemical study also infers that the Yanguoxia Formation was deposited under the oxidizing condition in a shallow marine environment. The minerals identified from the X-ray diffraction (XRD) analysis of shale and siltstone samples are 4.74%-33.53% clays, 23.45%-4l.70% carbonates and 33.99%-71.81% quartz, respectively, which infer that depositional conditions remained uniform during the formation of shales or siltstones of Yanguoxia Formation.     

Retrofit of reinforced concrete frames with buckling‐restrained braces

Damage to buildings observed in recent earthquakes suggests that many old reinforced concrete structures may be vulnerable to the effects of severe earthquakes. One suitable seismic retrofit solution is the installation of steel braces to increase the strength and ductility of a building. Steel bracings have some compelling advantages such as their comparatively low weight, their suitability for prefabrication, and the possibility of openings for utilities, access, and light. The braces are typically connected to steel frames that are fixed to the concrete structure using post‐installed concrete anchors along the perimeter. However, these framed steel braces are not without some disadvantages such as heavier steel usage and greater difficulties during the installation. Therefore, braces without steel frames appear to be an attractive alternative. In this study, braces were connected to gussets furnished with anchor brackets, which were fixed by means of a few post‐installed concrete anchors. The clear structural system and the increased utilization of the anchors allowed the anchorage to be designed precisely and economically. The use of buckling‐restrained braces (BRBs) provides additional benefits in comparison with conventional braces. BRBs improve the energy dissipation efficiency and allow the limitation of the brace force to be taken up by the highly stressed anchorage. Cyclic loading tests were conducted to investigate the seismic performance of BRBs connected with post‐installed anchors used to retrofit reinforced concrete frames. The tests showed that the proposed design method is feasible and increases strength as well as ductility to an adequate seismic performance level. Copyright © 2014 John Wiley & Sons, Ltd.     

Robust approach for optimal positioning and ranking potential rainwater harvesting structure (RWH): a case study of Iraq

Rainwater harvesting (RWH) structure is considered as the best solution to conserve water for arid regions. The selection of RWH location is based on several key determinants such as hydrology, environment, topography, and socio-economic. This study proposed a robust methodology to identify and select the location of RWH using geographical information systems (GIS) and remote sensing (RS) with multi-criteria decision techniques in areas where data are scarce. Several thematic maps were extracted such as vegetation cover, soil group, slope, land use, and digital elevation (DEM). The RWH sites were ranked based on four major indexes: evaporation, cost-benefit, sediment, and hydrological index. Sensitivity analysis shows that the variance inverse (VI) and rank order method (ROM) considered all indices that effect ranking as compared to the analytic hierarchy process (AHP) and fuzzy-AHP. Sensitivity analysis also proved that the proposed method is suitable to be used for RWH site selection in arid regions.     

Probabilistic seismic hazard analysis and spectral accelerations for United Arab Emirates

In recent years, the United Arab Emirates (UAE) has experienced an unprecedented growth which is coupled with the increase in seismic activity in the surroundings. Previous studies presents significant variations in their results whereas some recent studies although very detailed focus on only few cities. This study reviews the results of previous studies and presents new findings for the whole of UAE based on the improved source model and use of next generation attenuation (NGA) equations. The peak ground accelerations, spectral accelerations and deaggregation of hazard for major cities are presented. Moreover, the breakdown of the range of mapped spectral accelerations (S _0.2 and S ₁) is proposed to form the basis for the development of site amplification factors in subsequent studies. The results of this study indicate almost similar values of ground motion compared to some recently published studies and smaller values compared to some earlier studies.     

Prediction of future situation of land use/cover change and modeling sensitivity to pollution in Edku Lake,Egypt based on geospatial analyses

GeoJournal - Assessing land use/cover (LULC) change in coastal lakes is an essential process for sustainable development. Edku Lake is one of the most important lakes in the northern part of Nile...     

Population pressure, agricultural intensification and changes in rural systems in Bangladesh

Sustainable agricultural growth is the key to rural system changes that include changes in rural bio-physical environment, economic infrastructure and social conditions. The present study has examined the temporal changes in 18 selected indicators of rural systems in Bangladesh during the period 1975-2000, and explored the influences of demographic, market forces, environmental, institutional and technological factors inducing and mediating such changes. An analysis of 64 district level published census data showed significant increase in agricultural intensity, cropping patterns, land productivity and farm income; decline in labor and technological productivities; and major improvement in rural housing, economic and social conditions during this period. Spatially, major agricultural growth and rural development were observed in districts with high population density, less constrained environments, and better access to markets, irrigation canals, and capital loans.