The Impact of Geology of Recharge Areas on Groundwater Quality: A Case Study of Zhob River Basin,Pakistan

Groundwater is a major source of water supply for domestic and irrigation uses in semiarid, remote but rapidly developing Kilasaifullah district part of Zhob River Basin, located at Pakistan–Afghanistan Border. Zhob River is among few major rivers of perennial nature in Balochistan, which flows from WSW to ENE and falls in Gomal River, a tributary of Indus River. Keeping in view the important geopolitical position and rapid development of the region, this study is primarily focused on groundwater chemistry for contamination sources as well as agriculture development. Water samples from open and tube wells are analyzed and calculated for electrical conductivity (EC), total dissolved solids (TDS), turbidity, pH, K⁺, Na⁺, Ca²⁺, Mg²⁺, HCO, Cl^?, NO, SO, PO, sodium percent (Na%), sodium adsorption ratio (SAR), Kelly's index (KI), and heavy metals (Fe, Cu, Cr, Zn, Pb, and Mn). On the basis of the chemical constituents two zones within the study area are identified and possible causes of the contaminants are pointed out. Two recharge areas were responsible for the different chemical results in groundwater, e.g., zone A was recharged from NNW saline geological formations (Nisai, Khojak, Multana, Bostan formations, and Muslim Bagh ophiolites), which are concentrated with high sodium and chloride. On the other hand Zone B was sourced from SSW from carbonate rich rocks (Alozai, Loralai, Parh formations, and Muslim Bagh ophiolites). The groundwater is classified as C2–S1, C3–S1, C3–S2, C4–S2 on the basis of EC and SAR values which indicate that most of the water of both zones can be used for irrigation safely except the samples plotted in C3–S2 and C4–S2 categories which could be dangerous for soil and crops. Groundwater samples are plotted in good to permissible limits with some samples excellent to good and few samples belong to doubtful category based on sodium percent. Groundwater of zone A is unsuitable for irrigation use due to higher values of KI (more than one) but water of zone B are good for irrigation based on KI. In general, water of both zones is suitable for irrigation but care should be taken during the selection of crops which are sensitive to alkalinity or sodium hazards particularly in zone A.     

Evaluation of Bioavailability and Partitioning of Aluminum in Sediment Samples of Different Ecosystems by Modified Sequential Extraction Methods

Sequential extraction procedures are widely used to characterize the different operational fractions with different potential toxicity of metals in environmental solid samples. The present work describes the application of different analytical approaches for sequential extraction of aluminum to evaluate its mobility, availability, and persistent chemical forms in sediment samples of different fresh water ecosystems (lake, canal, and river). The conventional BCR three‐stage sequential extraction procedure (C‐BCR) was modified at each stage, by applying ultrasonic device (U‐BCR), in order to shorten the required shaking time of 16 h for each three steps (excluding the hydrogen peroxide digestion in step 3, which was not performed with ultrasonic bath), could be completed in 40, 50, and 45 min, respectively. The aluminum in all extracts were determination by atomic absorption spectrometry using nitrous oxide – acetylene flame. The accuracy of results obtained from C‐BCR and proposed U‐BCR was verified with literature reported values of certified sediment sample (BCR 701). The overall recoveries of aluminum obtained by proposed U‐BCR were found in the range of 96.7–113% of those values obtained with C‐BCR for all fractions. Use of ultrasonic device, provided a large saving in extraction time relative to conventional shaking. It was observed that major part of Al in real sediment samples (80–83% of total Al) were bound to residual fraction. The acid soluble fraction of aluminum extracted by 0.11 mol/L CH₃COOH has good correlation with aluminum content in corresponding water samples of each ecosystem.     

A geocomputational analysis of Twitter activity around different world cities

The penetration and use of social media services differs from city to city. This paper is aimed to provide a comparison of the use of Twitter between different cities of the world. We present a temporal analysis of activity on Twitter in 15 cities. Our study consists of two parts: First, we created temporal graphs of the activity in the 15 cities, through which hours of high and low activity could be identified. Second, we created heat map visualizations of the Twitter activities during the period of 19 September 2012–25 September 2013. The heat map visualizations make the periods of intense and sparse activity apparent and provide a snapshot of the activity during the whole year.     

Effects of convective available potential energy,temperature and humidity on the variability of thunderstorm frequency over Bangladesh

Theoretical and Applied Climatology - The present study examines the effects of convective available potential energy (CAPE), temperature and humidity on the spatiotemporal variation of...     

Analysis and farmers’ perception of climate change in the Kashmir Valley,India

Theoretical and Applied Climatology - Analysis of climatic variables is important for the detection and attribution of climate change trends and has received considerable attention from researchers...     

Bias correction method of high-resolution satellite-based precipitation product for Peninsular Malaysia

Theoretical and Applied Climatology - Satellite-based precipitation (SBP) is emerging as a reliable source for high-resolution rainfall estimates over the globe. However, uncertainty in SBP is...     

Causes of landslide recurrence in a loess platform with respect to hydrological processes

Irrigation-induced landslide is a recurring problem in the Heifangtai loess platform of northwest China. The landslide sites are characterized by a concave topography. Numerical modeling indicates that the groundwater table at the past-landslide site rises more quickly than the other natural platform borders under irrigation conditions. This is consistent with the field observations that seepage of the groundwater appeared in the hollow is higher than that of lateral slopes. In order to investigate the response of soil behavior due to rise in groundwater table, stress-path tests were performed on undisturbed specimens. It has been observed that the increase in pore water pressure in loess can trigger soil liquefaction and eventually results in landslide. Hence, the concave past-landslide site is much more prone to landsliding, which contributed to the landslide recurrence.     

Petroleum geochemistry of the Potwar Basin,Pakistan: II – Oil classification based on heterocyclic and polycyclic aromatic hydrocarbons

In a previous study, oils in the Potwar Basin (Upper Indus) of Pakistan were correlated based on the dissimilarity of source and depositional environment of organic matter (OM) using biomarkers and bulk stable isotopes. This study is aimed at supporting the classification of Potwar Basin oils into three groups (A, B and C) using the distribution of alkylnaphthalenes, alkylphenanthrenes, alkyldibenzothiophenes, alkyldibenzofurans, alkylfluorenes, alkylbiphenyls, triaromatic steroids, methyl triaromatic steroids, retene, methyl retenes and cadalene. The higher relative abundance of specific methyl isomers of naphthalene and phenanthrene and the presence of diagnostic aromatic biomarkers clearly indicate the terrigenous and oxic depositional environment of OM for group A oil. Group B and C oils are of marine origin and the aforementioned heterocyclic and polycyclic aromatic hydrocarbons (HCs) differentiate them clearly into two different groups. The relative percentages of heterocyclic aromatic HCs reveal that the distribution of these compounds is controlled by the depositional environment of the OM. Sulfur-containing heterocyclic aromatic HCs are higher in crude oils generated from source rocks deposited in suboxic depositional environments, while oxygen-containing heterocyclic aromatic HCs in combination with alkylfluorenes are higher in marine oxic and deltaic oils. Biomarker and aromatic HC parameters do not indicate significant differences in the thermal maturity of Potwar Basin oils. Triaromatic and methyl triaromatic steroids support the division of Potwar Basin oils into the three groups and their relative abundances are related to source OM rather than thermal maturity. Significantly higher amounts of C₂₀ and C₂₁ triaromtic steroids and the presence or absence of long chain triaromatic steroids (C₂₅, C₂₆, C₂₇, and C₂₈) indicates that these compounds are probably formed from different biological precursors in each group. Different isomers of methyl substituted triaromatic steroids are present only for short chain compounds (C₂₀–C₂₂) and the origin of these compounds may be short chain methyl steranes from unknown biological precursors.     

Estimation of concentration and exposure doses due to radon by using CR-39 plastic track detectors in the residences of Sudhnuti, Azad Kashmir, Pakistan

This paper presents the results of indoor radon concentration measurements in 120 dwellings of district Sudhnuti of Azad Kashmir. Measurements were taken with CR-39 passive alpha track detector. CR-39 based box type radon detectors were installed in a bedroom and living rooms of each house. The detectors were retrieved after exposing to indoor radon for period of 6 months and then etched in 6 M NaOH at 80°C for 16 h, the observed track densities were converted in to the indoor radon concentration. Indoor radon concentration varied from 20 ± 12 to 170 ± 4 Bq m⁻³ for the houses of the district Sudhnuti. Arithmetic mean (AM), geometric mean (GM) and geometric standard deviations (GSD) were found to be 82 ± 6, 77 ± 6 and 1.51, respectively. The minimum value of weighted average radon concentration was recorded in one of the house of Mang town, whereas the maximum value was found in the Pattan Sher Khan region. Doses due to indoor radon exposure vary from 0.50 ± 0.31 to 4.28 ± 0.11 mSv year⁻¹ AM, GM and GSD. of mean effective doses were found to be 2.06 ± 0.13, 1.95 ± 0.18 and 1.51, respectively. According to the recommendations made by the Health Protection Agency, UK (200 Bq m⁻³) all the houses surveyed are within the safe limits.