Hydrogeophysical investigations for assessing the groundwater potential in part of the Peshawar basin,Pakistan

A large number of valleys and basin systems are present in the northwestern part of the Himalayas in Pakistan which form significant aquifers in the region. Hydrogeophysical investigations in the western part of Nowshera District, a part of the intermontane Peshawar basin, were undertaken to help to determine the availability of groundwater resources in the region. Thirty vertical electrical resistivity soundings (VES) were acquired using a Schlumberger expanding array configuration with a maximum current electrode spacing (AB/2) of 150 m in delineating the groundwater potential in the study area. The results of the interpreted VES data using a combination of curve matching technique and computer iterative modeling methods suggest that the area is underlain by 3 to 5 geo-electric layers. The interpretation results showed that the geo-electrical succession consists of alluvium comprising of alternating layers of clay, silty clay, fine to coarse sands, sand with gravels and gravels of variable thickness. High subsurface resistivity values are correlated with gravel–sand units and low resistivity values with the presence of clays and silts. The modeled VES results were correlated with the pumping tests results and lithological logs of the existing wells. The pumping test suggests the transmissivity of the aquifer sediments is variable corresponding to different sediments within the area. The gravel–sand intervals having high resistivity value show high transmissivity values, whereas clay–silt sediments show low transmissivities. It is concluded that majority of the high resistive gravel–sand sediments belong to an alluvial fan environment. These gravel–sand zones are promising zones for groundwater abstraction which are concentrated in the central part of the study area.     

Felsic dykes in the Neoproterozoic Nagar Parkar Igneous Complex,SE Sindh,Pakistan: geochemistry and tectonic settings

The Nagar Parkar Igneous Complex consists of Neoproterozoic igneous and metamorphic rocks dissected by mafic, felsic, and rhyolitic dykes. The latter can be classified broadly into porphyritic felsic dykes intruding gray and pink granites at Nagar Parkar and the surrounding areas, and the orthophyric felsic dykes intruding amphibolites, deformed pink granites, and the alkaline mafic dykes in the Dhedvero area, north of Nagar Parkar. The porphyritic felsic dykes are composed of perthites, quartz, and albitic plagioclase whereas the orthopheric felsic dykes contain K-feldspar (dominant), plagioclase, and minor quartz. Geochemically, the porphyritic and orthophyric felsic dykes are subalkaline and alkaline demonstrating post-orogenic A2- and OIB-A1-type characteristic on Nb–Y–Ce and Nb–Y–3Ga ternary plots, respectively. One orthophyric felsic dyke contains normative acmite and sodium metasilicate. This study suggests two distinct tectonic regimes for the origin of the felsic dykes of the area. The porphyritic felsic dykes show similarities with the ~800–700 Ma granites of the area, the rhyolite dykes of the Mount Abu, western Rajasthan in India, and the granites of the Seychelles microcontinent. The orthophyric felsic dykes show chemical resemblance with the Tavidar volcanic suite of western Rajasthan and the Silhouette and North islands of the Seychelles microcontinent. This study confirms spatial and temporal links among the Rodinian fragments exposed in the Nagar Parkar area of Pakistan, western Rajasthan of India, and the Seychelles microcontinent.     

Quaternary fossil coral communities in uplifted strata along the Balochistan coast of Pakistan: understanding modern coral decline in the Arabian Sea

Uplifted reefs due to being important palaeoclimate archives and a rich source of information on past physical and geochemical changes globally have become the centre of marine research. The uplifted fossil Quaternary coral communities of Jiwani and Gwadar are perfect places to study the palaeoclimatic and geological changes that have shaped the Balochistan coast. Studies on the palaeodiversity of corals along the Makran coast of Pakistan are lacking. In the present study, the samples collected using line intercept method from four uplifted sites (Balochistan coast: one at Gwadar and three at Jiwani) were analysed. The relative distribution and diversity of scleractinian fossil corals was determined, and the factors responsible for coral decline along Pakistan coast were compared with modern coral distribution and diversity. A total of 48 fossil coral species were recorded in nine families and 22 genera. High coral diversity was recorded in the uplifted landward sites of Jiwani and Gwadar headland. Terraces close to the shore at Jiwani had lower diversity. The corals seem to be Quaternary: most likely Pleistocene to Holocene. The modern fauna lacks many species recorded in the fossil community, thus suggesting a faunal turnover in diversity and redistribution of coral fauna which may be linked with past geological events and increasing anthropogenic pressure.     

A Numerical Study of Effects of Valley-Weathering and Valley-Shape-Ratio on the Ground Motion Characteristics

A study of combined effects of valley-weathering and valley-shaperatio on the ground motion characteristics and associated differential ground motion (DGM) is documented in this paper. In order to properly quantify the weathering effects, a forth-order-accurate staggered-grid viscoelastic time-domain finite-difference program has been used for the simulation of SH-wave responses. Simulated results revealed that the defocusing caused by valley is frequency-independent in contrast to the ridge-focusing. A decrease of average spectral amplification (ASA) with an increase of shape-ratio of the non-weathered triangular and elliptical valleys was obtained. Overall, the amplification and de-amplification pattern was larger in case of triangular valleys as compared to the elliptical valleys. It can be concluded that the dwelling within or near the topcorners of weathered valleys may suffer more damage as compared to their surroundings. A weathered triangular valley with large shape-ratio may cause unexpected damage very near its top-corners since both the ASA and DGM are largest.     

利用GIS定量评价太湖流域的非点源污染

利用流域地图和地理信息系统(Arcview)软件评估的不同土地利用状况下的基本污染负荷,以太湖流域的子流域——锡山流域为例定量评价了流域的非点源污染. 本文包括根据流域面积和污染物平均浓度模拟流域污染负荷,进而在设施流域最优管理措施的情况下评价非点源污染. 最优管理措施提供最有效的、最实用、最大成本效益的步骤减少流域的非点源污染. 结合流域边界和土地利用资料、营养物的平均浓度、及点源负荷资料,利用WATERSHEDS 3.0 软件的扩展的PLOAD GIS模型评价了非点源污染,并利用表格和图形对模型的模拟结果进行了评估.     

Calibration of local magnitude scale for Hindukush continental subduction zone

Hindukush is an active subduction zone where at least one earthquake occurs on daily basis. For seismic hazard studies, it is important to develop a local magnitude scale using the data of local seismic network. We have computed local magnitude scale for Hindukush earthquakes using data from local network belonging to Center for Earthquake Studies (CES) for a period of three years, i.e. 2015–2017. A total of 26,365 seismic records pertaining to 2,683 earthquakes with magnitude 2.0 and greater, was used with hypocentral distance less than 600 km. Magnitude scale developed by using this data comes to be M_L = logA + 0.929logr + 0.00298r – 1.84. The magnitude determined through formulated relation was compared with that of standard relation for Southern California and relation developed by the same authors for local network for Northern Punjab. It was observed that Hindukush region has high attenuation as compared to that of Southern California and Northern Punjab which implies that Hindukush is tectonically more disturbed as compared to the said regions, hence, seismically more active as well. We have calculated station correction factors for our network. Station correction factors do not show any pattern which probably owes to the geological and tectonic complexity of this structure. Standard deviation and variance of magnitude residuals for CES network determined using Hutton and Boore scale and scale developed in this study were compared, it showed that a variance reduction of 44.1% was achieved. Average of magnitude residuals for different distance ranges was almost zero which showed that our magnitude scale was stable for all distances up to 600 km. Newly developed magnitude scale will help in homogenization of earthquake catalog. It has been observed that b-value of CES catalog decreases when magnitude is calculated by using newly developed magnitude scale.     

Initiation of a convective dust storm over North India on 21 April 2010 inferred using satellite data

Dust storms commonly occur during the pre-monsoon (summer) season in north and northwest parts of India. Characteristics of dust events of the pressure gradient type are well understood. However, comprehensive studies on mechanism of convective dust storms in India are few. A convective dust storm which occurred on 21 April 2010 in association with a western disturbance over North India was hence studied. In the absence of in situ data, we used available satellite data to study the event. Dust storm that occurred on 20 April 2010 on the surface of the Thar Desert transported dust to northern and northwestern parts of India (Rajasthan, Haryana, Delhi and some parts of Uttar Pradesh). This formed a background of aerosols that affected the thunderstorm formed in association with western disturbance and the strong updraft in the thunderstorm carried the dust lingering in the atmosphere to higher altitudes. Large amount of aerosols carried to higher altitude suppressed the chance of precipitation by affecting the cloud top microphysics. Enhancement in evaporation due to an increase in aerosol concentration and strong downdrafts during dissipation of the thunderstorm resulted in emission of dust particles which led to the convective dust event of 21 April 2010.     

GIS-based high-resolution spatial interpolation of precipitation in mountain–plain areas of Upper Pakistan for regional climate change impact studies

In this study, the baseline period (1960–1990) precipitation simulation of regional climate model PRECIS is evaluated and downscaled on a monthly basis for northwestern Himalayan mountains and upper Indus plains of Pakistan. Different interpolation models in GIS environment are used to generate fine scale (250?×?250 m²) precipitation surfaces from PRECIS precipitation data. Results show that the multivariate extension model of ordinary kriging that uses elevation as secondary data is the best model especially for monsoon months. Model results are further compared with observations from 25 meteorological stations in the study area. Modeled data show overall good correlation with observations confirming the ability of PRECIS to capture major precipitation features in the region. Results for low and erratic precipitation months, September and October, are however showing poor correlation with observations. During monsoon months (June, July, August) precipitation pattern is different from the rest of the months. It increases from south to north, but during monsoon maximum precipitation is in the southern regions of the Himalayas, and extreme northern areas receive very less precipitation. Modeled precipitation toward the end of the twenty-first century under A2 and B2 scenarios show overall decrease during winter and increase in spring and monsoon in the study area. Spatially, both scenarios show similar pattern but with varying magnitude. In monsoon, the Himalayan southern regions will have more precipitation, whereas northern areas and southern plains will face decrease in precipitation. Western and south western areas will suffer from less precipitation throughout the year except peak monsoon months. T test results also show that changes in monthly precipitation over the study area are significant except for July, August, and December. Result of this study provide reliable basis for further climate change impact studies on various resources.     

Green and Eco‐Friendly Removal of Mycotoxins with Organo‐Bentonites; Isothermal,Kinetic, and Thermodynamic Studies

In the current study the application of organo‐modified bentonite for the adsorption of mycotoxins (aflatoxin B1, citrinin, patulin, and zearalenone) is presented. The modification of clays is carried out using benzyl‐tri‐n‐butyl ammonium bromide (BTB), benzethonium chloride (BTC), and dioctyl sodium sulfosuccinate (DSS). Various experimental parameters such as pH, time, adsorbent dose, and mycotoxins concentration are thoroughly studied. The modified clays (B‐BTB, B‐BTC and B‐DSS) are characterized by X‐ray fluorescence, X‐ray diffraction, and Fourier transform infrared spectroscopy. The results depicted the high detoxification efficiency (≈99%) of modified clays for the removal of mycotoxins under optimized conditions (pH 5, time: 30 min, adsorbent amount: 50 mg). The adsorption capacities of modified clays are found in the order of: B‐BTC (AFB1: 18.02, CIT: 18.35, PAT: 18.21, ZEA: 18.09 mg g^?1) > B‐BTB (AFB1: 17.7, CIT: 18.11, PAT: 17.95, ZEA: 17.90 mg g^?1) > B‐DSS (AFB1: 17.5, CIT: 18.02, PAT: 17.86, ZEA: 17.80 mg g^?1). The obtained results fitted well with thermodynamic, isothermal (Langmuir) and pseudo‐second order kinetics. Low cost organo‐modified bentonite shows the promise in mitigating mycotoxin contamination, which could improve food safety and reduce environmental contamination.