Elemental characterization of black shales of Khyber Pakthunkhawa (KPK) region of Pakistan using AAS

Black shale samples were collected from Chimiari Khyber Pakthunkhawa region of Pakistan and were analyzed for elemental compositions. Atomic Absorption Spectrophotometry (AAS) was utilized for the determination of elements in the digested solutions. The analysis of black shale was performed precisely with relative standard deviation (RSD) lower than 2%. Results showed that the samples contained high concentrations of Ca (11.98 %), Al (7.09%), Fe (3.03%), Mg (0.59%) and Ti (0.58%).     

Use of receiver functions in wide-angle controlled-source crustal data sets

First-arrival waveforms remain underutilized in crustal refraction–reflection seismology by mostly reducing them to traveltime picks. However, as in earthquake seismology, the waveforms also contain important information about shallow near-receiver structures. We illustrate the use of three-component waveform analysis on the records from the ACCRETE wide-angle data set (SE Alaska and British Columbia; 1994), apply the Receiver Function (RF) methodology to the codas of P -wave arrivals, and draw two important conclusions. First, the P -wave polarization azimuths are found to be controlled by the near-receiver structures and virtually unrelated to the source–receiver backazimuths, from which they deviate by up to ∼40°. This observation might be important for studies of anisotropy and also for earthquake RF studies. Second, after correcting for the polarization azimuths, clear P / S mode conversions are reliably detected within 80–400 ms following the primary arrivals. The conversions are interpreted as originating at the base of the sedimentary cover of the fjord channel. In most cases, imaging of the basement requires only several records; however, notable exceptions are also found and interpreted as caused by multipathing, localized scattering, and onsets of crustal and Moho reflections. The ACCRETE example shows that RF methodology could be useful for constraining sediment thickness and deriving P - and S -wave receiver statics in land refraction surveys where collocated reflection profiles are not available. In addition, RFs from repeatable controlled sources could be useful for testing and calibration of RF techniques.     

Geochemistry and Mineralogy of Paleocene Coal from the Padhrar and Darra Adam Khel Coalfields of Pakistan

Pakistan is rich in coal resources, which amount to around 186 billion tons. The Paleocene Padhrar and Darra Adam Khel coalfields are located in the Central Salt Range Punjab Province and the Khyber Pakhtunkhwa Province, Pakistan, respectively. Padhrar coal has not been studied in detail and the Darra Adam Khel coalfields are newly-discovered, so no research has been done, due to security considerations. In this study, an attempt has been made to study the geochemical and mineralogical characteristics of the Padhrar and Darra Adam Khel coals, in order to learn about the coal quality, element enrichment mechanism, sedimentary medium conditions and potentially valuable elements for coal utilization. The Padhrar and Darra Adam Khel coals are low to medium ash, low moisture content, high in volatiles and high total sulfur coal. The vitrinite reflectance in Darra Adam Khel coal is higher than in Padhrar coal, indicating either a greater burial depth or the effects of Himalayan tectonism. The vitrinite content is dominant in the Padhrar and Darra Adam Khel coals, followed by inertinite and liptinite, the major minerals including quartz, clay minerals, calcite and pyrite. The trace elements Ni, As, Be Zn, Ge, Mo, Ta, W, Co and Nb, Sn, Hf, Ta, Pb, Th, Cd, In, Be, V, Cr, Zr, Ag, Li, W and Co are concentrated in some of the Padhrar and Darra Adam Khel coal samples, respectively. The Padhrar coal shows positive Ce, Eu and Gd anomalies, with most of the Darra Adam Khel coal showing negative Ce, Eu and positive Gd anomalies with high LREE. The Al2O3/TiO2 values indicate that the sediment source of the Padhrar and Darra Adam Khel coals is mostly related to intermediate igneous rocks. The Sr/Ba, SiO2 + Al2O3, Fe2O3 + CaO + MgO/SiO2 + Al2O3 and high sulfur content in the Padhrar and Darra Adam Khel coals indicate epithermal and marine water influence with a tidal flat, coal-forming environment and a deltaic coal-forming environment, respectively.     

Bartonian orthophragminids with new endemic species from the Pirkoh and Drazinda formations in the Sulaiman Range,Indus Basin,Pakistan

The Pirkoh and Drazinda formations in the Sulaiman Range, central Pakistan, yielded assemblages of (early) Bartonian orthophragminids, characterized predominantly by discocyclinids with a significant number of species probably endemic to Indian Subcontinent. The rarity of Asterocyclina and the absence of Orbitoclypeus and Nemkovella are noteworthy. Ten species of Discocyclina Gümbel and two species of Asterocyclina Gümbel, referable to the Shallow Benthics Zone (SBZ) 17 are described for the first time from Pakistan. The discocyclinids, i.e. Discocyclina praeomphalus, D. sulaimanensis, D. kutchensis, along with the new taxa established here, D. zindapirensis sp. nov., D. rakhinalaensis sp. nov., and D. pseudodispansa sp. nov., seem to be confined to the Indo-Pakistani region (Eastern Tethys). The Discocyclina dispansa, D. discus, D. nandori, and D. augustae lineages known from Western Tethys are also common in the Indian Subcontinent, as are asterocyclinids, such as Asterocyclina sireli and A. stellata. The upper part of the Drazinda Formation (‘Pellatispira beds’), referable to latest Bartonian and/or the early Priabonian, is poor in orthophragminids and is characterized by the occurrence of reticulate Nummulites, Heterostegina, Pellatispira and Silvestriella. The records of ‘Lepidocyclina of Caribbean affinity’ with large embryons from the Eocene of the Indian Subcontinent correspond to misidentified Discocyclina discus.     

The effect of surface profile, rock strength and pretension load on bending behaviour of fully grouted bolts

Fully encapsulated rock bolting has, in recent years, become a universally accepted system of ground reinforcement in mining and tunnel construction. The application of bolting systems extends both to rebar as well as cable bolting. The effectiveness of the bolt application has been studied in shear, both by laboratory tests as well as by numerical modeling. A specially constructed double shearing apparatus (DSA) was used to examine the shearing behaviour of a bolt installed perpendicularly across two joints. The experimental study was complemented with three-dimensional numerical analysis. Parameters examined include, the effect of reinforced material on tension/compression zones along the sheared bolt, shear resistance, shear displacement and induced strains and stresses during bolt bending process. The study was undertaken at both free load and pretension conditions. The conclusions drawn from the study were the level of bolt resistance to shear was influenced by bolt profile configuration, the strength of the rock or medium influenced the level of load generated on the bolt and the increased bolt pretension contributed to increased shearing load of the bolted medium. The numerical simulation of the bolt/medium interaction and deformational behaviour were found to be in close agreement with the experimental test results.     

Assessment of characteristics and distinguished hydrological periods of a river regime

This study was carried out to analyze the hydrological characteristics and assess the distinguished hydrological periods of Upper Indus Basin (UIB) Rivers of Pakistan. For this purpose, statistical analysis (variation coefficient, the auto-correlation coefficient, sequential Mann–Kendall’s test) and a proposed method for distinguishing hydrological periods (described in methodology section) were applied. The results revealed that all rivers reflect moderate variability. The results of auto-correlation displayed that the river flow observed at Astore gauging station only indicated independency, while for Gilgit, Hunza and Kachura guaging at Indus River exhibited 2, 2, 4-year lag. The mutation analysis indicated that after 1980, the change point occurred at all UIB rivers. During analysis, it was also observed that river regimes have the same hydrological periods (i.e., 4), but with different dates of occurrence. The Gilgit River showed a low high-flow hydrological period compared to Astore, Hunza and Kachora (Indus). This difference may be due to the river’s own area natural conditions. The current analysis may be helpful for planning and management of water resources, designing of hydraulic structures and to make better policies in response to agricultural water requirement downstream of UIB River.     

Emission quantification of refrigerant CFCs,HCFCs and HFCs in megacity Lahore (Pakistan) and contributed ODPs and GWPs

An integrated assessment of emissions of some important refrigerant ozone depleting substances (ODSs) (CFC-11, CFC-12, HCFC-141b and HFC-134a) and their contributed ozone depletion potentials (ODPs) and global warming potentials (GWPs) have been made in the megacity Lahore (Pakistan) for the period from 2005 to 2013. During the production of 6.488 million refrigerator units, the cumulative estimated emissions of CFC-11, CFC-12, HCFC-141b and HFC-134a were 129.7, 6.8, 1257 and 104 mega grams (1 Mg = 10⁶ grams). The estimated GWP (CO₂-eq) and ODP (CFC 11-eq) associated with production phase emissions of these four gases were 616.07, 73.52, 910.96, and 87.36 kilotonnes, and 129.7, 6.8, 139.4, and 0 tonnes, respectively. ODP of HFC-134a is considered to be zero. In addition, the repair and maintenance of 81.2 thousand units resulted in 10.8 Mg emissions of CFC-12 with 10.8 tonnes ODP(CFC 11-eq) and 117,802 tonnes GWP (CO₂-eq) that were higher than the HFC-134a emissions recorded at 4.3 Mg causing 4563 tonnes GWP(CO₂-eq). A decrease in ODP (CFC 11-eq) and GWP (CO₂-eq) at the rate of ?8.3% and ?8.2% per year is observed to be contributed by all the selected ODSs during the study period.     

Effects of climate anomaly on rainfall,groundwater depth,and soil moisture on peatlands in South Sumatra,Indonesia

Climate anomalies can cause natural disasters such as severe fires and floods on peatlands in South Sumatra. Factors that affect the natural disasters on peatlands include rainfall, groundwater level, and soil moisture. This paper aims to study the effect of the climate anomalies in 2019 and 2020 and effects of these influencing factors on peatlands in South Sumatra. The data used in this study was derived from in-situ measurement at two SESAME’s measurement stations in the study area. The results indicate that in the 2019 dry season, the rainfall was minimal, the lowest groundwater table depth was ?1.14 m and the lowest soil moisture was 3.4%. In the 2020 dry season, rainfall was above the monthly average of 100 mm, the lowest groundwater level was ?0.44 m, and the lowest soil moisture was 26.64%. There is also a strong correlation between soil moisture and groundwater table depth. The correlation between the two is stronger when there is less rainfall.     

Riverine flood assessment in Jhang district in connection with ENSO and summer monsoon rainfall over Upper Indus Basin for 2010

Pakistan has experienced severe floods over the past decades due to climate variability. Among all the floods, the flood of 2010 was the worst in history. This study focuses on the assessment of (1) riverine flooding in the district Jhang (where Jhelum and Chenab rivers join, and the district was severely flood affected) and (2) south Asiatic summer monsoon rainfall patterns and anomalies considering the case of 2010 flood in Pakistan. The land use/cover change has been analyzed by using Landsat TM 30 m resolution satellite imageries for supervised classification, and three instances have been compared, i.e., pre-flooding, flooding, and post-flooding. The water flow accumulation, drainage density and pattern, and river catchment areas have been calculated by using Shutter Radar Topography Mission digital elevation model 90 m resolution. The standard deviation of south Asiatic summer monsoon rainfall patterns, anomalies and normal (1979–2008) has been calculated for July, August, and September by using rainfall data set of Era interim (0.75° × 0.75° resolution). El Niño Southern Oscillation has also been considered for its role in prevailing rainfall anomalies during the year 2010 over Upper Indus Basin region. Results show the considerable changing of land cover during the three instances in the Jhang district and water content in the rivers. Abnormal rainfall patterns over Upper Indus Basin region prevailed during summer monsoon months in the year 2010 and 2011. The El Niño (2009–2010) and its rapid phase transition to La Niña (2011–2012) may be the cause of severity and disturbances in rainfall patterns during the year 2010. The Geographical Information System techniques and model based simulated climate data sets have been used in this study which can be helpful in developing a monitoring tool for flood management.