Cenozoic development of southwestern Malay Basin: new insights from subsidence analysis and thermal history

Subsidence and thermal history analysis are carried out in order to investigate the Cenozoic basin development of the southwestern (Tenggol Arch and basinal side) part of the Malay basin. Structurally, the southwestern part consists of normal faults and horst and graben geometry. Tectonic subsidence curves show that the basinal side is more active than the Tenggol Arch due to movement along normal faults. Cenozoic development initiated with the deposition of sedimentary Units M & L (Oligocene) and the activation of the Tenggol fault on the basinal side. Several periods of accelerated and slow subsidence are observed during the Oligocene to Middle Miocene that could be associated with changes in regional stresses caused by pulsating plate movement. The Malay Basin experienced inversion throughout the Middle to Late Miocene related to mantle induced slab avalanche effect, causing relatively higher tectonic subsidence rates on the Tenggol Arch compared to the basinal side, suggesting that the Tenggol Arch is less affected by inversion than the basinal side. After a period (Late Miocene) of non-deposition, the basin was reactivated (Pliocene to recent) due to thermal relaxation with thick sedimentation. Paleo heat flows estimated utilizing a novel technique introduced in this study and present day heat flow calibrated using BHT data further supports our results, in that increase in heat flow is related to rapid tectonic subsidence. An anomalously high heat pulse affected the basin during inversion and could be the cause of meta-sediment formation whereas present heat flows, although high compared to average basins, shows decreasing trend from the inversion period.     

Recent developments in immobilizing titanium dioxide on supports for degradation of organic pollutants in wastewater- A review

This review focuses on the various types of supports used for immobilization of titanium dioxide nanomaterial catalyst for degradation of organic pollutants in wastewater. Several supports suitable to particular immobilization technique used for the degradation of pollutants in wastewater streams are explained. In general, a coating of catalyst on supports is carried out either by physical (e.g., thermal treatment) or by chemical (e.g., sol–gel). Among a range of the supports used, some of the prominent ones include glass, silica, activated carbon, stainless steel, cellulose, clay. Also, characterization methods in use such as X-ray diffraction, transmission electron microscope, scanning electron microscope, and UV-spectroscopy are discussed. The operating parameters such as temperature for the selected immobilization techniques are also explained.     

Characterization of locally available soil as a liner material for solid waste landfills in Sri Lanka

This study aimed to develop a low-cost and effective clay liner material for solid waste landfills in Sri Lanka. A locally available clayey soil and its admixtures with 5 and 10% bentonite were examined for this purpose. Laboratory experiments to determine soil plasticity and swell index were carried out on the tested samples. Hydraulic conductivity (k) tests were carried out in the laboratory using water and an aqueous solution of CaCl₂ on unconsolidated samples prepared by either dry or slurry packing and pre-consolidated samples with five different consolidation pressures (p) from 10 to 200 kPa. Measured liquid limits for tested admixtures increased with increasing bentonite contents and correlated well with measured values of the swell index. The difference in permeant solutions had little effect on measured k values for both unconsolidated and pre-consolidated samples. The hydraulic conductivities were highly affected by changing p, i.e., the k values decreased on two orders of magnitude as p increased from 10 to 200 kPa. The Kozeny–Carman equation, a theoretical permeability model that expresses the k-porosity relationship, was applied to measured data including reported values. Results showed the Kozeny–Carman equation captured well the porosity-dependent k values for tested soils and their admixtures with bentonite under a wide range of void ratios, suggesting that the Kozeny–Carman equation is a useful tool to estimate the magnitude of k values for differently compacted soil and its bentonite admixtures.     

Modelling the vulnerability of groundwater to contamination in an unconfined alluvial aquifer in Pakistan

The area of Thal Doab is located in the Indus Basin and is underlain by a thick alluvial aquifer called the Thal Doab aquifer (TDA). The TDA is undergone intense hydrological stress owing to rapid population growth and excessive groundwater use for livestock and irrigated agricultural land uses. The potential impact of these land uses on groundwater quality was assessed using a DRASTIC model in a Geographic Information System environment. Seven DRASTIC thematic maps were developed at fixed scale and then combined into a groundwater vulnerability map. The resultant vulnerability index values were grouped into four zones as low, moderate, high and very high. The study has established that 76% of the land area that is underlain by the TDA has a high to very high vulnerability to groundwater contamination mainly because of a thin soil profile, a shallow water table and the presence of soils and sediments with high hydraulic conductivity values. In addition, only 2 and 22% of the total area lie in low and moderate vulnerability zones, respectively. The outcomes of this study can be used to improve the sustainability of the groundwater resource through proper land-use management.     

Optimization of area–volume–elevation curve using GIS–SRTM method for rainwater harvesting in arid areas

The major limitation in planning water harvesting is the lack of knowledge in the estimation of surface area and storage volume at any depth of dam reservoir. The area–volume–elevation (AVE) curve of a reservoir plays a key role in estimating the most suitable depth, optimum surface area and highest capacity of reservoir storage. The existing methods to estimate the AVE curve are costly and time-consuming and require laborious work. This study attempts to develop a method to optimize the AVE curve for earth dams, using the digital elevation model generated by the Shuttle Radar Topography Mission (SRTM) data, and integrate it with the geographic information system (GIS), known as the GIS–SRTM. The proposed method was tested using field data in the Western Desert of Iraq, which is an arid environment. Three constructed small earth dams were selected for this study. The AVE curves were extracted for Horan 2 (H2), Al-gara 2 (G2) and Al-gara 4 (G4) earth dams. Comprehensive analyses have been carried out to evaluate the performance of the AVE curves using the proposed GIS–SRTM method and the field data. From the comparison, the proposed GIS–SRTM method was able to produce reliable AVE curves with a relative error less than 20%. Additionally, the proposed method was less time-consuming and the AVE curves can be visualized immediately. The proposed GIS–SRTM method is relatively supportive in analyzing spatial data to select the optimal site for rainwater harvesting and prevent excessive evaporation losses.     

Hydrogeophysical investigations for assessing the groundwater potential in part of the Peshawar basin,Pakistan

A large number of valleys and basin systems are present in the northwestern part of the Himalayas in Pakistan which form significant aquifers in the region. Hydrogeophysical investigations in the western part of Nowshera District, a part of the intermontane Peshawar basin, were undertaken to help to determine the availability of groundwater resources in the region. Thirty vertical electrical resistivity soundings (VES) were acquired using a Schlumberger expanding array configuration with a maximum current electrode spacing (AB/2) of 150 m in delineating the groundwater potential in the study area. The results of the interpreted VES data using a combination of curve matching technique and computer iterative modeling methods suggest that the area is underlain by 3 to 5 geo-electric layers. The interpretation results showed that the geo-electrical succession consists of alluvium comprising of alternating layers of clay, silty clay, fine to coarse sands, sand with gravels and gravels of variable thickness. High subsurface resistivity values are correlated with gravel–sand units and low resistivity values with the presence of clays and silts. The modeled VES results were correlated with the pumping tests results and lithological logs of the existing wells. The pumping test suggests the transmissivity of the aquifer sediments is variable corresponding to different sediments within the area. The gravel–sand intervals having high resistivity value show high transmissivity values, whereas clay–silt sediments show low transmissivities. It is concluded that majority of the high resistive gravel–sand sediments belong to an alluvial fan environment. These gravel–sand zones are promising zones for groundwater abstraction which are concentrated in the central part of the study area.     

Felsic dykes in the Neoproterozoic Nagar Parkar Igneous Complex,SE Sindh,Pakistan: geochemistry and tectonic settings

The Nagar Parkar Igneous Complex consists of Neoproterozoic igneous and metamorphic rocks dissected by mafic, felsic, and rhyolitic dykes. The latter can be classified broadly into porphyritic felsic dykes intruding gray and pink granites at Nagar Parkar and the surrounding areas, and the orthophyric felsic dykes intruding amphibolites, deformed pink granites, and the alkaline mafic dykes in the Dhedvero area, north of Nagar Parkar. The porphyritic felsic dykes are composed of perthites, quartz, and albitic plagioclase whereas the orthopheric felsic dykes contain K-feldspar (dominant), plagioclase, and minor quartz. Geochemically, the porphyritic and orthophyric felsic dykes are subalkaline and alkaline demonstrating post-orogenic A2- and OIB-A1-type characteristic on Nb–Y–Ce and Nb–Y–3Ga ternary plots, respectively. One orthophyric felsic dyke contains normative acmite and sodium metasilicate. This study suggests two distinct tectonic regimes for the origin of the felsic dykes of the area. The porphyritic felsic dykes show similarities with the ~800–700 Ma granites of the area, the rhyolite dykes of the Mount Abu, western Rajasthan in India, and the granites of the Seychelles microcontinent. The orthophyric felsic dykes show chemical resemblance with the Tavidar volcanic suite of western Rajasthan and the Silhouette and North islands of the Seychelles microcontinent. This study confirms spatial and temporal links among the Rodinian fragments exposed in the Nagar Parkar area of Pakistan, western Rajasthan of India, and the Seychelles microcontinent.     

Quaternary fossil coral communities in uplifted strata along the Balochistan coast of Pakistan: understanding modern coral decline in the Arabian Sea

Uplifted reefs due to being important palaeoclimate archives and a rich source of information on past physical and geochemical changes globally have become the centre of marine research. The uplifted fossil Quaternary coral communities of Jiwani and Gwadar are perfect places to study the palaeoclimatic and geological changes that have shaped the Balochistan coast. Studies on the palaeodiversity of corals along the Makran coast of Pakistan are lacking. In the present study, the samples collected using line intercept method from four uplifted sites (Balochistan coast: one at Gwadar and three at Jiwani) were analysed. The relative distribution and diversity of scleractinian fossil corals was determined, and the factors responsible for coral decline along Pakistan coast were compared with modern coral distribution and diversity. A total of 48 fossil coral species were recorded in nine families and 22 genera. High coral diversity was recorded in the uplifted landward sites of Jiwani and Gwadar headland. Terraces close to the shore at Jiwani had lower diversity. The corals seem to be Quaternary: most likely Pleistocene to Holocene. The modern fauna lacks many species recorded in the fossil community, thus suggesting a faunal turnover in diversity and redistribution of coral fauna which may be linked with past geological events and increasing anthropogenic pressure.     

Length-weight relationship of eleven species of marine catfishes from the northern Arabian Sea coast of Pakistan

This study records length-weight relationships(LWRs)for eleven commercially important marine catfi sh species of the family Ariidae(sea catfi shes)and Plotosidae(eel catfi shes)from the northern Arabian Sea coast of Pakistan.The specimens were sampled from December 2014 to November 2015,using bottom trawls with various mesh sizes by commercial vessels.The species were Nemapteryx caelatus,Sciades sona,Arius gagora,Batrachocephalus mino,Netuma thalassina,N.bilineata,Osteogeneiosus militaris,Plicofollis dussumieri,P.tenuispinis,Plotosus limbatus,and P.lineatus.Of the eleven species,two species A.gagora and N.bilineata were recorded for the fi rst time and LWRs for four species A.gagora,N.bilineata,S.sona,and B.mino still have no data in the Fish Base database.In addition,new maximum length for each of the three species N.bilineata,O.militaris and B.m ino was also found.