New insights into the origin of perylene in geological samples

The origin of the polycyclic aromatic hydrocarbon (PAH) perylene in sediments and petroleum has been a matter of continued debate. Reported to occur in Phanerozoic organic matter (OM), fossil crinoids and tropical termite mounds, its mechanism of formation remains unclear. While a combustion source can be excluded, structural similarities to perylene quinone-like components present in e.g. fungi, plants, crinoids and insects, potentially suggest a product-precursor relationship. Here, we report perylene concentrations, ¹³C/¹²C, and D/H ratios from a Holocene sediment profile from the Qingpu trench, Yangtze Delta region, China. Perylene concentrations differ from those of pyrogenic PAHs, and rise to prominence in a stratigraphic interval that was dominated by woody vegetation as determined by palynology including fungal spores. In this zone, perylene concentrations exhibit an inverse relationship to the lignin marker guaiacol, D/H ratios between −284‰ and −317‰, similar to the methoxy groups in lignin, as well as co-variation with spores from wood-degrading fungi. ¹³C/¹²C of perylene differs from that of land plant wax alkanes and falls in the fractionation range expected for saprophytic fungi that utilise lignin, which is isotopically lighter than cellulose and whole wood. During progressive lignin degradation, the relative carbon isotopic ratio of the perylene decreases. We therefore hypothesise a relationship of perylene to the activity of wood-degrading fungi. To support our hypothesis, we analysed a wide range of Phanerozoic sediments and oils, and found perylene to generally be present in subordinate amounts before the evolutionary rise of vascular plants, and to be generally absent from marine-sourced oils, few exceptions being attributed perhaps to a contribution of marine and/or terrestrial-derived fungi, anoxia (especially under marine conditions) and/or contamination of core material by fungi. A series of low-molecular-weight aromatic quinones bearing the perylene-backbone were detected in Devonian and Cretaceous sediments, potentially representing precursor components to perylene.     

Non-vacuum static cylindrically symmetric solution and energy distribution in f(R) gravity

In this paper, we investigate static cylindrically symmetric solution in metric f(R) gravity by taking matter in the form of dust. The assumption of constant Ricci scalar curvature is taken to find the solution. The energy distribution of this solution is explored by applying Landau-Lifshitz energy-momentum complex. In addition, we explore the stability as well as constant scalar curvature conditions for some viable f(R) models along with their energy distribution. It is interesting to mention here that these models satisfy the above mentioned conditions.     

Seismic sources for southern Pakistan and seismic hazard assessment of Karachi

Natural Hazards - Karachi is Pakistan’s largest city with population exceeding 18 million and is amongst the top five most congested cities in the world. Karachi has experienced no earthquake...     

Household vulnerability and resilience in flood hazards from disaster-prone areas of Punjab,Pakistan

Natural Hazards - An environmental variation has caused Pakistan an alarming portrait of vulnerability in flood disasters. The government has focused on a number of realistic actions, heartening...     

辽东半岛复州湾剖面寒武系第二统光合作用生物膜建造的核形石

作为一种经常大于鲕粒的包覆颗粒类型,核形石以其不平滑的圈层被解释为微生物成因,区别于成因存在较大争议的鲕粒,而且常与鲕粒和其他类型的碳酸盐颗粒相互共生;作为一种在围绕着生物碎屑和非生物碎屑核心的序列式纹层化作用过程中形成的球形或假球型生物沉积构造,核形石还常常单独产出和分布,所以又被解释为微生物碳酸盐岩,或者被归为球状叠层石。在辽东半岛寒武系第二统碱厂组和馒头组之中,厘米级别大小的核形石密集发育在三级层序的顶部,成为一种时间特化的相。另外,以下重要特征将辽东半岛寒武系第二统的核形石特征化,包括:(1)与凝块和微凝块共生;(2)多为球状和椭球状;(3)由不均一的非纹层状致密泥晶和微亮晶构成;(4)核形石皮层以及核形石间凝块中发育特别的蓝细菌鞘钙化化石等。尽管穿越成岩作用过滤器去解释古代核形石复杂的形成机理存在着巨大的挑战,也尽管形成这些核形石的复杂生物膜钙化作用细节需要更加深入地研究才能得到更好地了解,但是,辽东半岛第二统碱厂组和馒头组核形石中直接的微生物化石证据,尤其是核形石内较为丰富的钙化蓝细菌鞘化石,使其成为一个了解光合作用生物膜建造核形石的典型实例。     

Genetic Structure and Diversity of the Moon Jellyfish Aurelia coerulea Polyp Population in Jaran Bay,Korea, Revealed by Mitochondrial COI and 16S rRNA Genes

Ocean Science Journal - Blooms of the moon jellyfish (Aurelia coerulea) have been responsible for huge economic losses and environmental disruptions in oceans around the world. The mass occurrence...     

Imaging of Stratigraphic Pinch-Out Traps Within the Lower-Cretaceous Shaly-Sandstone System,Pakistan, Using 3D Quantitative Seismic Inverted Porosity–Velocity Modeling

Incised valleys form excellent stratigraphic pinch-out traps. Traditional seismic data analysis techniques fail to predict quantitatively the porous and low-velocity sand-fills for incised valleys. The 3D quantitative seismic inverted porosity–velocity (3DQSIPV) analysis was applied in the Indus Basin, SW Pakistan. The reflection strength attribute better portrayed the reservoir sandstone and faults compared to seismic amplitude attribute. The sweetness-based continuous wavelet transform authenticated the development of the stratigraphic play. The 17 Hz amplitude delineated the non-porous seal and porous reservoirs of sand-filled incised valley and strand plain, and faults. The integrated model of seismic attributes categorizes the reservoir and seal constituents. The petrophysical modeling corroborated the gas-bearing “sweet-spots” within the stratigraphic-based dynamical system. The facies modeling predicted the for coarse-grained sandstone and fine-grained shales, depositional environments, fluctuations of sea level and their impacts on the overall development of stratigraphic plays. The predicted density and P-wave velocity for the sandstone-filled incised valley of the lowstand system tract were?~?1.4–1.75 g/cc and?~?3217–3802 m/s, respectively. The predicted density and P-wave velocity for the sealing shales facies of strand plain of transgressive system tract were?~?1.9–2.1 g/cc and 2.55–2.7 g/cc and 3900–4700 m/s, respectively. The 3DQSIPV predicted?>?25% porosity and?~?3300 m/s velocity of reservoirs in the west. The eastern zones shows?<?12% porosity and high velocity of?~?4580 m/s. Cross-plots of porosity, velocity, and thickness showed correlation coefficients of R²?>?0.90 for inverted velocity. This workflow may serve as an analogue for the remaining oil and gas fields of the Indus Basins of Pakistan and similar geological settings of divergent plate margins.

     

Performance of CMORPH,TMPA, and PERSIANN rainfall datasets over plain,mountainous, and glacial regions of Pakistan

The present study aims at the assessment of six satellite rainfall estimates (SREs) in Pakistan. For each assessed products, both real-time (RT) and post adjusted (Adj) versions are considered to highlight their potential benefits in the rainfall estimation at annual, monthly, and daily temporal scales. Three geomorphological climatic zones, i.e., plain, mountainous, and glacial are taken under considerations for the determination of relative potentials of these SREs over Pakistan at global and regional scales. All SREs, in general, have well captured the annual north-south rainfall decreasing patterns and rainfall amounts over the typical arid regions of the country. Regarding the zonal approach, the performance of all SREs has remained good over mountainous region comparative to arid regions. This poor performance in accurate rainfall estimation of all the six SREs over arid regions has made their use questionable in these regions. Over glacier region, all SREs have highly overestimated the rainfall. One possible cause of this overestimation may be due to the low surface temperature and radiation absorption over snow and ice cover, resulting in their misidentification with rainy clouds as daily false alarm ratio has increased from mountainous to glacial regions. Among RT products, CMORPH-RT is the most biased product. The Bias was almost removed on CMORPH-Adj thanks to the gauge adjustment. On a general way, all Adj versions outperformed their respective RT versions at all considered temporal scales and have confirmed the positive effects of gauge adjustment. CMORPH-Adj and TMPA-Adj have shown the best agreement with in situ data in terms of Bias, RMSE, and CC over the entire study area.     

Processes of initial collision and suturing between India and Asia

The initial collision between Indian and Asian continents marked the starting point for transformation of land-sea thermal contrast, uplift of the Tibet-Himalaya orogen, and climate change in Asia. In this paper, we review the published literatures from the past 30 years in order to draw consensus on the processes of initial collision and suturing that took place between the Indian and Asian plates. Following a comparison of the different methods that have been used to constrain the initial timing of collision, we propose that the tectono-sedimentary response in the peripheral foreland basin provides the most sensitive index of this event, and that paleomagnetism presents independent evidence as an alternative, reliable, and quantitative research method. In contrast to previous studies that have suggested collision between India and Asia started in Pakistan between ca. 55 Ma and 50 Ma and progressively closed eastwards, more recent researches have indicated that this major event first occurred in the center of the Yarlung Tsangpo suture zone (YTSZ) between ca. 65 Ma and 63 Ma and then spreading both eastwards and westwards. While continental collision is a complicated process, including the processes of deformation, sedimentation, metamorphism, and magmatism, different researchers have tended to define the nature of this event based on their own understanding, an intuitive bias that has meant that its initial timing has remained controversial for decades. Here, we recommend the use of reconstructions of each geological event within the orogenic evolution sequence as this will allow interpretation of collision timing on the basis of multidisciplinary methods.     

DHI evaluation by combining rock physics simulation and statistical techniques for fluid identification of Cambrian-to-Cretaceous clastic reservoirs in Pakistan

The use of seismic direct hydrocarbon indicators is very common in exploration and reservoir development to minimise exploration risk and to optimise the location of production wells. DHIs can be enhanced using AVO methods to calculate seismic attributes that approximate relative elastic properties. In this study, we analyse the sensitivity to pore fluid changes of a range of elastic properties by combining rock physics studies and statistical techniques and determine which provide the best basis for DHIs. Gassmann fluid substitution is applied to the well log data and various elastic properties are evaluated by measuring the degree of separation that they achieve between gas sands and wet sands. The method has been applied successfully to well log data from proven reservoirs in three different siliciclastic environments of Cambrian, Jurassic, and Cretaceous ages. We have quantified the sensitivity of various elastic properties such as acoustic and extended elastic (EEI) impedances, elastic moduli (K _sat and K _sat–μ), lambda–mu–rho method (λρ and μρ), P-to-S-wave velocity ratio (V _P/V _S), and Poisson’s ratio (σ) at fully gas/water saturation scenarios. The results are strongly dependent on the local geological settings and our modeling demonstrates that for Cambrian and Cretaceous reservoirs, K _sat–μ, EEI, V _P/V _S, and σ are more sensitive to pore fluids (gas/water). For the Jurassic reservoir, the sensitivity of all elastic and seismic properties to pore fluid reduces due to high overburden pressure and the resultant low porosity. Fluid indicators are evaluated using two metrics: a fluid indicator coefficient based on a Gaussian model and an overlap coefficient which makes no assumptions about a distribution model. This study will provide a potential way to identify gas sand zones in future exploration.