Risk analysis of health,safety and environment in chemical industry integrating linguistic FMEA,fuzzy inference system and fuzzy DEA

Stochastic Environmental Research and Risk Assessment - Organizations are continuously endeavoring to provide a healthy work environment without any incident, by Health, Safety, and Environment...     

Tensionless–frictionless interaction of flexible annular foundation with a transversely isotropic multi‐layered half‐space

A transversely isotropic multi‐layered half‐space, with axis of material symmetry perpendicular to the free surface, supports a flexible either annular or solid circle foundation. The contact area of the foundation and the half‐space is considered to be both frictionless and tensionless. The foundation is assumed to be affected by a vertical static axisymmetric load. Detailed analysis of the interaction of these two systems with different thickness of layers is the target of this paper. With the use of ring load Green's functions for both the foundation and the continuum half‐space, an integral equation accompanied with some inequalities is introduced to model the complex BVP. With the incorporation of ring‐shape FEM, we are capable of capturing both regular and singular solution smoothly. The validity of the combination of the analytical and numerical method is proved with comparing the results of this paper with a number of benchmark cases of both linear and nonlinear interaction of circular and annular foundation with half‐space. Some new illustrations are presented to portray the aspect of the anisotropy and layering of the half‐space. Copyright © 2014 John Wiley & Sons, Ltd.     

Leaching of an oxide gold ore with chloride/hypochlorite solutions

An oxide gold ore was subjected to chloride/hypochlorite leaching at room temperature. The effects of three factors, including Ca(OCl)₂ vs. NaOCl, OCl⁻ concentration, and HCl concentration on gold leaching performance were investigated. Due to formation of CaOCl⁺ complex in solution and hence less reactivity, calcium hypochlorite produces a sluggish gold leaching kinetics, taking twice the time (46 h) to achieve maximum gold recovery of 58% compared to sodium hypochlorite. 10 g/L of total initial hypochlorite species in solution produces reasonable gold recoveries. The amount of added HCl and hence the initial pH was found to have a major effect on gold leaching kinetics and maximum gold recovery. A high level of 9 g/L of added HCl causes HClO to be very reactive, producing very fast kinetics, reaching 67% gold extraction in 4 h. It also causes a faster consumption of hypochlorous acid, through catalytic decomposition (by NiO and CuO) and disproportionation. Hypochlorous acid reactions with sulfide and ferrous content of ore proceed very slowly in the pH range of 4–11. Gold–chloro complexes are strongly adsorbed on quartz component of ore. To minimize this undesirable adsorption of gold–chloro species, the aging time must be limited to a few hours only.     

An investigation on the ground motion parameters and seismic response of underground structures

Peak ground acceleration (PGA), frequency content and time duration are three fundamental parameters of seismic loading. This study focuses on the seismic load frequency and its effect on the underground structures. Eight accelerograms regarding different occurred earthquakes that are scaled to an identical PGA and variation of ground motion parameters with ratio of peak ground velocity (PGV) to PGA, as a parameter related to the load frequency, are considered. Then, concrete lining response of a circular tunnel under various seismic conditions is evaluated analytically. In the next, seismic response of underground structure is assessed numerically using two different time histories. Finally, effects of incident load frequency and frequency ratio on the dynamic damping of geotechnical materials are discussed. Result of analyses show that specific energy of seismic loading with identical PGA is related to the seismic load frequency. Furthermore, incident load frequency and natural frequency of a system have influence on the wave attenuation and dynamic damping of the system.     

Biofiltration of Hexane Vapor: Experimental and Neural Model Analysis

Biofiltration is a commonly practiced biological technique to remove volatile compounds from waste gas streams. From an industrial view‐point, biofilter (BF) operation should be flexible to handle temperatures and inlet load (IL) variations. A compost BF was operated at different temperatures (30–45°C) and at various inlet loading rates (ILR; 8–598 g m^?3 h^?1) under intermittent loading conditions. Complete removal of n‐hexane was observed at 30 and 35°C at ILRs up to 330 g m^?3 h^?1. Besides, 20–75% of the pollutant was removed at 40°C, corresponding to the different ILs applied to the BF. Increasing the temperature to 45°C decreased the removal efficiency (RE) significantly. A feed forward neural network was used to predict the RE of BF with temperature and ILR as the input variables. The experimental data was divided into training (2/3) and test datasets (1/3). The best structure of neural network was obtained by trial and error on the basis of the least differences between predicted and experimental values, as ascertained from their coefficient of regression (R²) values. The modeling results showed that a multilayer network with the topology 2?10?1 was able to predict BF performance effectively with R²‐value of 0.995 for the test data. The results from this study showed the predicting capability of ANNs which can be considered as an alternative for conventional knowledge‐based models.     

Mixed model for interoccurrence times of earthquakes based on the expectation-maximization algorithm

In this paper, the goodness-of-fit test based on a convex combination of Akaike and Bayesian information criteria is used to explain the features of interoccurrence times of earthquakes. By analyzing the seismic catalog of Iran for different tectonic settings, we have found that the probability distributions of time intervals between successive earthquakes can be described by the generalized normal distribution. This indicates that the sequence of successive earthquakes is not a Poisson process. It is found that by decreasing the threshold magnitude, the interoccurrence time distribution changes from the generalized normal distribution to the gamma distribution in some seismotectonic regions. As a new insight, the probability distribution of time intervals between earthquakes is described as a mixture distribution via the expectation-maximization algorithm.     

The western Durkan Complex (Makran Accretionary Prism,SE Iran): A Late Cretaceous tectonically disrupted seamounts chain and its role in controlling deformation style

The Durkan Complex is a key tectonic element of the Makran accretionary prism (SE Iran) and it has been interpreted as representing a continental margin succession. We present here a multidisciplinary study of the western Durkan Complex, which is based on new geological, stratigraphic, biostratigraphic data, as well as geochemical data of the volcanic and meta-volcanic rocks forming this complex. Our data show that this complex consists of distinct tectonic slices showing both non-metamorphic and very low-grade metamorphic deformed successions. Stratigraphic and biostratigraphic data allow us to recognize three types of successions. Type-I is composed by a Coniacian – early Campanian pelagic succession with intercalation of pillow lavas and minor volcaniclastic rocks. Type-II succession includes a volcanic sequence passing to a volcano-sedimentary sequence with Cenomanian pelagic limestones, followed by a hemipelagic sequence. This succession is characterized by abundant mass-transport deposits. Type-III succession includes volcanic and volcano-sedimentary sequences, which are stratigraphically covered by a Cenomanian platform succession. The latter is locally followed by a hemipelagic sequence. The volcanic rocks in the different successions show alkaline geochemical affinity, suggesting an origin from an oceanic within-plate setting. Our new results indicate that the western Durkan Complex represents fragments of seamounts tectonically incorporated in the Makran accretionary wedge during the latest Late Cretaceous–Paleocene. We propose that incorporation of seamounts in the frontal prism caused a shortening of the whole convergent margin and possibly contributed to controlling the deformation style in the Makran Accretionary Wedge during Late Cretaceous–Paleocene times.     

Forced vertical and horizontal movements of a rectangular rigid foundation on a transversely isotropic half‐space

An analytical investigation of a half‐space containing transversely isotropic material under forced vertical and horizontal displacements applied on a rectangular rigid foundation is presented in this paper. With the goal of a rigorous solution to the shape‐ and rigidity‐ induced singular mixed boundary value problem, the formulation employs scalar potential representation, the Fourier expansion and the Hankel integral transforms method to obtain the surface arbitrary point‐load solution in cylindrical coordinate system. The obtained Green's functions are rewritten in rectangular coordinate system, allowing the response of the half‐space because of an arbitrary distributed load on a rectangular surface area be given in terms of a double integral. The numerical evaluations of stresses are done with the use of an element, which is singular at the edge and the corner of the rectangle. Upon the imposition of the rigidity displacement boundary condition for a rigid foundation and the use of a set of two‐dimensional adaptive‐gradient elements, which can capture the singular behavior in the contact stress effectively, a set of new numerical results are presented to illustrate the effect of transverse isotropy on the foundation response. Copyright © 2012 John Wiley & Sons, Ltd.