Acute toxicity of mine tailings to four marine species

Acute toxicity bioassays were conducted on mine tailings produced by pilot plant testing for the proposed Quartz Hill molybdenum mine, which will be situated near Ketchikan, Alaska. Tailings bioassays were conducted in seawater with juvenile coho salmon (Oncorhynchus kisutch), mussel larvae (Mytilus edulis), infaunal amphipods (Rhepoxynius abronius), and euphausiids (Euphausia pacifica). The same general range of mine tailings concentrations was acutely toxic to all four test species with acute effects observed between 61 000 to 277 000 mg l^?1 (wet wt) tailings solids (range of 95% confidence limits for LC₅₀ and EC₅₀ values). Chemical analyses of bioassay test solutions and leaching test solutions were conducted for metals (including Cd, Cu, Pb, Zn, Mn and Mo), EPA Priority Pollutant base/neutral organics, and more general parameters such as sulphate, nitrate/nitrite, cyanides, phosphate and ammonia. Parameters possibly contributing to the observed toxicity were complex contaminant mixtures including total suspended solids and heavy metals. The present study provides information related to the marine disposal of mine tailings and shows that these mine tailings present a relatively low level of acutely toxic effects.     

Detection of Pharmaceuticals and Personal Care Products in Agricultural Soils Receiving Biosolids Application

Increasing research has suggested that biosolids generated from municipal wastewater treatment can be a major sink for many pharmaceuticals and personal care products (PPCPs) and their land application potentially introduces these contaminants into the terrestrial and aquatic environments. In this study, methods were developed for the analysis of 14 PPCPs in biosolids and soils using pressurized liquid extraction, solid phase extraction and liquid chromatography‐tandem mass spectrometry. Recoveries were over 50% for all analytes except diphenhydramine (?30%) in soils. Soil properties or type of biosolids showed minor effects on method recoveries. Estimated method limits of quantification (LOQ) range from 0.1–15 ng g^–1 for soil and 0.3–27 ng g^–1 for biosolids. A field study utilizing the methods revealed that other than carbamazepine‐10,11‐epoxide, all targeted compounds were detected in biosolids. Diphenhydramine, fluoxetine, triclosan and triclocarban were detected up to the μg g^–1 range with the highest concentration of 23 μg g^–1 for triclocarban. Seven of the PCCPs found in biosolids were also detected in agricultural soils amended with these biosolids and several (carbamazepine, diphenhydramine, and triclocarban) appeared to be persistent in soils. Triclocarban was also found most abundant in soils with the highest average concentration of 0.2 μg g^–1 while the rest of compounds were in the lower ng g^–1 range. Generally, the concentrations found on the fields were 2–3 degrees of magnitude lower than in the biosolids, which is likely to be due to dilution, degradation and leaching processes.     

Micro- to nano-scale characterization of martite from a banded iron formation in India and a lateritic soil in Brazil

The pseudomorphic transformation of magnetite into hematite (martitization) is widespread in geological environments, but the process and mechanism of this transformation is still not fully understood. Micro- and nano-scale techniques—scanning electron microscopy, focused ion bean transmission electron microscopy, and Raman spectroscopy—were used in combination with X-ray diffraction, Curie balance and magnetic hysteresis analyses, as well as Mössbauer spectroscopy on martite samples from a banded iron formation (2.9 Ga, Dharwar Craton, India), and from lateritic soils, which have developed on siliciclastic and volcanic rocks previously affected by metamorphic fluids (Minas Gerais, Brazil). Octahedral crystals from both samples are composed of hematite with minor patches of magnetite, but show different structures. The Indian crystals show trellis of subhedral magnetite hosting maghemite in sharp contact with interstitial hematite crystals, which suggests exsolution along parting planes. Grain boundary migrations within the hematite point to dynamic crystallization during deformation. Dislocations and fluid inclusions in hematite reflect its precipitation related to a hydrothermal event. In the Brazilian martite, dislocations are observed and maghemite occurs as Insel structures and nano-twin sets. The latter, typical for the hematite, are a transformation product from maghemite into hematite. For both samples, a deformation-induced hydrothermally driven transformation from magnetite via maghemite to hematite is proposed. The transformation from magnetite into maghemite comprises intermediate non-stoichiometric magnetite steps related to a redox process. This study shows that martite found in supergene environment may result from earlier hypogene processes.     

Cosmic ray exposure ages of features and events at the apollo landing sites

Cosmic ray exposure ages of lunar samples have been used to date surface features related to impact cratering and downslope movement of material. Only when multiple samples related to a feature have the same rare gas exposure age, or when a single sample has the same⁸¹Kr-Kr and track exposure age can a feature be considered reliably dated. Because any single lunar sample is likely to have had a complex exposure history, assignment of ages to features based upon only one determination by any method should be avoided. Based on the above criteria, there are only five well-dated lunar features: Cone Crater (Apollo 14) 26 m.y., North Ray Crater (Apollo 16) 50 m.y., South Ray Crater (Apollo 16) 2 m.y., the emplacement of the Station 6 boulders (Apollo 17) 22 m.y., and the emplacement of the Station 7 boulder (Apollo 17) 28 m.y. Other features are tentatively dated or have limits set on their ages: Bench Crater (Apollo 12) ?99 m.y., Baby Ray Crater (Apollo 16) ?2 m.y., Shorty Crater (Apollo 17) ≈ 30 m.y., Camelot Crater (Apollo 17) ?140 m.y., the emplacement of the Station 2 boulder 1 (Apollo 17) 45–55 m.y., and the slide which generated the light mantle (Apollo 17) ?50 m.y.     

Probing the Fundamental Physics of the Solar Corona with Lunar Solar Occultation Observations

Imaging and spectroscopy of the solar corona, coupled with polarimetry, are the only tools available at present to capture signatures of physical processes responsible for coronal heating and solar wind acceleration within the first few solar radii above the solar limb. With the recent advent of improved detector technology and image processing techniques, broad-band white light and narrow-band multi-wavelength observations of coronal forbidden lines, made during total solar eclipses, have started to yield new views about the thermodynamic and magnetic properties of coronal structures. This paper outlines these unique capabilities, which until present, have been feasible primarily with observations during natural total solar eclipses. This work also draws attention to the exciting possibility of greatly increasing the frequency and duration of solar eclipse observations with Moon orbiting observatories utilizing lunar limb occultation of the solar disk for coronal measurements.     

Hard X-ray states and radio emission in GRS 1915+105

We compare simultaneous Ryle Telescope radio and Rossi X-Ray Timing Explorer X-ray observations of the galactic microquasar GRS 1915+105, using the classification of the X-ray behaviour in terms of three states as previously established. We find a strong (one-to-one) relation between radio oscillation events and series of spectrally hard states in the X-ray light curves, if the hard states are longer than ∼100 s and are 'well separated' from each other. In all other cases the source shows either low-level or high-level radio emission, but no radio oscillation events. During intervals when the source stays in the hard spectral state for periods of days to months, the radio behaviour is quite different; during some of these intervals a quasi-continuous jet is formed with an almost flat synchrotron spectrum extending to at least the near-infrared. Based on the similarities between the oscillation profiles at different wavelengths, we suggest a scenario which can explain most of the complex X-ray:radio behaviour of GRS 1915+105. We compare this behaviour with that of other black hole sources, and challenge previous reports of a relation between spectrally soft X-ray states and the radio emission.     

FLAIR observations of planetary nebulae in the Large Magellanic Cloud

This paper presents new observations of 97 planetary nebulae in the Large Magellanic Cloud (LMC) obtained using the FLAIR system on the UK 1.2-m Schmidt Telescope. These nebulae are mostly at the fainter end of the known population, and about 75 per cent have not been observed before in spectroscopic mode. Radial velocities have been measured using cross-correlation techniques, and represent an increase of 66 per cent in the sample of LMC planetary nebulae with known radial velocities. The major line ratios are given, and are analysed in conjunction with published data. One-quarter of the faint nebulae are Type I objects with very strong [N II ] and [S II ] lines; most of the other faint nebulae have low density, low excitation and relatively strong [S II ] lines.     

RXTE spectroscopy of GRS 1915+105

The galactic superluminal motion source GRS 1915+105 has been extensively observed with the RXTE satellite over the last two years. More than 250 RXTE pointings have been performed until mid-May 1998 with more than 1.5 Msec exposure time on roughly a weekly basis. Here we report on first results of our spectral analysis of a major part of these pointed RXTE observations. We establish the existence of at least 5 spectral components and present the changes of these components over the last two years.     

Magnetic mineralogy of the Yaxcopoil‐1 core,Chicxulub

Abstract— Core from the Yaxcopoil‐1 (Yax‐1) hole, drilled as a result of the Chicxulub Scientific Drilling Project (CSDP), has been analyzed to investigate the relationship between opaque mineralogy and rock magnetic properties. Twenty one samples of suevite recovered from the depth range 818–894 m are generally paramagnetic, with an average susceptibility of 2000 times 10^?6 SI and have weak remanent magnetization intensities (average 0.1 A/m). The predominant magnetic phase is secondary magnetite formed as a result of low temperature (<150 °C) alteration. It occurs in a variety of forms, including vesicle infillings associated with quartz and clay minerals and fine aggregates between plagioclase/diopside laths in the melt. Exceptional magnetic properties are found in a basement clast (metamorphosed quartz gabbro), which has a susceptibility of >45000 times 10^?6 SI and a remanent magnetization of 77.5 A/m. Magnetic mafic basement clasts are a common component in the Yax‐1 impactite sequence. The high susceptibility and remanence in the mafic basement clasts are caused by the replacement of amphiboles and pyroxenes by an assemblage with fine <1 μm magnetite, ilmenite, K‐feldspar, and stilpnomelane. Replacement of the mafic minerals by the magnetic alteration assemblage occurred before impact. Similar alteration mechanisms, if operative within the melt sheet, could explain the presence of the high amplitude magnetic anomalies observed at Chicxulub.