Pb isotopic zoning of K-feldspar megacrysts determined by Laser Ablation Multi-Collector ICP-MS: Insights into granite petrogenesis

This study investigates Pb isotopic zoning in magmatic K-feldspar megacrysts from the Monte Capanne pluton (Elba, Italy) using Laser Ablation Multi-Collector-ICPMS. The studied crystals provide an ideal opportunity to use in situ techniques to assess the extent of open-system processes and better characterize the components involved in the genesis of complex magma systems. Earlier investigations of the pluton identified the importance of magma mixing between mantle and crustal-derived magmas.The investigated K-feldspar megacrysts exhibit strong zoning in ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, correlated with lead elemental variations. We interpret these variations as reflecting growth zoning, as opposed to secondary diffusive exchange. Despite a great variety of zoning patterns, we were able to correlate different events of megacryst growth, reflecting crystallization in a dynamic magma system. Our two-step model includes (1) growth of a granitic magma chamber by addition of low ²⁰⁸Pb/²⁰⁶Pb magma to a high ²⁰⁸Pb/²⁰⁶Pb magma contaminated with crustal material (i.e., the megacryst cores) and (2) recharge by mantle-derived magma (i.e., the megacryst rims). We interpret the thorogenic nature of the megacryst rims to reflect the mantle-derived component involved in the mixing process. Taking account of other data from the Tuscan Magmatic Province, the mantle source is inferred to have been metasomatized by continental material during subduction. TIMS Sr isotopic data from microdrilled cores in one megacryst provides general support for the model but show that the two isotopic systems are decoupled.     

Re-Os ages for Archean molybdenite and pyrite, Kuittila-Kivisuo, Finland and Proterozoic molybdenite, Kabeliai, Lithuania: testing the chronometer in a metamorphic and metasomatic setting

Seven ¹⁸⁷Re-¹⁸⁷Os ages were determined for molybdenite and pyrite samples from two well-dated Precambrian intrusions in Fennoscandia to examine the sustainability of the Re-Os chronometer in a metamorphic and metasomatic setting. Using a new ¹⁸⁷Re decay constant (1.666 × 10⁻¹¹y⁻¹) with a much improved uncertainty (±0.31%), we determined replicate Re-Os ages for molybdenite and pyrite from the Kuittila and Kivisuo prospects in easternmost Finland and for molybdenite from the Kabeliai prospect in southernmost Lithuania. These two localities contain some of the oldest and youngest plutonic activity in Fennoscandia and are associated with newly discovered economic Au mineralization (Ilomantsi, Finland) and a Cu-Mo prospect (Kabeliai, Lithuania). Two Re-Os ages for vein-hosted Kabeliai molybdenite average 1486 ± 5 Ma, in excellent agreement with a 1505 ± 11 Ma U-Pb zircon age for the hosting Kabeliai granite pluton. The slightly younger age suggests the introduction of Cu-Mo mineralization by a later phase of the Kabeliai magmatic system. Mean Re-Os ages of 2778 ± 8 Ma and 2781 ± 8 Ma for Kuittila and Kivisuo molybdenites, respectively, are in reasonable agreement with a 2753 ± 5 Ma weighted mean U-Pb zircon age for hosting Kuittila tonalite. These Re-Os ages agree well with less precise ages of 2789 ± 290 Ma for a Rb-Sr whole-rock isochron and 2771 ± 75 Ma for the average of six Sm-Nd T_DM model ages for Kuittila tonalite. Three Re-Os analyses of a single pyrite mineral separate, from the same sample of Kuittila pluton that yielded a molybdenite separate, provide individual model ages of 2710 ± 27, 2777 ± 28, and 2830 ± 28 Ma (Re = 17.4, 12.1, and 8.4 ppb, respectively), with a mean value of 2770 ± 120 Ma in agreement with the Kuittila molybdenite age. The Re and ¹⁸⁷Os abundances in these three pyrite splits are highly correlated (r = 0.9994), and provide a ¹⁸⁷Re-¹⁸⁷Os isochron age of 2607 ± 47 Ma with an intercept of 21 ppt ¹⁸⁷Os (MSWD = 1.1). It appears that the Re-Os isotopic system in pyrite has been reset on the millimeter scale and that the 21 ppt ¹⁸⁷Os intercept reflects the in situ decay of ¹⁸⁷Re during the ∼160 to 170 m.y. interval from ∼2778 Ma (time of molybdenite ± pyrite deposition) to ∼2607 Ma (time of pyrite resetting). When the Re-Os data for molybdenites from the nearby Kivisuo prospect are plotted together with the Kuittila molybdenite and pyrite data, a well-constrained five-point isochron with an age of 2780 ± 8 Ma and a ¹⁸⁷Os intercept (−2.4 ± 3.8 ppt) of essentially zero results (MSWD = 1.5). We suggest that the pyrite isochron age records a regional metamorphic and/or hydrothermal event, possibly the time of Au mineralization. A proposed Re-Os age of ∼2607 Ma for Au mineralization is in good agreement with radiometric ages by other methods that address the timing of Archean Au mineralization in deposits worldwide (so-called “late Au model”). Molybdenite, in contrast, provides a robust Re-Os chronometer, retaining its original formation age of ∼2780 Ma, despite subsequent metamorphic disturbances in Archean and Proterozoic time. Received: 25 September 1996 / Accepted: 27 August 1997     

FLAIR observations of planetary nebulae in the Large Magellanic Cloud

This paper presents new observations of 97 planetary nebulae in the Large Magellanic Cloud (LMC) obtained using the FLAIR system on the UK 1.2-m Schmidt Telescope. These nebulae are mostly at the fainter end of the known population, and about 75 per cent have not been observed before in spectroscopic mode. Radial velocities have been measured using cross-correlation techniques, and represent an increase of 66 per cent in the sample of LMC planetary nebulae with known radial velocities. The major line ratios are given, and are analysed in conjunction with published data. One-quarter of the faint nebulae are Type I objects with very strong [N II ] and [S II ] lines; most of the other faint nebulae have low density, low excitation and relatively strong [S II ] lines.     

RXTE spectroscopy of GRS 1915+105

The galactic superluminal motion source GRS 1915+105 has been extensively observed with the RXTE satellite over the last two years. More than 250 RXTE pointings have been performed until mid-May 1998 with more than 1.5 Msec exposure time on roughly a weekly basis. Here we report on first results of our spectral analysis of a major part of these pointed RXTE observations. We establish the existence of at least 5 spectral components and present the changes of these components over the last two years.     

Water uptake by two river red gum (Eucalyptus camaldulensis) clones in a discharge site plantation in the Western Australian wheatbelt

The heat-pulse technique was used to estimate year-long water uptake in a discharge zone plantation of 9-year-old clonal Eucalyptus camaldulensis Dehnh. near Wubin, Western Australia. Water uptake matched rainfall closely during weter months but exceeded rainfall as the dry season progressed. Average annual water uptake (1148 mm) exceeded rainfall (432 mm) by about 2.7 fold and approached 56% of pan evaporation for the area. The data suggest that at least 37% (i.e. (1/2.7) × 100) of the lower catchment discharge zone should be planted to prevent the rise of groundwater.

Water uptake varied with soil environment, season and genotype. Upslope trees used more water than did downslope trees. Water uptake was higher in E. camaldulensis clone M80 than in clone M66 until late spring. The difference reversed as summer progressed. Both clones, however, have the potential to dry out the landscape when potential evapotranspiration exceeds rainfall. This variation in water uptake within the species indicates the potential for manipulating plantation uptake by matching tree characteristics to site characteristics.

Controlled experiments on the heat-pulse technique indicated accuracy errors of approximately 10%. This, combined with the ability to obtain long-term, continuous data and the superior logistics of use of the heat-pulse technique, suggests that results obtained by it would be much more reliable than those achieved by the ventilated chamber technique.     

An oxygen isotope — Climate record from the Law Dome,Antarctica

Ice cores from a 473 m deep borehole at the summit of the Law Dome, Antarctica have been analysed for oxygen isotope ratio variations. Values averaged over each core section (nominally 2 m long) are used to compile a continuous record for climatic studies and the fine detail measurements which show annual variations are used to establish a date of deposition versus depth relationship. The temperature record derived from the isotope data shows a warm period from 300 to 1000 AD followed by a cooling which, after a partial recovery between 1400 and 1600 AD reaches a maximum around 1800. Temperatures then increase during the nineteenth and twentieth centuries to almost the same values as prior to 1000 AD.     

Heat flow in Eastern Egypt: The thermal signature of a continental breakup

The Red Sea is a modern example of continental fragmentation and incipient ocean formation. Heat flow data have been collected from eastern Egypt to provide information relating to the mode and mechanism of Red Sea opening. Preliminary heat flow data, including new data reported here, are now available from twenty-five sites in eastern Egypt and one site in western Sinai. A pattern of low to normal heat flow (35–55 mW m⁻²) inland with high heat flow (75–100 mW m⁻²) in a zone within 30 to 40 km of the coast is indicated.Moderately high heat flow (around 70 mW m⁻²) is indicated for the Gulf of Suez. The coastal zone thermal anomaly appears continuous with high heat flow previously reported for the Red Sea shelf. Heat production data indicate that the coastal thermal anomaly is not primarily related to crustal radiogenic heat production. The effects of rapid erosion may contribute to the anomaly, but are not thought to be the primary cause of the anomaly. If the anomaly is caused by lateral conduction from hot, extended, offshore lithosphere, the extension must have been active for the last 30 Ma or so, and a minimum of 100% extension is indicated. Alternatively, the anomaly is primarily caused by high mantle heat flow causing lithospheric thinning, centred beneath the Red Sea. The Red Sea is probably underlain by dominantly basic crust, formed either by intrusion into attenuated continental crust or sea-floor spreading, and for most purposes the crust formed in these two modes of extension may be essentially indistinguishable. Fission-track ages from eastern Egypt indicate that uplift started prior to, or at latest at the time of initial Red Sea opening, and this result, together with thermo-mechanical considerations, suggests an active asthenospheric upwelling beneath the Red Sea and high temperature in the lithosphere prior to extension.     

Acute toxicity of mine tailings to four marine species

Acute toxicity bioassays were conducted on mine tailings produced by pilot plant testing for the proposed Quartz Hill molybdenum mine, which will be situated near Ketchikan, Alaska. Tailings bioassays were conducted in seawater with juvenile coho salmon (Oncorhynchus kisutch), mussel larvae (Mytilus edulis), infaunal amphipods (Rhepoxynius abronius), and euphausiids (Euphausia pacifica). The same general range of mine tailings concentrations was acutely toxic to all four test species with acute effects observed between 61 000 to 277 000 mg l^?1 (wet wt) tailings solids (range of 95% confidence limits for LC₅₀ and EC₅₀ values). Chemical analyses of bioassay test solutions and leaching test solutions were conducted for metals (including Cd, Cu, Pb, Zn, Mn and Mo), EPA Priority Pollutant base/neutral organics, and more general parameters such as sulphate, nitrate/nitrite, cyanides, phosphate and ammonia. Parameters possibly contributing to the observed toxicity were complex contaminant mixtures including total suspended solids and heavy metals. The present study provides information related to the marine disposal of mine tailings and shows that these mine tailings present a relatively low level of acutely toxic effects.