Chemical Characterisation of Geological Raw Materials Used in Traditional Ceramics

A wide range of natural raw materials is used in the manufacture of traditional ceramic products such as ceramic tiles, frits, glazes and pigments. The chemical composition of these raw materials needs to be strictly controlled to assure end-product quality and enable the identification of the origin of defects caused by impurities or contamination. Six types of ceramic raw materials (silica sand, clays and kaolin, feldspars and related minerals, calcium and magnesium carbonates, sodium and calcium borates, and zirconium silicates) have been analysed in this study. X-ray fluorescence (XRF), potentiometry, coulometry and atomic absorption spectrometry (AAS) were used in this chemical characterisation. A methodology has been established for characterising each studied raw material, by identifying the chemical elements to be determined, selecting the most appropriate technique and validating each measurement. The reference materials used for validation were BCS CRM 267, 313/1, 393 and 388 (BAS), GBW 03103, GBW 07404, NIST SRM 181, 201a and 1835, Euronorm CRM 782-1 and Syenite SY-2. The results showed that most of the elements present in the geological samples used as traditional ceramic raw materials could be determined by XRF. The determination of light elements, such as lithium, fluorine and boron, is more suitably conducted by ICP-AES/AAS, potentiometry or potentiometry/ICP-AES respectively. Organic and inorganic carbon could be determined by coulometry. Inorganic carbon (CO₂) could also be determined by coulometry or by thermogravimetry, if samples did not contain clay minerals. Loss on ignition was always determined by gravimetry.     

Lake-level fluctuations and paleovegetation during the Houghton phase of glacial Lake Minong

Journal of Paleolimnology - The Houghton phase was a brief period of low water in the glacial Lake Minong (ancestral Lake Superior) basin during the early-mid Holocene. Previous lake-level...     

Neoliberalism,Mineral Development and Indigenous People: a framework for analysis

There have been suggestions in recent literature that neoliberalism and globalisation present positive opportunities for Indigenous communities engaging in resource development projects on their traditional lands. This paper will present evidence from preliminary research on the neoliberal restructuring that has endured for those Indigenous communities of Queensland who have engaged with mineral development opportunities. Initial findings indicate that the State has devolved some of its responsibilities to the mining company in relation to Indigenous development and service provision. This paper develops a theoretical and analytical framework to enable an examination of the implications of this voluntary devolution of responsibility for Indigenous development and service provision and questions whether this represents a positive opportunity for Indigenous people in the region.     

Fault‐controlled dolomite bodies as palaeotectonic indicators and geofluid reservoirs: New insights from Gargano Promontory outcrops

The Upper Jurassic to Lower Cretaceous platform‐slope to basinal carbonate strata cropping out in Gargano Promontory (southern Italy) are partly dolomitized. Fieldwork and laboratory analyses (petrographic, petrophysical and geochemical) allowed the characterization of the dolomite bodies with respect to their distribution within the carbonate succession, their dimensions, geometries, textural variability, chemical stability, age, porosity, genetic mechanisms and relation with tectonics. The dolomite bodies range from metres to kilometres in size, are fault‐related and fracture‐related, and probably formed during the Early Cretaceous at <500 m burial depths and temperatures <50°C. The proposed dolomitization model relies on mobilization of Early Cretaceous seawater that flowed, downward and then upward, along faults and fractures and was modified in its isotopic composition moving through Triassic and Jurassic strata that underlie the studied dolomitized succession. Despite the numerous cases reported in literature, this study demonstrates that hydrothermal and/or high‐temperature fluids are not necessarily required for fault‐controlled dolomitization. Distribution and geometries of dolomite bodies can be used for palaeotectonic reconstructions, as they partly record the characteristics (size, attitude and kinematics) of the palaeo‐faults, even if not preserved, that controlled dolomitization. In Gargano Promontory, dolomites record Early Cretaceous palaeo‐faults from metres to kilometres long, striking north‐west/south‐east to east/west and characterized by normal to strike‐slip kinematics. Dolomitization increases the matrix porosity by up to 7% and, therefore, can improve the geofluid storage capacity of tight, platform‐slope to basinal limestones. The results have a great significance for characterization of geofluid (for example, hydrocarbons) reservoirs hosted in similar dolomitized carbonate successions. Distribution, size and shapes of reservoir rocks (i.e. dolomite bodies) could be broadly predictable if the characteristics of the palaeo‐fault system present at the time of dolomitization are known.     

Falling Lake Victoria water levels: Is climate a contributing factor?

Recently, and perhaps most threatening, Lake Victoria water level has been receding at an alarming rate. A recent study suggested the possibility of the expanded hydroelectric power station in Uganda. However, since the lake receives 80% of its refill through direct rainfall and only 20% from the basin discharge, climatic contributions cannot be ignored, since the 80% water is directly dependant on it. It is therefore necessary to investigate climatic contribution to the declining Lake Victoria water level observed over a long period, i.e., 30 years. This contribution uses 30 years period anomalies for rainfall, river discharge and lake level changes of stations within Lake Victoria basin to analyse linear and cyclic trends of climate indicators in relation to Lake levels. Linear trend analysis using the Student’s t test indicate a decreasing pattern in rainfall anomalies, with the slope being statistically similar to those of water levels at both Kisumu, Maziba and Jinja stations for the same period of time (1976–1999), thus showing a strong correlation. On the other hand, cyclic trend analysis using Discrete Fourier Transform (DFT) shows cyclic period of water level to coincide with those of droughts and rainfall. The strong relationship between climatic indicators of drought and rainfall on one-hand and lake levels on the other hand signifies the need to incorporate climate information in predicting, monitoring and managing lake level changes.     

Introducing a Comprehensive Data Reduction and Uncertainty Propagation Algorithm for U‐Th Geochronometry with Extraction Chromatography and Isotope Dilution MC‐ICP‐MS

We present an open‐source algorithm in Mathematica application (Wolfram Research) with a transparent data reduction and Monte Carlo simulation of systematic and random uncertainties for U‐Th geochronometry by multi‐collector ICP‐MS. Uranium and thorium were quantitatively separated from matrix elements through a single U/TEVA extraction chromatography step. A rigorous calibrator‐sample bracketing routine was adopted using CRM‐112A and IRMM‐035 standard solutions, doped with an IRMM‐3636a ²³³U/²³⁶U ‘double‐spike’ to account for instrumental mass bias and deviations of measured isotope ratios from certified values. The mean of ²³⁴U/²³⁸U and ²³⁰Th/²³²Th in the standard solutions varied within 0.42 and 0.25‰ (permil) of certified ratios, respectively, and were consistent with literature values within uncertainties. Based on multiple dissolutions with lithium metaborate flux fusion, U and Th concentrations in USGS BCR‐2 CRM were updated to 1739 ± 2 and 5987 ± 50 ng g^?1 (95% CI), respectively. The measurement reproducibility of our analytical technique was evaluated by analysing six aliquots of an in‐house reference material, prepared by homogenising a piece of speleothem (CC3A) from Cathedral Cave, Utah, which returned a mean age of 21483 ± 63 years (95% CI, 2.9‰). Replicate analysis of ten samples from CC3A was consistent with ages previously measured at the University of Minnesota by single‐collector ICP‐MS within uncertainties.     

Strong-motion observations from the OGS temporary seismic network during the 2012 Emilia sequence in northern Italy

Strong-motion data consisting of peak ground acceleration and velocity and 5 % damped response spectra are presented for 46 earthquakes of the Emilia seismic sequence which occurred in the Po Plain (northern Italy) in 2012. The data were recorded by the OGS temporary network installed close to the town of Ferrara following the main shock of May 20, 2012. Ground-motion peak parameters and spectral responses are compared with the ground-motion prediction equation (GMPE) of Bindi et al. (Bull Earthq Eng 9:1899–1920, 2011) for soft soils and reverse faults. Peak ground accelerations are in general in good agreement with those predicted by GMPE, while predicted peak ground velocities underestimate the observed data, especially for stronger events at more distant stations. The response spectra follow the trend in peak ground velocities, with observed values higher than predicted values at longer periods. This behavior has been interpreted as a site effect due to the deep soft alluvial cover of the Po Plain, which promotes ground motion characterized by a large low-frequency spectral content that is not yet well modeled by the Italian GMPE. A peculiar behavior was shown by the event occurring on June 6, 04:08:33 UTC, \(\hbox {M}=4.5\) , located at the eastern edge of the Po Plain, which produced peak ground accelerations exceeding three times the values estimated by attenuation laws. Such a great discrepancy could be related to post-critically reflected S-waves and multiples from the Moho (SmSM).     

Soft proton flux on <Emphasis Type="Italic">ATHENA</Emphasis> focal plane and its impact on the magnetic diverter design

The experience gained with the current generation of X-ray telescopes like Chandra and XMM-Newton has shown that low energy “soft” protons can pose a severe threat to the possibility to exploit scientific data, reducing the available exposure times by up to 50% and introducing a poorly reproducible background component. These soft protons are present in orbits outside the radiation belts and enter the mirrors, being concentrated towards the focal plane instruments, losing energy along their path and finally depositing their remaining energy in the detectors. Their contribution to the residual background will be even higher for ATHENA with respect to previous missions, given the much higher collecting area of the mirrors, even if the instruments will likely suffer no significant radiation damage from this particles flux. As a consequence this soft proton flux shall be damped with the use of a magnetic diverter to avoid excess background loading on the WFI or X-IFU instruments. We present here a first complete evaluation of this background component for the two focal plane instruments of the ATHENA mission in absence of a magnetic diverter, and derive the requirements for such device to reduce the soft protons induced background below the level required to enable the mission science. We estimate the soft proton flux expected in L2 for the interplanetary component and for the component generated locally by acceleration processes in the magnetotail. We produce a proton response matrix for each of the two instruments of ATHENA focal plane, exploiting two independent Monte Carlo simulations to estimate the optics concentration efficiency, and Geant4 simulations to evaluate the energy loss inside the radiation filters and deposited in the detector. With this modular approach we derive the expected fluxes and spectra for the soft protons component of the background. Finally, we calculate the specifics of a magnetic diverter able to reduce such flux below the required level for both X-IFU and WFI.