Effects of cations and anions on iron and manganese sorption and desorption capacity in calcareous soils from Iran

This study investigated the effect of cations and anions on the sorption and desorption of iron (Fe) and manganese (Mn) in six surface calcareous soil samples from Western Iran. Six 10 mM electrolyte background solutions were used in the study, i.e., KCl, KNO₃, KH₂PO₄, Ca(NO₃)₂, NaNO₃, and NH₄NO₃. NH₄NO₃ and NaNO₃ increased the soil retention of Fe and Mn, whereas Ca(NO₃)₂ decreased the soil retention of Fe and Mn. Iron and Mn sorption was decreased by NO₃ ^? compared with H₂PO₄ ^? or Cl^?. The Freundlich equation adequately described Fe and Mn adsorption, with all background electrolytes. The Freundlich distribution coefficient (K _F) decreased in the order H₂PO₄ ^? > Cl^? > NO₃ ^? for Mn and H₂PO₄ ^? > NO₃ ^? > Cl^? for Fe. The highest sorption reversibility was for Fe and Mn in competition with a Ca²⁺ background, indicating the high mobility of these two cations. A MINTEQ speciation solubility model showed that Fe and Mn speciation was considerably affected by the electrolyte background used. Saturation indices indicated that all ion background solutions were saturated with respect to siderite and vivianite at low and high Fe concentrations. All ion background solutions were saturated with respect to MnCO_3(am), MnHPO₄, and rhodochrosite at low and high Mn concentrations. The hysteresis indices (HI) obtained for the different ion backgrounds were regressed on soil properties indicating that silt, clay, sand, and electrical conductivity (EC) were the most important soil properties influencing Fe adsorption, while cation exchange capacity (CEC), organic matter (OM), and Mn-DTPA affected Mn adsorption in these soils.     

Geochemistry of Triassic Carbonates: Exploration Guide to Pb–Zn Mineralization in North Tunisia

The Triassic carbonate rocks in Northern Tunisia (Nappes, Domes, Jurassic Mountains zones), consist of massive carbonates, clays and gypsum with authigenic minerals. These are associated with several Pb–Zn deposits and occurrences. At Jebel Ichkeul, Bechateur and Oum Edeboua, these Triassic carbonates exhibit enrichment in Pb (0.32 to 228 ppm), Zn (17 to 261 ppm), Cd (5 to 6 ppm) and Co (0.3 to 89.5 ppm), with respect to their average contents in crustal carbonates. The enrichment is more pronounced at Oum Edeboua (near the ore zone). Permeability is one of the most effective factors of dispersion of metallic trace elements, causing the development of geochemical halos. The genetic relationship of the Triassic carbonate rocks with the ore deposits was controlled by diapirism and tectonic movements, which favored mineralization along the Triassic‐cover contact as well as the remobilization of metals from the mineralized rocks. Analysis of metallic trace elements in Triassic rocks provides clues to the presence of possible mineral deposits. These could be effectively used for both geochemical interpretation and mineral exploration. Carbon and O‐isotope data (– 9.3‰ < δ¹³C < +3‰; +21.9 < δ¹⁸O < +31‰) suggest that the Triassic carbonates of all study areas have marine carbonates as their origin; some of them show significantly lower δ¹⁸O values indicating some exchange with hydrothermal fluids. Calcites associated with mineralization at Oum Edeboua have δ¹³C of –6.2‰ to –8.22‰ and δ¹⁸O of +24.88‰ to +25‰. The C‐isotope compositions of these calcites are ¹³C depleted, indicating an organic origin.     

Statistic and genetic investigation of faults in North Tehran tectonic wedge (South Central Alborz)

In this research, we have focused on the geometrical characteristics of young faults in North Tehran tectonic wedge which is confined with the Mosha and North Tehran faults, the most outstanding active faults in Alborz fold-thrust belt. The statistical, genetic, and kinematic relationships between internal faults, boundary faults, and the stress regime in the area (at the finite state of deformation path) are considered in detail with the help of rose diagrams and Riedel??s model. On this basis, all faults with diverse mechanisms have been classified into different Riedel fractures and their orders of formation are identified. Pattern of faults implies a more or less N?CS compression at the period of faulting. Consideration of geometry and tectonic setting of abundant normal faults have led to propose folding and listric faulting model to explain the origin of normal faults in a compressional tectonic region. These structural models represent the mechanism of normal faulting in response to compression in crustal and upper crustal scales, respectively.     

Application of ASTER and Landsat TM Data for Geological Mapping of Esfandagheh Ophiolite Complex,Southern Iran

This research developed an approach to enable the discrimination of lithological units and detection of host rock of chromitite bodies within ophiolitic complexes using the advanced spaceborne thermal emission and reflection radiometer (ASTER) and Landsat thematic mapper (TM) satellite data. Three main ophiolite complexes located in southern Iran were selected for the study. A specialized band ratio (4/1, 4/5, 4/7) of ASTER, minimum noise fraction (MNF) components and spectral angle mapper (SAM) on ASTER and Landsat TM data were used to distinguish ophiolitic rock units. Results show that the specialized band ratio was able to identify different rock units and serpentinized dunite as host rock of chromitites within ophiolitic complexes. Minimum noise fraction components of ASTER and Landsat TM data are suitable for distinguishing ophiolitic rock complexes at a regional scale. The integration of SAM and feature level fusion used in this investigation discriminated the ophiolitic rock units and provided geological map for the study area, including identification of high potential areas (serpentinite dunite) for chromite exploration targets.     

Optimization of Bottom Friction Coefficient Using Inverse Modeling in the Persian Gulf

Ocean Science Journal - A practical method for the calibration of the ocean circulation model is introduced using measured water levels along the Persian Gulf coastlines. Dimensional analysis is...     

Dynamic 3-D soil–railway track interaction by BEM–FEM

A study on the dynamic response of a railway track is presented via a 3-D formulation based on the frequency domain Boundary Element Method (BEM) and the Finite Element Method (FEM). The railway track consists of a group of surface, massive, rigid footings resting on a viscoelastic half-space and connected by an overlaying rail structure. The BEM, employing the full-space fundamental solutions and quadrilateral elements, is used for the simulation of the elastic half-space while the FEM is used to model the rigid footings and the rail superstructure. The loading function consists of a set of externally applied, harmonic or transient loads. Frequency as well as transient, by way of FFT, results are presented for various modes of vibration. Various numerical studies assess the through-the-soil interaction of the adjacent footings, the influence of soil damping, the effect of the overlaying structure on the frequency content of the system, and the effective simulation of an infinitely long railway track by a truncated one.     

Investigating thermal evolution of the self-gravitating one dimensional molecular cloud by smoothed particle hydrodynamics

The heating of the ion-neutral (or ambipolar) diffusion may affect the thermal phases of the molecular clouds. We present an investigation on the effect of this heating mechanism in the thermal instability of the molecular clouds. A weakly ionized one-dimensional slab geometry, which is allowed for self-gravity and ambipolar diffusion, is chosen to study its thermal phases. We use the thermodynamic evolution of the slab to obtain the regions where slab cloud becomes thermally unstable. We investigate this evolution using the model of ambipolar diffusion with two-fluid smoothed particle hydrodynamics, as outlined by Hosking and Whitworth. Firstly, some parts of the technique are improved to test the pioneer works on behavior of the ambipolar diffusion in an isothermal self-gravitating slab. Afterwards, the improved two-fluid technique is used for thermal evolution of the slab. The results show that the thermal instability may persist inhomogeneities with a large density contrast at the intermediate parts of the cloud. We suggest that this feature may be responsible for the planet formation in the intermediate regions of a collapsing molecular cloud and/or may also be relevant to the formation of star forming dense cores in the clumps.     

Evidence of the formation of landslide-dammed lakes in the Zagros Mountains range,Iran

Alternation of high and low resistance sedimentary beds,active tectonics,large rivers,and slope erosion in valleys consequently resulted in landslide in dammed lakes within the Zagros range.This study presents the results in the analysis of geological and topographic data,satellite imageries,morphotectonics and hydrodynamics of drainage networks about the landslide dammed lakes.There are four landslides in central Zagros(Zagros FoldThrust Belt,ZFTB)which have formed five dammed lakes named,Seymareh,Jaidar,Shur,Shimbar,and Godar.According to the results,damming landslides occurred in the active-tectonic regions on the slopes of anticlines and in valleys with undercutting effects of rivers on their slopes consisting of alternations of loose and resistant beds.The studied landslide dams in narrow valleys are formed as a result of blocking river by sliding debris slopes and rock slides.This study also indicates the formation of Jaidar and Godar in one stage and the presence of Lake Terrace sequence in Seymareh,Shur and Shimbar lakes.The observed sequences of terrace formation in these lakes are caused by four Seymareh Landslides followed by the three-stage excavation of Shur andShimbar lakes.     

Formation of Small-Scale Condensations in the Molecular Clouds via Thermal Instability

A systematic study of the linear thermal instability of a self-gravitating magnetic molecular cloud is carried out for the case when the unperturbed background is subject to local expansion or contraction. We consider the ambipolar diffusion, or ion-neutral friction on the perturbed states. In this way, we obtain a non-dimensional characteristic equation that reduces to the prior characteristic equation in the non-gravitating stationary background. By parametric manipulation of this characteristic equation, we conclude that there are, not only oblate condensation forming solutions, but also prolate solutions according to local expansion or contraction of the background. We obtain the conditions for existence of the Field lengths that thermal instability in the molecular clouds can occur. If these conditions establish, small-scale condensations in the form of spherical, oblate, or prolate shape may be produced via thermal instability.