Stability of waterfront retaining wall subjected to pseudo-static earthquake forces

Waterfront retaining walls supporting dry backfill are subjected to hydrostatic pressure on upstream face and earth pressure on the downstream face. Under seismic conditions, if such a wall retains a submerged backfill, additional hydrodynamic pressures are generated. This paper pertains to a study in which the effect of earthquakes along with the hydrodynamic pressure including inertial forces on such a retaining wall is observed. The hydrodynamic pressure is calculated using Westergaard's approach, while the earth pressure is calculated using Mononobe-Okabe's pseudo-static analysis. It is observed that when the horizontal seismic acceleration coefficient is increased from 0 to 0.2, there is a 57% decrease in the factor of safety of the retaining wall in sliding mode. For investigating the effect of different parameters, a parametric study is also done. It is observed that if φ is increased from 30° to 35°, there is an increase in the factor of safety in the sliding mode by 20.4%. Similar observations were made for other parameters as well. Comparison of results obtained from the present approach with [Ebeling, R.M., Morrison Jr, E.E., 1992. The seismic design of waterfront retaining structures. US Army Technical Report ITL-92-11. Washington DC] reveal that the factor of safety for static condition (k_h=0), calculated by both the approaches, is 1.60 while for an earthquake with k_h=0.2, they differ by 22.5% due to the consideration of wall inertia in the present study.     

Heavy metal exposure from co-processing of hazardous wastes for cement production and associated human risk assessment

This study was carried out to determine the concentration of heavy metals (Cd, Ni, Pb, Cr, Ni and Zn) in ordinary Portland cement (OPC) produced from the co-processing with hazardous waste in comparison with OPC produced using natural raw materials. The results showed that the concentration of heavy metals in cement produced from natural raw material was in the order of Zn > Pb > Cr > Ni > Cu > Cd. Zn and Cd were the highest and the lowest concentrations, respectively, in cements produced from the co-processing activity. The difference between heavy metals concentrations in OPC produced with and without co-processing was found to be statistically significant. The concentration of heavy metals in the cement produced is generally factory dependent. The human risk assessment associated with the heavy metals for non-carcinogenic and carcinogenic risks has been evaluated. The calculated hazard index (HI) and total lifetime cancer risks (LCR) were lower than the acceptable threshold reference values, HI < 1 and LCR < 1 × 10^?4, respectively. Thus, it is anticipated that there is no potential of non-carcinogenic and carcinogenic risks for both adult and children. However, the findings indicated that there is a need for regulatory monitoring. The exposure pathway for both non-carcinogenic and carcinogenic risks are both in the order of ingestion > dermal > inhalation.     

Multi-criteria decision-making analysis in selecting suitable plotting positions for IDF curves of storm events

Selecting suitable distributions for rainfall data is usually subjective and complex since it requires decision-makers to consider results from various measures of goodness-of-fit indices. In this study, the VIKOR method in multi-criteria decision-making analysis is modified to select the most suitable plotting positions to represent extreme storm intensities in order to build the intensity–duration–frequency (IDF) curves of storm events. This is done by considering the rankings provided by all goodness-of-fit indices used to obtain a compromise solution. Nine plotting positions are considered: Weibull (W), Adamowski (A), Gringorten (G), Hazen (H) and Gumbel (EV I) and two known plotting positions for generalized extreme value (GEV) distribution using Pearson’s skewness and another two using L-skewness. The IDF curves obtained are compared to a reference IDF curves which was found using the GEV distribution. The mean and median for three goodness-of-fit indices, the coefficient of variation of root mean square error, CV_RMSE, the mean percentage of difference, Δ, and the coefficient of determination, R ², are taken as the criteria for selection process. The results show that six plotting positions, A, H, W, G and the two plotting positions with L-skewness, are equally superior compared to the other three plotting positions.     

Behavior of Weak Soils Reinforced with End-Bearing Soil-Cement Columns Formed by the Deep Mixing Method

This article reports on a series of small-scale, plane strain, 1 g physical model tests designed to investigate the bearing capacity and failure mechanics of end-bearing soil-cement columns formed via Deep Mixing (DM). Pre-formed soil-cement columns, 24 mm in diameter and 200 mm in length, were installed in a soft clay bed using a replacement method; the columns represented improvement area ratios, a_p, of 17%, 26%, and 35% beneath a rigid foundation of width 100 mm. Particle Image Velocimetry (PIV) was implemented in conjunction with close-range photogrammetry in order to track soil displacement during loading, from which the failure mechanisms were derived. Bearing capacity performance was verified using Ultimate Limit State numerical analysis, with the results comparing favorably to the analytical static and kinematic solutions proposed by previous researchers. A new equation for bearing capacity was derived from this numerical analysis based on the improvement area ratio and cohesion ratio of the soil column and ground model.     

Separation of Vanillin from Oil Palm Empty Fruit Bunch Lignin

The separation of vanillin from the lignin of empty fruit bunch oil palm is presented in this study. The lignin was extracted from soda black liquor derived from oil palm empty fruit bunches (EFB) using 20% sulfuric acid. Nitrobenzene oxidation was carried out by adding 50 mg of dry EFB lignin into a mixture of 7 mL of 2 M NaOH and 4 mL of nitrobenzene in a 15 mL steel autoclave. The autoclave was sealed tightly with a screw cap fitted with a Teflon gasket and heated to 165°C for 3 h in a preheated thermostatic oil bath. High performance liquid chromatography (HPLC) was used to determine the concentration of each compound present in the lignin. There were eight compounds detected in the HPLC chromatogram. The crystallization process was then used as a method to separate vanillin from other compounds. Based on the solubility of vanillin in acetone, 15 mL of acetone was added to the residue of the oxidized products and heated to 60°C for 10 min. A yield of 1.6% vanillin was isolated from a 50 mg lignin sample. The isolated compound was analyzed with HPLC, Fourier transform infrared spectrophotometry (FT‐IR) and nuclear magnetic resonance (¹³C‐NMR) for structural verification. The results of the characterization studies proved that the isolated compound is vanillin.     

Estimation of air-overpressure produced by blasting operation through a neuro-genetic technique

Blasting operations usually produce significant environmental problems which may cause severe damage to the nearby areas. Air-overpressure (AOp) is one of the most important environmental impacts of blasting operations which needs to be predicted and subsequently controlled to minimize the potential risk of damage. In order to solve AOp problem in Hulu Langat granite quarry site, Malaysia, three non-linear methods namely empirical, artificial neural network (ANN) and a hybrid model of genetic algorithm (GA)–ANN were developed in this study. To do this, 76 blasting operations were investigated and relevant blasting parameters were measured in the site. The most influential parameters on AOp namely maximum charge per delay and the distance from the blast-face were considered as model inputs or predictors. Using the five randomly selected datasets and considering the modeling procedure of each method, 15 models were constructed for all predictive techniques. Several performance indices including coefficient of determination (R ²), root mean square error and variance account for were utilized to check the performance capacity of the predictive methods. Considering these performance indices and using simple ranking method, the best models for AOp prediction were selected. It was found that the GA–ANN technique can provide higher performance capacity in predicting AOp compared to other predictive methods. This is due to the fact that the GA–ANN model can optimize the weights and biases of the network connection for training by ANN. In this study, GA–ANN is introduced as superior model for solving AOp problem in Hulu Langat site.     

Nature,origin and evolution of a Late Pleistocene incised valley‐fill,Sunda Shelf,Southeast Asia

Understanding the stratigraphic fill and reconstructing the palaeo‐hydrology of incised valleys can help to constrain those factors that controlled their origin, evolution and regional significance. This condition is addressed through the analysis of a large (up to 18 km wide by 80 m deep) and exceptionally well‐imaged Late Pleistocene incised valley from the Sunda Shelf (South China Sea) based on shallow three‐dimensional seismic data from a large (11 500 km²), ‘merge’ survey, supplemented with site survey data (boreholes and seismic). This approach has enabled the characterization of the planform geometry, cross‐sectional area and internal stratigraphic architecture, which together allow reconstruction of the palaeo‐hydrology. The valley‐fill displays five notable stratigraphic features: (i) it is considerably larger than other seismically resolvable channel forms and can be traced for at least 180 km along its length; (ii) it is located in the axial part of the Malay Basin; (iii) the youngest part of the valley‐fill is dominated by a large (600 m wide and 23 m deep), high‐sinuosity channel, with well‐developed lateral accretion surfaces; (iv) the immediately adjacent interfluves contain much smaller, dendritic channel systems, which resemble tributaries that drained into the larger incised valley system; and (v) a ca 16 m thick, shell‐bearing, Holocene clay caps the valley‐fill. The dimension, basin location and palaeo‐hydrology of this incised valley leads to the conclusion that it represents the trunk river, which flowed along the length of the Malay Basin; it connected the Gulf of Thailand in the north with the South China Sea in the south‐east. The length of the river system (>1200 km long) enables examination of the upstream to downstream controls on the evolution of the incised valley, including sea‐level, climate and tectonics. The valley size, orientation and palaeo‐hydrology suggest close interaction between the regional tectonic framework, low‐angle shelf physiography and a humid‐tropical climatic setting.