Convergence acceleration of iterative sequences for equilibrium chemistry computations

Computational Geosciences - The modeling of thermodynamic equilibria leads to complex nonlinear chemical systems which are often solved with the Newton-Raphson method. But this resolution can lead...     

Studying the impacts of groundwater evolution on the environment,west Qena city,Egypt

The current research has been conducted to evaluate groundwater aquifers qualitatively in the area located in the Western side of Qena city. The Quaternary aquifer represents the main groundwater source in the study area. It exists under unconfined to semiconfined conditions at depths varying between 4 m due North and 80 m in the South. The chemical analyses of the groundwater samples indicate that 77% of the total samples are fresh and 20% are brackish, while only 3% are saline. In addition, the iso-salinity contour map indicates that the salinity increases towards the central and northern parts of the study area. The total and permanent hardness increase as water salinity increases and vice versa in case of temporary hardness in the groundwater samples. The chemical water types and the ion ratios indicate meteoric origin of groundwater as well as the dissolution of terrestrial and marine salts. The contribution of recent recharge from the River Nile to a few groundwater wells in the study area varies from low to high. In addition, the most recharge sources are from the precipitation. Nitrate concentrations in groundwater increase towards the central and Northern areas significantly elevated in response to increasing anthropogenic land uses. Much of the solutes and physicochemical parameters in these waters are under the undesirable limits of World Health Organization (WHO) for drinking purpose, and a plot of sodium adsorption ratio versus EC shows that about 23% of the groundwater samples are good water quality, about 45% of groundwater samples are moderate quality, and 23% of the groundwater samples are intermediate water class, while the rest of samples (9%) are out of the range.     

‘Unionising’ the new spaces of the new economy? Alternative labour organising in India’s IT Enabled Services-Business Process Outsourcing industry

This paper explores the lived experiences and aspirational social constructions of call centre work and employment in India’s high profile IT Enabled Services-Business Process Outsourcing (ITES-BPO) industry; the ways in which they differ from those previously documented amongst call centre workers in the Global North (specifically the UK); and the consequences of that geographical reconfiguration of offshored call centre work for the replicability in India of workplace collective bargaining strategies successfully developed in some UK call centres. These issues are analysed using new empirical evidence from a regional survey of 511 non-unionised ITES-BPO workers and 42 in-depth interviews in India’s National Capital Region. Based on this analysis, the paper then discusses the operation, outcomes and ongoing challenges faced by the newly formed ‘Union for ITES Professionals’ (UNITES Pro) in developing an alternative occupational organising model better suited to the particular needs, motivations and preferences of India’s young, mobile, call centre workers. The empirical analysis presented in the paper is located, therefore, within wider debates on the role of geographical context in shaping possibilities for organising white-collar service workers at different ends of global service chains in the new economy.     

Assessment of contaminants in Dubai coastal region, United Arab Emirates

Coastal uses and other human activities have inevitably impinged on the Gulf environment; therefore, these regions require continuous monitoring. The investigated area covered the maximum fragments of Dubai coastal region in the Arabian Gulf. The determination of major oxides and trace metal concentrations in Dubai sediments revealed three heavily and moderately contaminated regions. One is in the far northeastern part at Al-Hamriya Sts 1–3 and contaminated by Fe, Cu, Pb, and Zn; the second is in the mid-northeastern part at Dry Docks and contaminated by Cu, Ni, Pb, and Zn; and finally, the third is in the near southwestern part at Dubal and contaminated by Fe, Mg, Cr, Ni, and Zn. Al-Hamriya St 3 represented the highest values of Cu, Pb, and Zn, whereas Dubal exhibited the maximum values of Fe, Mg, Ba, Cr, Mn, Ni, and V. The anthropogenic discharge and natural deposits are the main sources of contamination. In general, all trace and major elements showed the minimal levels at Jebel Ali Sanctuary (Sts 11, 12, 13) except for Sr and Ca, which showed their maximum values. The highest concentrations of Ca and Sr are mainly attributed to carbonate gravel sands and sands, which cover most stations. Each of V and Ni showed negative correlation with TPH, which may be indicated that the source of oil contamination in the region is not related to crude oil but mostly attributable to anthropogenic sources. The significant positive correlation, which was found between trace metals and TOC indicates that organic matter plays an important role in the accumulation of trace metals in case of Cu, Zn, and Pb.     

Characterisation of organic matter and microbial communities in contrasting arsenic-rich Holocene and arsenic-poor Pleistocene aquifers,Red River Delta,Vietnam

High concentrations of geogenic As in the groundwaters of south and SE Asia, which are used as drinking waters, are causing severe health impacts to the exposed human populations. It is widely accepted that As mobilisation from sediments into these shallow reducing groundwaters requires active metal-reducing microbes and electron donors such as organic matter (OM). Although OM in such Holocene aquifers has been characterised, there is a dearth of data on Pleistocene aquifers from the same areas. Reported here are preliminary studies of OM and microbial communities present in two aquifers, one of Pleistocene and one of Holocene age, with contrasting concentrations of As (viz. Pleistocene: low As <10 μg/L; Holocene: high As up to 600 μg/L) from Van Phuc village in the Red River Delta, Vietnam. Results revealed OM inputs from multiple sources, including potential contributions from naturally occurring petroleum seeping into the shallow aquifer sediments from deeper thermally mature source rocks. Although concentrations vary, no noticeable systematic differences in biomarker distribution patterns within the OM were observed between the two sites. Microbial analyses did not show a presence of microbial communities previously associated with As mobilisation. All clone libraries were dominated by α-, β-, and γ-Proteobacteria not known to be able to reduce Fe(III) or sorbed As(V). Furthermore, representatives of the Fe(III)-reducing genus Geobacter could only be detected at very low abundance by PCR, using highly selective 16S rRNA gene primers, supporting the hypothesis that metal reduction is not a dominant in situ process in these sediments. No correlation between As concentration in groundwater and OM composition nor microbial community in the host sediments was found. This suggests that either (i) As is not being significantly mobilised in situ in these sediments, instead As appears to be mobilised elsewhere and transported by groundwater flow to the sites or (ii) sorption/desorption processes, as implicated by geochemical data from the cores, play a critical role in controlling As concentrations at these sites.     

Compressibility and shear strength of a residual soil

A detailed study was performed to investigate the compressibility and the shear strength of a residual soil in Omdurman, Sudan. The soil resulted from weathering of sandstone and mudstone. The soil is classified as sandy clayey silt (MH-CH) and is generally partially saturated. Consolidation tests were performed to study the compressibility of the soil and UU, CIU and insitu tests (CPT and SPT) were performed to study the shear strength characteristics of the soil. The characteristics of this residual soil can generally be predicted using correlations proposed in the literature for transported soils. The soil is of low to medium compressibility and exhibits slight apparent overconsolidation behavior. The soil dilates during shear and shows no long term effective cohesion. Problems associated with open cuts in this soil are attributed to loss of strength upon saturation.     

Quantifying the spatio-temporal patterns of settlement growth in a metropolitan region of Ghana

Retrospective understanding of the magnitude and pace of urban expansion is necessary for effective growth management in metropolitan regions. The objective of this paper is to quantify the spatial–temporal patterns of urban expansion in the Greater Kumasi Sub-Region (GKSR)—a functional region comprising eight administrative districts in Ghana, West Africa. The analysis is based on Landsat remote sensing images from 1986, 2001 and 2014 which were classified using supervised maximum likelihood algorithm in ERDAS IMAGINE. We computed three complementary growth indexes namely; Average Annual Urban Expansion Rate, Urban Expansion Intensity Index (UEII) and Urban Expansion Differentiation Index to estimate the amount and intensity of expansion over the 28-year period. Overall, urban expansion in the GKSR has been occurring at an average annual rate of 5.6 %. Consequently, the sub-region’s built-up land increased by 313 km² from 88 km² in 1986 to 400 km² in 2014. The analysis further show that about 72 % of the total built-up land increase occurred in the last 13 years alone, with UEII value of 0.605 indicating a moderate intensity of urban expansion. Moreover, the metropolitan-core of the sub-region, being the focal point of urban development and the historical origins of expansion, accounted for more than half of the total built-up land increase over the 28-year period. Over the last decade and half however, urban expansion has spilled into the neighbouring peripheral districts, with the highest intensity and fastest rate of expansion occurring in districts located north and north east of the sub-regional core. We recommend a comprehensive regional growth management strategy grounded in effective strategic partnerships among the respective administrative districts to curb unsustainable urban expansion.     

Urban form study: the sprawling city—review of methods of studying urban sprawl

There is a large body of research on urban forms. This review paper focuses on the urban sprawl using new and old approaches and new techniques from the subfield of urban Geography. There has been a debate among researchers about the definition of the sprawl, which makes it difficult to suggest a reliable model of the urban sprawl. This review is extremely selective. Numerous papers have focused on measuring the in terms of its physical cost or the environmental and transportation measures linked to this phenomenon. Several attempts have been made to improve the measurement of the sprawl using new approaches. Furthermore, this paper show that certain researchers did not attempt to explore new methods to investigate the urban sprawl in the past and present overlay layers for many years, researchers may use cartography techniques, for example, thereby collecting 20 years of data to match layers and show the differences in any metropolitan area. Several problems remain like differences in the understanding of the sprawl among planners and between other researchers interested in this issue. Also, it is problematic to find one measure, such as mixing different measures together to distinguish between car density and resident density. This study evaluated and reviewed old and recent studies to show that the most important issue in the urban sprawl relates to measurements. Incorporates inform and which measure is best. This article argues that urban spatial expansion reviews some of articles written on urban sprawl and showing the different approaches to studying.