The major‐ and trace‐element whole‐rock fingerprints of Egyptian basalts and the provenance of Egyptian artefacts

Discrimination diagrams have been developed that source Egyptian basaltic artefacts using whole‐rock major element geochemistry. These include K₂O versus SiO₂, TiO₂ and P₂O₅ against MgO/Fe₂O₃^t (total Fe as Fe₂O₃), and a discriminant analysis diagram using SiO₂, Fe₂O₃^t, CaO, and MnO. A complementary set of diagrams uses easily obtained trace element data (Nb/Y versus Zr/Nb; Zr [ppm] versus Rb/Sr; TiO₂ [wt % volatile free] versus V; and Cr [ppm] versus Zr/Y) to determine the bedrock sources. These diagrams have been applied to seven First Dynasty basalt vessels (Abydos), two Fourth Dynasty basalt paving stones (Khufu's funerary temple, Giza), and two Fifth Dynasty paving stones (Sahure's complex, Abu Sir). They show that the bedrock source for all the artefacts was the Haddadin flow in northern Egypt. Multidimensional scaling and cluster analysis applied to the whole‐rock data (major elements and trace elements together) and previously published mineral fingerprinting studies confirm these results. Comparing mineral versus whole‐rock fingerprinting techniques, a major advantage of the former is the small sample size required (0.001 g compared to ≥ 0.1 g). Analytical costs are similar for both methods assuming that a comparison (bedrock) database can be assembled from the literature. For most archaeological problems, a whole‐rock bedrock database is more likely to exist than a mineral database, and whole‐rock analyses on artefacts will generally be easier to obtain than mineral analyses. Whole‐rock fingerprinting may be more sensitive than mineral‐based fingerprinting. Thus, if sample quantity is not an issue, whole‐rock analysis may have a slight cost, convenience, and technical advantage over mineral‐based methods. Our results also emphasize that the Egyptians cherished their Haddadin basalt flow and used it extensively and exclusively for manufacturing basalt vessels and paving stones for at least 600 years (∼3150 B.C. to 2500 B.C., approximate ages of the vessels and Abu Sir paving stones, respectively). © 2001 John Wiley & Sons, Inc.     

Shallow and deep aquifer hydrochemistry and chemical variability of water quality at Shariatpur district, Bangladesh

Water quality and hydrochemistry of Shariatpur district were evaluated in terms of hydrochemical composition and some important physico-chemical parameters. The groundwater of the study area is good for drinking, domestic as well as for irrigation purposes. Among the major ions, shallow tube well waters give higher concentration of Ca²⁺ which ranges from 24 to 260 mg/L. The deep tubewell waters show higher concentration of Na⁺ which varies from 74 to 582 mg/L during dry season. Among the trace elements most of the shallow aquifer samples show higher concentration of Fe²⁺, Mn²⁺ and As. Concentration of Fe²⁺ varies from 0.655 to 18.8 mg/L, and Mn²⁺ from trace to 0.868 mg/L during dry period. Hydrochemical analyses reveal significant seasonal variation in water quality of shallow aquifer. Both the shallow aquifer and the surface water of the study area are predominantly of Ca–Mg–HCO₃ type, while the deep aquifer water is mainly of Na–K–Cl–SO₄ type with slight inclination to Ca–Mg–HCO₃ type. The study area is suitable for groundwater development if comprehensive and holistic approaches towards water resource management are taken into consideration.     

Molecular and distribution data on the poorly known,elusive, cave mysid Harmelinella mariannae (Crustacea: Mysida)

Mediterranean underwater marine caves harbour abundant populations of several species of mysids that are increasingly used as biological models in ecological and evolutionary studies. One exception is the species Harmelinella mariannae, described in 1989 and then hardly ever again reported in the literature. We here provide the first data on the distribution of this poorly known taxon that, contrary to expectations for a rare brooding cave dweller, we now report from Madeira Island in the nearby Atlantic, to the easternmost parts of the Mediterranean. Brief behavioural observations are added, particularly its atypical solitary habits and its feeding behaviour as a high trophic level carnivore. Molecular characterization of the different specimens captured provided three sorts of information. Mitochondrial COI and 16S haplotypes suggest different colonization waves in the Mediterranean, with one group in the Eastern Basin, two in the Marseille region in the NW part of this sea, and another group with a very wide extension from Madeira to Liguria and Malta. Mitochondrial data also support that one of the groups in Marseille might have diverged as a cryptic species of Harmelinella. 18S rRNA gene displays a single common sequence to all specimens from the four groups, and seems to confirm the original proposed placement of this taxon within the subfamily Heteromysinae, not Leptomysinae.     

Trace element geochemistry of CR chondrite metal

We report trace element analyses by laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) of metal grains from nine different CR chondrites, distinguishing grains from chondrule interior (“interior grains”), chondrule surficial shells (“margin grains”), and the matrix (“isolated grains”). Save for a few anomalous grains, Ni‐normalized trace element patterns are similar for all three petrographic settings, with largely unfractionated refractory siderophile elements and depleted volatile Au, Cu, Ag, S. All three types of grains are interpreted to derive from a common precursor approximated by the least‐melted, fine‐grained objects in CR chondrites. This also excludes recondensation of metal vapor as the origin of the bulk of margin grains. The metal precursors were presumably formed by incomplete condensation, with evidence for high‐temperature isolation of refractory platinum‐group‐element (PGE)‐rich condensates before mixing with lower temperature PGE‐depleted condensates. The rounded shape of the Ni‐rich, interior grains shows that they were molten and that they equilibrated with silicates upon slow cooling (1–100 K h^?1), largely by oxidation/evaporation of Fe, hence their high Pd content, for example. We propose that Ni‐poorer, amoeboid margin grains, often included in the pyroxene‐rich periphery common to type I chondrules, result from less intense processing of a rim accreted onto the chondrule subsequent to the melting event recorded by the interior grains. This means either that there were two separate heating events, which formed olivine/interior grains and pyroxene/margin grains, respectively, between which dust was accreted around the chondrule, or that there was a single high‐temperature event, of which the chondrule margin records a late “quenching phase,” in which case dust accreted onto chondrules while they were molten. In the latter case, high dust concentrations in the chondrule‐forming region (at least three orders of magnitude above minimum mass solar nebula models) are indicated.     

3‐D hydrodynamic simulations of the solar chromosphere

We present first results of three‐dimensional numerical simulations of the non‐magnetic solar chromosphere, computed with the radiation hydrodynamics code CO⁵BOLD. Acoustic waves which are excited at the top of the convection zone propagate upwards into the chromosphere where the waves steepen into shocks. The interaction of the waves leads to the formation of complex structures which evolve on short time scales. Consequently, the model chromosphere is highly dynamical, inhomogeneous, and thermally bifurcated.     

Simulation of the interaction of galactic cosmic‐ray protons with meteoroids: On the production of radionuclides in thick gabbro and iron targets irradiated isotropically with 1.6 GeV protons

Abstract— Thick spherical targets made of gabbro (R = 25 cm) and of steel (R = 10 cm) were irradiated isotropically with 1.6 GeV protons at the Saturne synchrotron at Laboratoire National Saturne (LNS)/CEN Saclay in order to simulate the interaction in space of galactic cosmic‐ray (GCR) protons with stony and iron meteoroids. Proton fluences of 1.32 × 10¹⁴ cm^?2 and 2.45 × 10¹⁴ cm^?2 were received by the gabbro and iron sphere, respectively, which corresponds to cosmic‐ray exposure ages of about 1.6 and 3.0 Ma. Both artificial meteoroids contained large numbers of high‐purity target foils of up to 28 elements at different depths. In these individual target foils, elementary production rates of radionuclides and rare gas isotopes were measured by x‐ and γ‐spectrometry, by low‐level counting, accelerator mass spectrometry (AMS), and by conventional rare gas mass spectrometry. Also samples of the gabbro itself were analyzed. Up to now, for each of the experiments, ～500 target‐product combinations were investigated of which the results for radionuclides are presented here. The experimental production rates show a wide range of depth profiles reflecting the differences between low‐, medium‐, and high‐energy products. The influence of the stony and iron matrices on the production of secondary particles and on particle transport, in general, and consequently on the production rates is clearly exhibited by the phenomenology of the production rates as well as by a detailed theoretical analysis. Theoretical production rates were calculated in an a priori way by folding depth‐dependent spectra of primary and secondary protons and secondary neutrons calculated by Monte Carlo techniques with the excitation functions of the underlying nuclear reactions. Discrepancies of up to a factor of 2 between the experimental and a priori calculated depth profiles are attributed to the poor quality of the mostly theoretical neutron excitation functions. Improved neutron excitation functions were obtained by least‐squares deconvolution techniques from experimental thick‐target production rates of up to five thick‐target experiments in which isotropic irradiations were performed. A posteriori calculations using the adjusted neutron cross sections describe the measured depth profiles of all these simulation experiments within 9%. The thus validated model calculations provide a basis for reliable physical model calculations of the production rates of cosmogenic nuclides in stony and iron meteorites as well as in lunar samples and terrestrial materials.     

The Puerto Lápice eucrite

Abstract— Puerto Lápice is a new eucrite fall (Castilla‐La Mancha, Spain, 10 May 2007). In this paper, we report its detailed petrography, magnetic characterization, mineral and bulk chemistry, oxygen and noble gas isotope systematics, and radionuclide data. Study of four thin sections from two different specimens reveal that the meteorite is brecciated in nature, and it contains basaltic and granulitic clasts, as well as recrystallized impact melt and breccia fragments. Shock veins are ubiquitous and show evidence of at least three different shock events. Bulk chemical analyses suggest that Puerto Lápice belongs to the main group of basaltic eucrites, although it has a significantly higher Cr content. Oxygen isotopes also confirm that the meteorite is a normal member of the HED suite. Noble gas abundances show typical patterns, with dominant cosmogenic and radiogenic contributions, and indicate an average exposure age of 19 ± 2 Ma, and a Pu‐fission Xe age well within typical eucrite values. Cosmogenic radionuclides suggest a preatmospheric size of about 20–30 cm in diameter.