Optimal Allocation of Water Resources Using a Two-Stage Stochastic Programming Method with Interval and Fuzzy Parameters

Natural Resources Research - Efficient water allocation is one of the most prominent issues in water resources management. In this research, a two-stage interval-parameter stochastic fuzzy...     

Nonparametric Geostatistical Simulation of Subsurface Facies: Tools for Validating the Reproduction of,and Uncertainty in,Facies Geometry

Delineation of facies in the subsurface and quantification of uncertainty in their boundaries are significant steps in mineral resource evaluation and reservoir modeling, which impact downstream analyses of a mining or petroleum project. This paper investigates the ability of nonparametric geostatistical simulation algorithms (sequential indicator, single normal equation and filter-based simulation) to construct realizations that reproduce some expected statistical and spatial features, namely facies proportions, boundary regularity, contact relationships and spatial correlation structure, as well as the expected fluctuations of these features across the realizations. The investigation is held through a synthetic case study and a real case study, in which a pluri-Gaussian model is considered as the reference for comparing the simulation results. Sequential indicator simulation and single normal equation simulation based on over-restricted neighborhood implementations yield the poorest results, followed by filter-based simulation, whereas single normal equation simulation with a large neighborhood implementation provides results that are closest to the reference pluri-Gaussian model. However, some biases and inaccurate fluctuations in the realization statistics (facies proportions, indicator direct and cross-variograms) still arise, which can be explained by the use of a single finite-size training image to construct the realizations.

     

Mass balance of major elements in relation to weathering in soils developed on igneous rocks in a semiarid region, northwestern Iran

This study was conducted to evaluate the weathering intensity of the major soils developed on igneous rocks in semiarid region of northwestern Iran.Eight parent materials were selected including monzodiorite,alkali granite,granodiorite,syenite,pyroxene diorite,hornblende andesite,pyroxene andesite,and dacite.Representative soil profiles were described and soil samples were collected and analyzed for selected chemical and physical properties and total concentrations of major elements and Zr,V,Ti and Y.Bulk densities as well as Ti,Zr and V concentrations were used to estimate the strain factors and mass balance equations were used to quantify the net result of pedogenic weathering,i.e.elemental loss and gain.The results of clay content and pedogenic iron variability as well as index of compositional variability(ICV),chemical index of alteration(CIA) and,A-CN-K and MFW ternary plots showed that the soils developed on volcanic rocks(hornblende andesite> pyroxene andesite> dacite) were more weathered than those on the plutonic parent rocks(alkali granite,granodiorite,monzodiorite,syenite,pyroxene diorite).The results of mass balance calculations based on the strain factors revealed that the Ca and Na depleted during weathering progress mostly from plagioclase grains.In the semiarid regions Ca is precipitated as pedogenic calcite in the soil horizons.K and Mg depletion is less than Ca and Na especially in the profiles on the hornblende andesite with the highest clay and LOI content.The results of this study clearly suggest that the behavior of K and Mg during the weathering cannot only be explained by the disintegration of the primary minerals,since they are fixed on the secondary clay minerals.Iron did not change in the soils compared to the parent material and was precipitated as the pedogenic iron and conserved in the soil horizons.Overall,the results on the weathering indicators and major elements mass balance enrichment/depletion in the study area confirmed that the soil profiles developed on volcanic rocks are more weathered than those on the plutonic igneous rocks.     

Response Surface Optimization of Acid Red 119 Dye Adsorption by Mixtures of Dried Sewage Sludge and Sewage Sludge Ash

The mixtures of dried sewage sludge (DSS) and sewage sludge ash were studied for removal of acid red 119 (AR119) dye as a new, more environmental friendly, and low cost adsorbent. For this purpose, response surface methodology was applied to optimize the dye removal efficiency and turbidity of treated dye solutions as two individual responses. Results revealed that an optimum condition under specified constraints (dye removal efficiency >95% and turbidity <50 NTU) was obtained at a contact time of 60 min, 40 wt% DSS in the mixture, an initial pH of 6, and an initial dye concentration of 200 mg dye/L in distilled water. Under the optimal condition, dye removal efficiency of 94.98% and effluent turbidity of 24.9 NTU was observed. In further studies, at optimum condition, the effect of some additives on adsorption process and desorption/reusability of adsorbent was investigated. It was observed that removal efficiency was significantly decreased to 83.76% when a simulated dye wastewater (containing the selected dye, acetic acid, and Glauber's salt dissolved in tap water) was used. Desorption studies revealed that AR119 dye could be well removed from dye‐loaded adsorbent by 0.3 M NaOH solution.     

Preparation,Characterization of a Novel Chelating Resin Functionalized with o‐Hydroxybenzamide and Its Application for Preconcentration of Trace Metal Ions

A stable extractor of metal ions was synthesized through azo linking of o‐hydroxybenzamide (HBAM) with Amberlite XAD‐4 (AXAD‐4) and was characterized by elemental analyses, IR spectral, and thermal studies. Its water regain value and hydrogen ion capacity were found to be 12.93 and 7.68 mmol g^?1, respectively. The optimum pH range (with the half‐loading time [min], t_1/2) for Cu(II), Cr(III), Ni(II), Co(II), Zn(II), and Pb(II) ions were 2.0–4.0 (5.5), 2.0–4.0 (7.0), 2.0–4.0 (8.0), 4.0–6.0 (9.0), 4.0–6.0 (12.0), and 2.0–4.0 (15.0), respectively. Comparison of breakthrough and overall capacities of the metals ascertains the high degree of column utilization (>70%). The overall sorption capacities for Cu(II), Cr(III), Ni(II), Co(II), Zn(II), and Pb(II) ions were found to be 0.29, 0.22, 0.20, 0.16, 0.13, and 0.11 mmol g^?1 with the corresponding preconcentration factor of 400, 380, 380, 360, 320, and 320, respectively. The limit of preconcentration was in the range of 5.0–6.3 ng mL^?1. The detection limit for Cu(II), Cr(III), Ni(II), Co(II), Zn(II), and Pb(II) were found to be 0.39, 0.49, 0.42, 0.59, 0.71, and 1.10 ng mL^?1, respectively. The AXAD‐4‐HBAM has been successfully applied for the analysis of natural water, multivitamin formulation, infant milk substitute, hydrogenated oil, urine, and fish.     

Hydrologic response of a Hawaiian watershed to future climate change scenarios

The impact of potential future climate change scenarios on streamflow and evapotranspiration (ET) in a mountainous Hawaii watershed was studied using the distributed hydrology soil vegetation model (DHSVM). The hydrologic response of the watershed was simulated for 43 years for different levels of atmospheric CO₂ (330, 550, 710 and 970 ppm), temperature (+1.1 and + 6.4 °C) and precipitation (±5%, ±10% and ±20%) on the basis of the Intergovernmental Panel on Climate Change (IPCC) AR4 projections under current, B1, A1B1 and A1F1 emission scenarios. Vegetation leaf conductance and leaf area index were modified to reflect the increase in CO₂ concentration. The relative departure of streamflow and ET from their levels during the reference scenarios was calculated on a monthly and annual basis. Results of this study indicate that the streamflow and ET are less sensitive to changes in temperature compared with changes in precipitation. However, temperature increase coupled with precipitation showed significant effect on ET and streamflow. Changes in leaf conductance and leaf area index with increasing CO₂ concentration under A1F1 scenario had a significant effect on ET and subsequently on streamflow. Evapotranspiration is less sensitive than streamflow for a similar level of change in precipitation. On the basis of a range of climate change scenarios, DHSVM predicted a change in ET by ±10% and streamflow between ?51% and 90%. From the six ensemble mean scenarios for AR4 A1B, simulations suggest reduction in streamflow by 6.7% to 17.2%. These reductions would produce severe impact on water availability in the region. Copyright © 2011 John Wiley & Sons, Ltd.     

A synthetic Earth gravity model based on a topographic-isostatic model

The Earth??s gravity field is related to the topographic potential in medium and higher degrees, which is isostatically compensated. Hence, the topographic-isostatic (TI) data are indispensable for extending an available Earth Gravitational Model (EGM) to higher degrees. Here we use TI harmonic coefficients to construct a Synthetic Earth Gravitational Model (SEGM) to extend the EGMs to higher degrees. To achieve a high-quality SEGM, a global geopotential model (EGM96) is used to describe the low degrees, whereas the medium and high degrees are obtained from the TI or topographic potential. This study differes from others in that it uses a new gravimetric-isostatic model for determining the TI potential. We test different alternatives based on TI or only topographic data to determine the SEGM. Although the topography is isostatically compensated only to about degree 40?C60, our study shows that using a compensation model improves the SEGM in comparison with using only topographic data for higher degree harmonics. This is because the TI data better adjust the applied Butterworth filter, which bridges the known EGM and the new high-degree potential field than the topographic data alone.     

Teleseismic Source Parameters of the Rigan County Earthquakes and Evidence for a New Earthquake Fault

Two medium-sized earthquakes occurred on 20 December 2010 and 27 January 2011 in Rigan County, Kerman Province, southeastern Iran. According to the dislocation grid search method results, the first event was nearly strike-slip including reverse component (strike 115°, dip 50°, and rake ?5°) whereas the second event had some amount of reverse component (strike 125°, dip 75°, and rake ?5°). Based on synthetic Green’s function deconvolution and aftershock distribution, the down-dip-propagated rupture migrated toward southeast districts with low population distribution, confirming the reason for low casualties. Meanwhile, the aftershock distribution indicates the existence of a new earthquake fault for which we suggest the name “Rigan earthquake fault.” However, the same aftershock distribution indicates that the second mainshock was inevitably triggered by the first one, most probably along the continuation of the Bam earthquake fault.     

Scour countermeasures for cylindrical piers using riprap and combination of collar and riprap

Various methods are proposed to control scouring around bridge piers. In the present study application of riprap alone and combinations of riprap and collar were examined experimentally for scour control around cylindrical bridge piers. Tests were conducted with seven riprap sizes and with two different sizes of collars. Empirical equations were developed for stable riprap diameter for two cases of piers with and without collar protection. Extent of riprap layer is also presented for these two cases. The results showed that in the range of b/dR≤7.5 (where b is pier diameter and dR is riprap size) using a collar reduced the stable riprap size. It was also concluded that using collar reduced the riprap layer extension in front and sides of the pier.