Petrogenesis of the Late Cretaceous Tholeiitic Volcanism and Oceanic Island Arc Affinity of the Chagai Arc, Western Pakistan

The Late Cretaceous Chagai arc outcrops in western Pakistan, southern Afghanistan and eastern Iran. It is in the Tethyan convergence zone, formed by northward subduction of the Arabian oceanic plate beneath the Afghan block. The oldest unit of the Chagai arc is the Late Cretaceous Sinjrani Volcanic Group. This is composed of porphyritic lava flows and volcaniclastic rocks, and subordinate shale, sandstone, limestone and chert. The flows are fractionated low-K tholeiitic basalts, basaltic-andesites, and andesites. Relative enrichment in their LILE and depletion in HFSE, and negative Nb and Ta and positive K, Ba and Sr anomalies point to a subduction-related origin. Compared to MORB, the least fractionated Chagai basalts have low Na2O, Fe2O3T, CaO, Ti, Zr, Y and 87Sr/86Sr. Rather than an Andean setting, these results suggest derivation from a highly depleted mantle in an intraoceanic arc formed by Late Cretaceous convergence in the Ceno-Tethys. The segmented subduction zone formed between Gondwana and a collage of small continental blocks (Iran, Afghan, Karakoram, Lhasa and Burma) was accompanied by a chain of oceanic island arcs and suprasubduction ophiolites including Semail, Zagros, Chagai-Raskoh, Kandahar, Muslim Bagh, Waziristan and Kohistan-Ladakh, Nidar, Nagaland and Manipur. These complexes accreted to the southern margin of Eurasia in the Late Cretaceous.     

Analyses of Inclined Cracks Neighboring Two Iso-Path Cracks in Rock-Like Specimens Under Compression

Crack propagation process in pre-cracked rock like specimens has been studied experimentally and numerically considering three cracks in the middle part of each specimen. The rock-like specimens are specially prepared from Portland pozzolana cement, fine sands and water. These pre-cracked cylindrical specimens (each containing a single inclined crack in the neighborhood of two iso-path cracks) are experimentally tested under compressive loading. The same problems are numerically simulated by a modified displacement discontinuity method using higher order displacement discontinuity elements and higher order special crack tip elements for crack tip treatment to increase the accuracy of the Mode I and Mode II stress intensity factors obtained based on linear elastic fracture mechanics theory. The crack propagation and coalescence paths of the inclined crack are estimated by implementing a suitable iteration algorithm of incremental crack length extension in a direction predicted by using the maximum tangential stress criterion. The numerical and analytical crack extension analyses are compared which are in good agreement and show the validity, applicability and accuracy of the present work.     

An Experimental Characterization of Shear Wave Velocity (V<Subscript>s</Subscript>) in Clean and Hydrocarbon-Contaminated Sand

The characteristics of hydrocarbon-contaminated soils have been among major concerns of geotechnical engineers due to its significant frequency of event and also its influential consequences on our surroundings from various environmental and engineering viewpoints. Heretofore, the effects of diverse kinds of hydrocarbon contaminants on majority of geotechnical properties of fine- and coarse-grained soils such as grain size, hydraulic conductivity, plasticity, compressibility, internal friction, cohesion, and shear strength have been investigated. However, there has not been a concentrated research study examining shear wave velocity (\({\text{V}}_{\text{s}}\)) of hydrocarbon-contaminated soils as an important geotechnical property of soil due to this fact that, in small/very small strain levels, the maximum shear modulus of soils (\({\text{G}}_{ \hbox{max} }\)) can be determined using shear wave velocity (\({\text{G}}_{ \hbox{max} } =\uprho{\text{V}}_{\text{s}}^{2}\)). This paper aims to investigate effects of hydrocarbon contamination on shear wave velocity of sandy soils by comparing shear wave velocities in identically prepared clean and contaminated samples. To this aim, an Iranian light crude oil, a standard type of silica sand (Ottawa sand), and a bender element apparatus were used to minutely measure shear wave velocity of clean and crude oil contaminated sand samples. Moreover, dry and quasi-moist tamping methods were employed in order to provide comparable clean and contaminated specimens (containing 4, 6, 8, 10, and 12 wt% of crude oil), respectively. Firstly, a comprehensive bender element (BE) and resonant column tests were conducted on the identically prepared clean sand samples at various amounts of frequency (2–20 kHz) and under various confining pressure (50–500 kPa) to find the best methods of accurately determining shear wave travel time in BE tests. Thereafter, BE tests were conducted to examine shear wave velocity in contaminated specimens. Based on the results, it was found that there was a critical value for crude oil content with the maximum shear wave velocity so that shear wave velocity of 4 wt% contaminated sand (V_s-4 wt%) was about 1.2 times higher than clean one (V_s-clean), and contrastingly adding further crude oil up to 6 wt% made a significant reduction in value of shear wave velocity to some extent that V_s-6 wt% was slightly lower than V_s-clean (V_s-6 wt% = 0.95–0.97V_s-clean). Moreover, adding more contaminant (8–12 wt%) into sand had negligible influences on shear wave velocity. In this paper, the effects of crude oil contamination on sand microstructure were also evaluated using scanning electron microscopy.     

Estimation on ureolysis-based microbially induced calcium carbonate precipitation progress for geotechnical applications

There are some key challenges in the geotechnical applications of microbially induced CaCO₃ precipitation technique. These challenges mainly arise from lack of enough control on precipitation patterns within the soil. Monitoring precipitation progress in treatment solution (biogrout) before injection provides useful information on controlling the precipitation pattern. In this study, a hybrid of electrical conductivity change measurements and precipitation mass measurements was proposed for the monitoring. The results were described as characteristic curves which would provide useful information on interpreting, estimating, and steering the precipitation pattern within the soil. The effects of some influencing factors on the precipitation patterns were also statistically investigated. XRD, FTIR, and SEM were used for the microscale identification analysis of the precipitated solids.     

Early Cretaceous migmatitic mafic granulites from the Sabzevar range (NE Iran): implications for the closure of the Mesozoic peri-Tethyan oceans in central Iran

The ophiolitic mélange of the Sabzevar Range (northern Iran) is a remnant of the Mesozoic oceanic basins on the northern margin of the Neotethys that were consumed during the Arabia–Eurasia convergence history. Occurrence of km-scale, dismembered mafic HP granulitic slices is reported in this study. Granulites record an episode of amphibole-dehydratation melting and felsic (tonalite/throndhjemite) melt segregation at c. 1.1 GPa and 800 °C. In situ U(-Th)–Pb geochronology of zircon and titanite grains hosted in melt segregations points to an Early Cretaceous (Albian) age for the metamorphic climax. Results of this study (i) impose reconsideration of the current palaeotectonic models of the Neothetyan convergent margin during the Early Cretaceous and (ii) argue that punctuated events of subduction of short-lived back-arc oceanic basins accompanied the long-lasting history of the Neotethyan subduction in the region.     

Emarat carbonate-hosted Zn–Pb deposit, Markazi Province, Iran: A geological, mineralogical and isotopic (S, Pb) study

The Emarat deposit, with a total proved reserve of 10 Mt ore grading 6% Zn and 2.26% Pb, is one of the largest Zn–Pb deposits in the Malayer–Esfahan belt. The mineralization is stratabound and restricted to Early Cretaceous limestones and dolomites. The ore consists mainly of sphalerite and galena with small amounts of pyrite, chalcopyrite, calcite, quartz, and dolomite. Textural evidence shows that the ore has replaced the host rocks and thus is epigenetic.Sulfur isotopes indicate that the sulfur in sphalerite and galena has been derived from Cretaceous seawater through thermochemical sulfate reduction. Sulfur isotope compositions of four apparently coprecipitated sphalerite–galena pairs suggest their precipitation was under equilibrium conditions. The sulfur isotopic fractionation observed for the sphalerite–galena pairs corresponds to formation temperatures between 77 °C and 168 °C, which agree with homogenization temperatures of fluid inclusions.Lead-isotope studies indicate that the lead in galena has been derived from heterogeneous sources including orogenic and crustal reservoirs with high ²³⁸U/²⁰⁴Pb and ²³²Th/²⁰⁴Pb ratios. Ages derived from the Pb-isotope model give meaningless ages, ranging from Early Carboniferous to future. It is probable that the Pb-isotope model ages that point to an earlier origin than the Early Cretaceous host rocks are derived from older reservoirs in the underlying Carboniferous or Jurassic units, either from the host rocks or from earlier-formed ore deposits within these units.This research and other available data show that the Emarat Zn–Pb deposit has many important features of Mississippi Valley-type (MVT) lead–zinc deposits and thus we argue that it is an MVT-type ore deposit.     

A thirty-year artificial recharge experiment in a coastal aquifer in an arid zone: The Teboulba aquifer system (Tunisian Sahel)

With the increased demand for groundwater resulting from fast demographic growth, accelerated urbanization, economic and agricultural activity diversification, and the increase of per capita consumption, ground water resources, in particular in coastal regions, remain relatively low, compared to demand. The groundwater quality and piezometric variations result mainly from intensive exploitation, agricultural activities and the intrusion of seawater. This phenomenon is observed mostly in semi-arid areas, such as the oriental Sahel of Tunisia, where an apparent reduction in rainfall in recent years can be seen. Groundwater becomes overexploited especially as its natural recharge by rainwater does not succeed in maintaining the hydrologic balance. The imbalance between water demand and resources induces the degradation of the water quality. In such a case, the artificial recharge of water-table aquifers by water from dams is a credible alternative to improve the hydrodynamic and physicochemical conditions of the groundwater. Like most coastal aquifers, the Teboulba water-table aquifer is threatened by overexploitation for at least three decades. This threat appears by a considerable piezometric level drop and by water salinisation, due to seawater intrusion. Given this alarming situation, since 1971, artificial recharge through wells with surface water from a dam was tested in order to restore the water levels and to improve water quality. The piezometric and chemical surveys of the Teboulba aquifer permitted one to describe the temporal and spatial piezometric and geochemical conditions of the aquifer and to show the effect of the artificial recharge. Indeed, the artificial recharge undertaken since 1971 made the geochemical and piezometric conditions of the Teboulba aquifer improve. This example is a rare, well-documented case-study of the benefits of artificial recharge in a coastal aquifer, over the long term.     

Back analysis of an excavated slope failure in highly fractured rock mass: the case study of Kargar slope failure (Iran)

This paper examines the failure of Kargar cut slope located at the south part of Esfahan subway using analytical and numerical back analysis methods. The excavated trench has 27 m depth with near vertical walls due to the space limitation around it. The geology of the area comprises weathered and heavily jointed shale and sandstone overlaid by alluvium deposits. Despite the slope being supported by shotcrete and fully grouted rock bolts, a catastrophic failure occurred at the east wall. Due to the uncertainty about the causes of failure initiation, back analyses have been performed via both the limit equilibrium and numerical method for considering various probable mechanisms. In the back analysis with limit equilibrium method, the rock mass is assumed as an equivalent continuum and Hoek–Brown failure criterion and geological strength index (GSI) are applied to calculate the shear strength parameters. The results show that GSI value was 33 in the failed mass. In the numerical back analysis, the distinct element method is applied to study the contribution of rock joints to the failure and progressive rock mass strength degradation until failure. The results show that threshold values of joint cohesion and friction were 0.2 MPa and 30°, respectively. Also the modeled slip surface being step-shaped agrees with the observed one.     

Organochlorinated compounds in Caspian Sea sediments

Several organochlorinated contaminants, including numerous pesticides, were determined in coastal sediments from the Caspian Sea. The most important contaminants were p,p'-DDT (up to 7400 pg g(-1)) and its breakdown products, p,p'-DDD (up to 3400 pg g(-1)) and p,p'-DDE (up to 1300 pg g(-1)). Although the contamination was most severe in Azerbaijan, the sediment concentrations and percentage distribution of the three DDT-related compounds indicated that such contamination constitutes a contemporary and ubiquitous problem in the Caspian Sea. Lindane represented the second most significant contaminant, particularly in the Russian Federation, with concentrations up to 609 pg g(-1). The concentrations of HCB and other chlorinated pesticides (cis- and trans-chlordane, methoxychlor, heptachlor, heptachlor epoxide, aldrin, endrin, and endosulfans) were lower and not generally of concern, but the pesticides did demonstrate markedly different distributions reflecting differing agricultural usage in the region. The concentrations of Sigma PCBs were also quite low and ranged from 0.03 to 6.4 ng g(-1), with the highest amounts in the Russian Federation and Azerbaijan.