Origin of nickel in water solution of the chalk aquifer in the north of France and influence of geochemical factors

In the north of France, high registers of nickel are sometimes recorded within the chalk aquifer. In a confined context, the presence of pyrite in the covering clays or in the marcasite nodules encrusted in the clay may constitute a natural source of trace metals. With an objective of sanitary control, the limits of chemical contents regulating the quality of water destined for human consumption have been lowered by the European Framework Directive in the field of water policy (2000/60/EC). As a result, nickel limits have been reduced from 50 to 20 μg/l. The analyses, carried out on three water catchment fields in our area of study, were centred on variable parameters (Eh, O₂(d), pH, Conductivity, T°), major elements (SO₄, NO₃) and metals (Fe, Ni, Mn, Co). The acquired data enabled us to identify from one hand, the conditions which are presented within the site, special thanks to the evolution of nitrate and iron contents and on the other hand, the natural origin (geological) of nickel for two of the three sites studied based essentially on the evaluation of the Nickel/Cobalt ratio. Thus, on the first site, the evolution of nickel content and nitrate content showed the influence of the phenomenon of denitrification on the re-mobilisation of the nickel. Whereas on the second site, a high variation of total iron content and oxygen dissolved in solution highlighted a particular phenomenon of oxidation of the pyrite through molecular oxygen. Finally, the correlation with the sulphates clearly showed behaviour of the nickel, once released, that was entirely dependent on the phenomenon of adsorption on the iron and manganese hydroxides.     

Vulnerability and fate of a coastal sand dune complex,Rosetta-Idku,northwestern Nile Delta,Egypt

Types, distribution, and origin of recent sand dunes between Rosetta and Idku, in the western sector of the Nile Delta, Egypt were investigated. Sand samples from the dunes, beach, and seafloor were studied for grain size distribution and mineralogical composition. It has been found that most of the dunes in the study area have been subjected to deterioration and removal due to the construction of buildings and the International Coastal Highway. The remnant constitutes a damaged belt of foredunes that extends from El Bouseily village to the west of Idku town. The dune’s origin is interpreted to be the result of coastal drifting and the subsequent transport of sediments of the former Canopic Nile branch eastward by the predominant longshore current and by aeolian processes. The blown sand grains accumulated to form a belt of coastal sand dunes of original longitudinal and crescentic forms. Urbanization of the coast has severely altered the landscape. The study area is considered vulnerable to the impacts of climate change and the expected rise in sea level. The outcome of potential sea level rise is serious; erosion problems are expected to be exacerbated and vast areas from land and property would be lost. Thus, protection and preservation the remaining dunes in the study area are vital requirements for shore protection.     

A comparative study of four vulnerability mapping methods in a detritic aquifer under mediterranean climatic conditions

This paper presents the results of a comparative study relating to the application of four vulnerability mapping methods, GOD, AVI, DRASTIC and SINTACS, in a pilot detritic aquifer situated in NW Morocco, known as the Martil–Alila aquifer. The principal objective of this work is to determine the most suitable such methods for this aquifer type within a Mediterranean context, and to show the effect of the rainfall variations that are characteristic of the Mediterranean climate on the degree of vulnerability. The methods applied distinguish five classes of vulnerability, these being irregularly divided up in space, with the division varying according to the method in question. The vulnerability maps obtained by the different methods strongly suggest that the eastern half of the aquifer is more vulnerable to contamination than the western half, for all hydrological situations. The effect of climatic conditions on the degree of vulnerability is well represented by the DRASTIC, according to which the aquifer is moderately to strongly vulnerable during humid hydrological years and weakly to moderately vulnerable during dry ones. For the other methods, this climatic effect is limited to the area occupied by the two predominant classes (“High” and “Low” for GOD and “High” and “Moderate” for SINTACS) while it is null for AVI. In conclusion, DRASTIC appears the most suitable for mapping the vulnerability to contamination of Mediterranean coastal detritic aquifers such as the Martil–Alila aquifer.     

Nonlinear Analysis of Local Site Effects on Seismic Ground Response in the Bam Earthquake

The influence of local geologic and soil conditions on the intensity of ground shaking is addressed in this study. The amplification of the ground motion due to local site effects resulted in severe damage to dwellings in the Bam area during the 2003 Bam Earthquake. A unique set of strong motion acceleration recordings was obtained at the Bam accelerograph station. Although the highest peak ground acceleration recorded was the vertical component (nearly 1 g), the longitudinal component (fault-parallel motion) clearly had the largest maximum velocity as well as maximum ground displacement. Subsurface geotechnical and geophysical (down-hole) data in two different sites have been obtained and used to estimate the local site condition on earthquake ground motion in the area. The ground response analyses have been conducted considering the nonlinear behavior of the soil deposits using both equivalent linear and nonlinear approaches. The fully nonlinear method embodied in FLAC was used to evaluate the nonlinear soil properties on earthquake wave propagation through the soil layer, and compare with the response from the equivalent linear approach. It is shown that thick alluvium deposits amplified the ground motion and resulted in significant damage in residential buildings in the earthquake stricken region. The comparison of results indicated similar response spectra of the motions for both equivalent and nonlinear analyses, showing peaks in the period range of 0.3–1.5 s. However, the amplification levels of nonlinear analysis were less than the equivalent linear method especially in long periods. The observed response spectra are shown to be above the NEHRP building code design requirements, especially at high frequencies.     

Effect of Inter-Column Spacing on Soil Stresses due to Vibro-Installed Stone Columns: Interesting Findings

This paper reveals the interesting relation between the inter-column spacing and the corresponding alteration of soil state of stresses due to the vibro-installation technique. This relation is inferred from analyses for load settlement records of various field load tests, performed for stone columns arrangements with different inter-column spacing values. In order to have adequate confidence in the findings, a well-documented case history, involving three columns patterns along with their relevant field and laboratory test results, is utilized for this study. Moreover, a well-tested finite element model, capable of simulating both elasto-plastic and time dependent soil deformations as well as pore water pressure building and dissipation, is employed in the analysis. Instead of determining the soil response to the test load, based on known initial soil stresses and material properties, the analysis is inversely posed to determine the soil initial stresses, based on the recorded settlements and the post-installation material properties. The alteration in the soil state of stress is represented by the increase in the post-installation horizontal to vertical stress ratio, K*, as a function of the inter-column spacing. It is found that this alteration experiences a systematic decrease in its magnitude as the inter-column spacing increases.     

Seasonal and Spatial Variations of Total Mass Flux around Coral Reefs in the Southern Ryukyus,Japan

Total mass flux, size distribution of sediment particles and some chemical components such as total carbon (TC), total nitrogen (TN) and calcium carbonate (CaCO₃) were monitored monthly using a multi-cup sediment traps at seven coral reef sites (6 reef flat and 1 reef slope) of the Marine Protected Areas around Ishigaki, Kohama, Kuroshima and Iriomote Islands in the southern Ryukyus, Japan from September 2000 to September 2001. The size distribution of trapped sediments revealed mostly uni-modal fine sand to mud in the reef flat and gravelly to coarse sand in the reef slope. The total mass flux ranged between 0.54 to 872 gm⁻²d⁻¹, and showed a pronounced seasonality (high in summer-autumn and low in spring) at each site, which was consistent with the rainfall and typhoon regime. Exceptionally high values were observed on the reef slope (Iriomote) in February–March 2001 (1533 gm⁻²d⁻¹) owing to a large amount of bottom sediment re-suspension. On the reef flat (Todoroki South and North; Ishigaki), values obtained in July–August 2001 (872 gm⁻²d⁻¹) and August–September 2001 (800 gm^{− 2}d⁻¹) indicate the high terrestrial discharge from Todoroki River. Trapped sediment particles consist of CaCO₃ (1.2–27.1%) and a non-carbonate fraction (98.8–72.9%), which contains total carbon (4.9–26%), carbonate carbon (CO₂-C) (0.2–3.1%) and non-carbonate carbon (NC-C) (7.9–25.6%). Total nitrogen content was in the range 0.02–0.48%. TN is contained mainly in the carbonate fraction and NC-C may be contained in the non-carbonate fraction. The low TN/OC ratio of the trapped sediments suggests that they were mostly of terrestrial origin and that both fractions migrated. The high total mass flux derived from Todoroki River exceeded the threshold at which a lethal effect on coral community is caused. The results stress the importance of conducting seasonal studies of sedimentation over more than one year and at more than one location in south Japan coral reef ecosystems to gain an understanding of the processes controlling the total mass fluxes and their nutrients content, also to develop an awareness of how to prevent the damage of coral reef ecosystems and, if it does occur, to allow mitigation measures to be undertaken.     

Interstitial water chemistry of the inner continental shelf sediments off the gironde estuary

The interstitial water composition ( , alkalinity, Ca²⁺, Mg²⁺, Sr²⁺, Na⁺, K⁺) and the cation exchange capacity (CEC) were determined for the muddy sediments of the continental shelf off the Gironde Estuary (France), in the area where the sediment represents the deposit of the muddy suspension of the river. In comparison with seawater concentrations, the pore waters below 10 cm depth, show depletions of and Ca²⁺ and below a 30 cm depth show depletions of Mg²⁺. Inversely, the upper 10 cm an enrichment of Ca²⁺ concentration, and an increase of K⁺ concentration to a 40 cm depth. High values of are observed at the top 4 cm. Alkalinity enrichment is observed along the length of the core. Applying the alkalinity models for the sediment below a 10 cm depth demonstrates generally that calculated alkalinities are higher than the measured ones. Ca²⁺ dissolution occurs at the first 10 cm and authigenic carbonate precipitation starts beneath that level. Mg²⁺ depletion is accompanied by bicarbonate loss. This proves that Mg²⁺ depletion is due to a Mg-silicate reaction. The result of the CEC does not confirm the Mg²⁺ uptake by clay minerals in exchangeable site, under reducing conditions. Diffusion and bioturbation play an important role in the pore water concentration at the top of the core.     

Comparison of the biology, dynamics, and secondary production of Talorchestia brito (Amphipoda, Talitridae) in Atlantic (Portugal) and Mediterranean (Tunisia) populations

The biology, population dynamics, and production of Talorchestia brito were studied at two sandy beaches located on the Atlantic (Portugal) and on the Mediterranean (Tunisia) coasts, respectively. The seasonal variation in abundance and the overall densities were similar in both populations. Reproduction occurred from February to September in the Atlantic, and from March to early November in the Mediterranean. The sex ratio was male biased in the Atlantic, and female biased in the Mediterranean. Based on data from the Atlantic population, both abundance and the proportion of reproductive females were positively correlated with temperature, while the proportion of juveniles in the population was positively correlated with temperature and sediment moisture. On average, individuals from the Atlantic were larger than the ones from the Mediterranean. Life span was estimated at six to nine months in the Atlantic, and five to eight months in the Mediterranean. Talorchestia brito was shown to be a semiannual species, with iteroparous females producing two broods per year, and exhibited a bivoltine life cycle. The minimum age required for males' and females' sexual differentiation and for female sexual maturation was shorter in the Mediterranean. Growth production (P) was estimated at 0.19 g m⁻² y⁻¹ ash free dry weight (AFDW; 4.3 kJ m⁻² y⁻¹) in the Atlantic population, and 0.217 g m⁻² y⁻¹ AFDW (4.9 kJ m⁻² y⁻¹) in the Mediterranean one. Elimination production (E) was estimated at 0.35 g m⁻² y⁻¹ AFDW (7.9 kJ m⁻² y⁻¹) in the Atlantic, and 0.28 g m⁻² y⁻¹ AFDW (6.3 kJ m⁻² y⁻¹) in the Mediterranean. The average annual biomass ( ) (standing stock) was estimated at 0.032 g m⁻² in the Atlantic beach, and 0.029 g m⁻² in the Mediterranean one, resulting, respectively, in ratios of 5.9 and 7.5 and ratios of 10.8 and 9.6. Like other talitrids, T. brito exhibited geographic variation in morphometrical characteristics, sex ratio, growth rates, life span, and reproduction period, with the Atlantic population presenting a slower life history.     

A novel technique in analyzing non-linear wave-wave interaction

During wave growth non-linear wave–wave interactions cause transfer of some wave energy from lower to higher wave periods as the spectrum grows. Wavelet bicoherence, which is a new technique in the analysis of wind–wave and wave–wave interactions, is used to analyze non-linear wave–wave interactions. A selected record of wind wave that contains the maximum wave height observed during 6 h of wave generation is divided into five segments and wavelet bicoherence is computed for the whole record, and for all divided segments. The study shows that the non-linear wave–wave interaction occurs at different bicoherence levels and these levels are different from one segment to another due to the non-stationarity feature of the examined data set.     

Dynamics of the long-period tides

The long-period tides are a tool for understanding oceanic motions at low frequencies and large scales. Here we review observations and theory of the fortnightly, monthly and pole tide constitutents. Observations have been plagued by low signal-to-noise ratios and theory by the complex lateral geometry and great sensitivity to bottom slopes. A new spectral element model is used to compute the oceanic response to tidal forcing at 2-week and monthly periods. The general response is that of a heavily damped (Q ≈ 5) system with both the energy input from the moon and the dissipation strongly localized in space. The high dissipation result is probably generally applicable to all low frequency barotropic oceanic motions. Over much of the ocean, the response has both the character of a large-scale and a superposed Rossby wave-like character, thus vindicating two apparently conflicting earlier interpretations. To the extent that free waves are excited they are consistent with their being dominated by Rossby and topographic Rossby wave components, although gravity modes are also necessarily excited to some degree. In general, a modal representation is not very helpful. The most active regions are the Southern Ocean and the western and northern North Atlantic. These results are stable to changes in geometry, topography, and tide period. On a global average basis, the dynamical response of Mm is closer to equilibrium than is Mf.