Elemental hydrochemistry assessment on its variation and quality status in Langat River, Western Peninsular Malaysia

This paper discusses the hydrochemistry variation and its quality status in Langat River, based on the chemistry of major ions, metal concentrations and suitability for drinking purposes. Water samples were collected from 30 different stations to assess their hydrochemical characteristics. The physico-chemical parameters selected were temperature, electrical conductivity, total dissolved solids (TDS), salinity, dissolved oxygen , pH, redox potential, HCO₃, Cl, SO₄, NO₃, Ca, Na, K, Mg, ²⁷Al, ¹³⁸Ba, ⁹Be, ¹¹¹Cd, ⁵⁹Co, ⁶³Cu, ⁵²Cr, ⁵⁷Fe, ⁵⁵Mn, ⁶⁰Ni, ²⁰⁸Pb, ⁸⁰Se and ⁶⁶Zn to investigate the variation of the constituents in the river water. Most of the parameters comply with the Drinking Water Quality Standard of the World Health Organization and the Malaysian National Standard for Drinking Water Quality by the Malaysia Ministry of Health except for EC, TDS, Cl, HCO₃, SO₄, Na, Mg, Al, Fe and Se. The results show that the Langat River is unsuitable for drinking purposes directly without treatment.     

Transpressional regime in southern Arabian Shield: Insights from Wadi Yiba Area, Saudi Arabia

Detailed field-structural mapping of Neoproterozoic basement rocks exposed in the Wadi Yiba area, southern Arabian Shield, Saudi Arabia illustrates an important episode of late Neoproterozoic transpression in the southern part of the Arabian-Nubian Shield (ANS). This area is dominated by five main basement lithologies: gneisses, metavolcanics, Ablah Group (meta-clastic and marble units) and syn- and post-tectonic granitoids. These rocks were affected by three phases of deformation (D₁–D₃). D₁ formed tight to isoclinal and intrafolial folds (F₁), penetrative foliation (S₁), and mineral lineation (L₁), which resulted from early E-W (to ENE-WSW) shortening. D₂ deformation overprinted D₁ structures and was dominated by transpression and top-to-the-W (?WSW) thrusting as shortening progressed. Stretching lineation trajectories, S-C foliations, asymmetric shear fabrics and related mylonitic foliation, and flat-ramp and duplex geometries further indicate the inferred transport direction. The N- to NNW-orientation of both “in-sequence piggy-back thrusts” and axial planes of minor and major F₂ thrust-related overturned folds also indicates the same D₂ compressional stress trajectories. The Wadi Yiba Shear Zone (WYSZ) formed during D₂ deformation. It is one of several N-S trending brittle-ductile Late Neoproterozoic shear zones in the southern part of the ANS. Shear sense indicators reveal that shearing during D₂ regional-scale transpression was dextral and is consistent with the mega-scale sigmoidal patterns recognized on Landsat images. The shearing led to the formation of the WYSZ and consequent F₂ shear zone-related folds, as well as other unmappable shear zones in the deformed rocks. Emplacement of the syn-tectonic granitoids is likely to have occurred during D₂ transpression and occupied space created during thrust propagation. D₁ and D₂ structures are locally overprinted by mesoscopic- to macroscopic-scale D₃ structures (F₃ folds, and L₃ crenulation lineations and kink bands). F₃ folds are frequently open and have steep to subvertical axial planes and axes that plunge ENE to ESE. This deformation may reflect progressive convergence between East and West Gondwana.     

Estimation of the generalized logistic distribution of extreme events using partial L-moments

Abstract

Statistical analysis of extreme events is often carried out to predict large return period events. In this paper, the use of partial L-moments (PL-moments) for estimating hydrological extremes from censored data is compared to that of simple L-moments. Expressions of parameter estimation are derived to fit the generalized logistic (GLO) distribution based on the PL-moments approach. Monte Carlo analysis is used to examine the sampling properties of PL-moments in fitting the GLO distribution to both GLO and non-GLO samples. Finally, both PL-moments and L-moments are used to fit the GLO distribution to 37 annual maximum rainfall series of raingauge station Kampung Lui (3118102) in Selangor, Malaysia, and it is found that analysis of censored rainfall samples of PL-moments would improve the estimation of large return period events.

Editor D. Koutsoyiannis; Associate editor K. Hamed

Citation Zakaria, Z.A., Shabri, A. and Ahmad, U.N., 2012. Estimation of the generalized logistic distribution of extreme events using partial L-moments. Hydrological Sciences Journal, 57 (3), 424–432.     

Geologic controls of submarine groundwater discharge: application of remote sensing to north Lebanon

Typical of Mediterranean countries, the Lebanese shoreline is well known for its littoral and offshore groundwater discharges, the so-called submarine springs. The tectonic framework of the terrain explains its interruption by dense geologic structures, i.e., fracturing, faulting, karstic routes, as well as acute dips of rock strata seaward. All of these structures serve as hydrologic agents transporting groundwater to the sea. The study aims to locate these groundwater discharges, and to interpret their geologic controls on land. For this purpose, two major lines of approach were followed. The first is an airborne thermal infrared (TIR) survey using radiometers to identify thermal anomalies, thereby determining the exact location of submarine groundwater discharges (SGDs). The second line of approach is the analysis of satellite images (Landsat 7ETM⁺) to delineate the geologic features that govern the mechanism of water flow, thereby determining their sources on land. Twenty-seven major SGDs were identified, 10 of these being offshore springs, the others littoral springs. The springs show a large variety of discharge configurations and extents, mainly parallel or perpendicular to the shoreline or rounded. Three major structural controls were identified to contribute to the transport of groundwater to the sea. These are karstic galleries, faults, and tilted rock strata, their contributions being 48, 37, and 15%, respectively. The SGDs associated with linear passageways, i.e., karstic galleries and faults, are connected with land aquifer formations several kilometers away from the shoreline. Moreover, the presence of impervious rock formations at many localities along the coastline results in a confined hydrologic system, promoting the flow of SGDs into the sea.     

Geological impacts on groundwater pollution: a case study in Khuzestan Province

The main aims of this study were to examine the sources of pollution with an emphasis on geogenic sources and to predict the groundwater quality with reasonable accuracy. For this purpose, factor analysis/principal component analysis and partial least squares regression were used to analyze a data set of groundwater quality containing 17 parameters measured at 45 different sampling wells in Andimeshk Aquifer during 2006–2013 time period. Factor analysis identified three factors, which were responsible for the data structure explaining 78.3 % of the total variance of the data set. There were various sources of groundwater contamination, based on factor analysis, in which geological formations next to agricultural activities had the most influential effects. Partial least squares regression could predict the quality of groundwater according to the value of water quality index. The amounts of R-squared (0.79) and MSE (0.21) using seven PLS components showed that this method has been successful in the prediction of water quality in the study area.     

Tectonic and geologic influences on soil gas radon emission along the western extension of Damascus fault,Syria

The main purpose of this work is to demonstrate the possibility of using soil gas radon survey as a promising technique for locating the trend of western extension of Damascus fault, where it is hidden under a cover of Pliocene unconsolidated deposits. The normal level of radon background was established in a stationary area away from the tectonic influence of the fault zone. The sites of radon measurements were chosen according to the accessibility and suitability of the area, besides some indicative geologic and tectonic evidences. A total of 81 radon sampling points were analyzed, and the results revealed some reasonable spatial increases, with peak values of 2–3 times higher than the background level, trending in accordance with what is believed to be the general direction of the fault in the bedrock. However, permeability properties rather than geotectonic activities seemed to be the main causes controlling the variations of radon concentration over the concerned fault zone. Yet, the moderate level of the observed radon values could be attributed to the nature of the prevailing rock types, as well as the probable effect of locked tectonic structure due to the action of high regional compressive regime which typically originates such reverse faulting. Further, the accumulation of fill materials due to rock alteration along the plane of such dormant fault, through long geologic time, possibly led to increase in the ratio of clay minerals which may affect soil gas mobility through the medium.     

Lead in archaeological samples: an isotopic study by ICP-MS

Inductively coupled plasma mass spectrometry (ICP-MS) has been used to measure the concentration and isotopic composition of Pb in archaeological human and animal skeletal remains, soil from a village site of the Omaha tribe (U.S.A.) and cosmetic pigments.Lead concentrations in human bones from the Omaha tribe vary between 4.8 and 2570 μg/g, with younger people having the highest concentrations. Lead concentrations in animal bones from an Omaha village vary between 0.6 and 3.7 μg/g, and those of three soil samples range between 18 and 21 μg/g. Lead concentrations found in human bones from Anasazi (Utah, U.S.A.) and Alta (Peru) populations vary between 0.7 and 3.2 μg/g.Isotope ratios of a reagent grade Pb(NO₃)₂ solutions were measured by thermal ionization mass spectrometry (TIMS), as well as by ICP-MS to provide laboratory reference materials. The accuracy of the ICP-MS measurements relative to TIMS for the standard solution were found to be within 0.02–0.31% for²⁰⁶Pb/²⁰⁴Pb, 0.02–0.55% for²⁰⁷Pb/²⁰⁴Pb, and 0.16–0.56% for²⁰⁸Pb/²⁰⁴Pb. The precision of measurements on artifacts was 0.42–0.65% for²⁰⁶Pb/²⁰⁴Pb and 0.41–0.62% for²⁰⁷Pb/²⁰⁴Pb, whereas the precision for the same ratios for the bones was 0.85–1.8 and 0.82–1.67%, respectively. For the cosmetic lead-bearing pigments, a precision of 0.07–0.15% was found for both²⁰⁶Pb/²⁰⁴Pb and²⁰⁷Pb/²⁰⁴Pb ratios. Lead isotope ratios of artifacts give a radiogenic Pb signature, of which are close to signatures from PbZn mines of the central U.S. region. Lead isotope ratios of the pigments give non-radiogenic Pb signatures. Lead isotope ratios of the bones differ from those of the artifacts, and although similar in isotopic ratio to the pigments, they are more scattered, suggesting potential mixing of Pb from different regions.     

The middle Eocene high-K magmatism in Eastern Iran Magmatic Belt: constraints from U-Pb zircon geochronology and Sr-Nd isotopic ratios

ABSTRACT

Intrusive rocks are well-exposed in the south Birjand around the Koudakan is herein compared to previously studied outcrops along the middle Eocene to late Oligocene Eastern Iran Magmatic Belt. This pluton is composed mainly of monzonite, quartz-monzonite, and granite with high-K calc-alkaline to shoshonitic affinities. The U-Pb zircon geochronology from monzonite and quartz-monzonite reveals the crystallization ages of 40.96 ± 0.48 to 38.78 ± 0.78 Ma (Bartonian). The monzonite, quartz-monzonite, and granite rocks show similar REEs and trace element patterns, as well as limited variations in εNd_(i) and ⁸⁷Sr/⁸⁶Sr_(i) ratio, suggesting that they are a comagmatic intrusive suite. The chondrite and primitive mantle normalized rare earth and trace element patterns show enrichment in the light rare earth elements, K, Rb, Cs, Pb, Th, and U and depletion in heavy rare earth elements, Nb, Zr, and Ti. The εNd_(i) and ⁸⁷Sr/⁸⁶Sr_(i) values range from +1.32 to +1.68 and 0.7044 to 0.7047, respectively, identical to island-arc basalt composition. The whole-rock Nd model age (T_DM) for the intrusive rocks range between 0.69 and 0.73 Ga. These geochemical and isotopic signatures indicate a subduction-related sub-continental lithospheric mantle source for these rocks. Our new geochemical, isotopic, and geochronological studies integrated with previously published data indicate that the middle Eocene to late Oligocene magmatism in eastern Iran was formed in a post-collisional tectonic environment. We suggest the northeastward subduction of the Neo-Tethys ocean beneath the Lut block and the eastward subduction of the Sistan ocean beneath the Afghan block caused mantle wedge to be metasomatized by slab components. At a later stage, a collision between the Lut and Afghan blocks was accompanied by the lithospheric delamination, and the subsequent asthenospheric upwelling led to the melting of the metasomatized sub-continental lithospheric mantle and the generation of middle Eocene to late Oligocene magmatism in the Eastern Iran Magmatic Belt.     

Households’ participation in solid waste management system of Homs city,Syria

GeoJournal - Solid waste management practice is a matter of concern for public health and environmental protection and has become a major challenge in Syria. Improper waste management can bear...     

Effect of glyphosate-based herbicide on early life stages of Java medaka (Oryzias javanicus): A potential tropical test fish

Glyphosate is globally a widely used herbicide, yet there is little information on their toxicity to marine fishes. Java medaka, a small tropical fish native to coastal areas in several Southeast Asian countries, is viewed as a suitable candidate for toxicity test and thus was used for this study. Java medaka adults were cultured in the laboratory and the fertilized eggs of the F₂ generation were exposed to different concentrations of glyphosate-based herbicide (100, 200, 300, 400 and 500 ppm) until they hatched. The survival and hatching rates of the embryos, changes in the heart rate and morphological impairments were recorded. Generally, survival and hatching percentage decreased as glyphosate concentration increased. Absence of pectoral fin(s) and cornea, permanently bent tail, irregular shaped abdomen, and cell disruption in the fin, head and abdomen are among the common teratogenic effects observed. Furthermore, risk factor also increased with the increased in glyphosate concentrations.