Lead in archaeological samples: an isotopic study by ICP-MS

Inductively coupled plasma mass spectrometry (ICP-MS) has been used to measure the concentration and isotopic composition of Pb in archaeological human and animal skeletal remains, soil from a village site of the Omaha tribe (U.S.A.) and cosmetic pigments.Lead concentrations in human bones from the Omaha tribe vary between 4.8 and 2570 μg/g, with younger people having the highest concentrations. Lead concentrations in animal bones from an Omaha village vary between 0.6 and 3.7 μg/g, and those of three soil samples range between 18 and 21 μg/g. Lead concentrations found in human bones from Anasazi (Utah, U.S.A.) and Alta (Peru) populations vary between 0.7 and 3.2 μg/g.Isotope ratios of a reagent grade Pb(NO₃)₂ solutions were measured by thermal ionization mass spectrometry (TIMS), as well as by ICP-MS to provide laboratory reference materials. The accuracy of the ICP-MS measurements relative to TIMS for the standard solution were found to be within 0.02–0.31% for²⁰⁶Pb/²⁰⁴Pb, 0.02–0.55% for²⁰⁷Pb/²⁰⁴Pb, and 0.16–0.56% for²⁰⁸Pb/²⁰⁴Pb. The precision of measurements on artifacts was 0.42–0.65% for²⁰⁶Pb/²⁰⁴Pb and 0.41–0.62% for²⁰⁷Pb/²⁰⁴Pb, whereas the precision for the same ratios for the bones was 0.85–1.8 and 0.82–1.67%, respectively. For the cosmetic lead-bearing pigments, a precision of 0.07–0.15% was found for both²⁰⁶Pb/²⁰⁴Pb and²⁰⁷Pb/²⁰⁴Pb ratios. Lead isotope ratios of artifacts give a radiogenic Pb signature, of which are close to signatures from PbZn mines of the central U.S. region. Lead isotope ratios of the pigments give non-radiogenic Pb signatures. Lead isotope ratios of the bones differ from those of the artifacts, and although similar in isotopic ratio to the pigments, they are more scattered, suggesting potential mixing of Pb from different regions.     

Households’ participation in solid waste management system of Homs city,Syria

GeoJournal - Solid waste management practice is a matter of concern for public health and environmental protection and has become a major challenge in Syria. Improper waste management can bear...     

A typical weathering profile of granitic rock in Johor,Malaysia based on joint characterization

Arabian Journal of Geosciences - One of the most important challenges in the study of slope stability, foundation, and excavation in rocks is understanding the weathering states. This issue is more...     

Geoelectrical exploration for groundwater in Al Maha Forest,Ain Jouhra,Morocco

An area of about 30 km² located in Ain Jouhra, south of Rabat, Morocco, was the subject of a geoelectric resistivity investigation. The main goal of the investigation was the assessment of the groundwater potential of the uppermost aquifer. The aquifer conditions such as depth, thickness and boundaries were also investigated. The obtained apparent resistivity curves were first analysed qualitatively and classified using simple curve shapes. Thereafter, the data were converted to resistivity and thickness pairs semi‐quantitatively by means of master curves and then quantitatively by computer modelling using ATO and Winsev software (Zohdy, 1989; Zohdy and Bisdrof, 1989). Lithological control from the available single well with a stratigraphic log aided in the correlation of the resistivity values to different rock units. Three different AB‐spacing iso‐resistivity maps, an isopach map of the main groundwater‐bearing horizon, the depth to the aquifer substratum map and five geoelectric cross‐sections were constructed. The interpretation of these soundings indicates the presence of an unconfined to semi‐confined sandy aquifer with relatively important extent and varying thickness. The maximal thickness of the aquifer is recorded in the central part of the investigated area and is thinning southwards to pinch out farther to the south. Geophysical as well as field data indicate a hydraulic connection between the upper and deeper aquifers. Indeed, the two aquifers are separated from each other by a marly substratum that is indicated throughout the area by the lowest values of the interpreted true resistivity. The value of this resistivity varies laterally, most likely due to the lateral variation in the shale‐to‐sand ratio. The altitude of the substratum decreases towards the north, and increases southwards. Regarding the availability of the groundwater in the study area, zones with high potential are theoretically expected to occur in the central part where the transversal resistance is greatest. However, sufficient water supply and high flow rates from wells intended to produce restrictively from the most upper aquifer are not likely to exist. This conclusion, which seems to be very pessimistic, is evidenced from two real field and experimental observations. The first is the rapid fall of the level of Gharnoug lake, despite the ongoing feeding by three wells. Hence, the amount of water level drop cannot be accounted for by the evaporation alone. That means that the deeper aquifer is continuously draining the upper aquifer at a high flow rate. Very low rates are recorded in all the wells that penetrated only the upper aquifer, the exception being the well that reached deeper into the lower aquifer. The flow rate in this lower aquifer measured 18 litre s^?1. Copyright © 2007 John Wiley & Sons, Ltd.     

Analytical Modeling of Well Design in Riverbank Filtration Systems

Analytical studies for well design adjacent to river banks are the most significant practical task in cases involving the efficiency of riverbank filtration systems. In times when high pollution of river water is joined with increasing water demand, it is necessary to design pumping wells near the river that provide acceptable amounts of river water with minimum contaminant concentrations. This will guarantee the quality and safety of drinking water supplies. This article develops an analytical solution based on the Green's function approach to solve an inverse problem: based on the required level of contaminant concentration and planned pumping time period, the shortest distance to the riverbank that has the maximum percentage of river water is determined. This model is developed in a confined and homogenous aquifer that is partially penetrated by the stream due to the existence of clogging layers. Initially, the analytical results obtained at different pumping times, rates and with different values of initial concentration are checked numerically using the MODFLOW software. Generally, the distance results obtained from the proposed model are acceptable. Then, the model is validated by data related to two pumping wells located at the first riverbank filtration pilot project conducted in Malaysia.     

Distribution, classification, petrological and related gochemical (SRA) characteristics of a tropical lowland peat dome in the Kota Samarahan-Asajaya area, West Sarawak, Malaysia

Petrographic studies indicate that lateral variations in the decomposition levels of peat are associated with the predominantly occurring peat macerals. Source Rock Analyzer (SRA) results indicate lateral variation in peat organic matter types from type II to III and back again to type II, occurring laterally within the top 0-m to 0.5-m layer at the basin margin to the midsection and further towards the near-center areas of the peat dome. This variation is most likely caused by a combination of factors: (a) Horizontal zonation and lateral variation of the dominant species of plant assemblages (b) Fibric (marginal) peats and hemic to sapric peats associated with type II organic matter (kerogen). Sample organic matter (coal-equivalent kerogen) typing indicates that the relative abundance of phytoclasts and palynomorphs generally supports the organic matter classification obtained by the SRA method. Lateral variations in the peat organic matter types may support the lateral vegetation variation concept. The classification of peat organic matter types (interpreted from visual analyses of palynological slides) occurring from the basin periphery to the mid-section and further towards the basin center yields organic matter of type II to type III and mixed types II to III (coal kerogen-equivalent), respectively.     

Tectonic and geologic influences on soil gas radon emission along the western extension of Damascus fault,Syria

The main purpose of this work is to demonstrate the possibility of using soil gas radon survey as a promising technique for locating the trend of western extension of Damascus fault, where it is hidden under a cover of Pliocene unconsolidated deposits. The normal level of radon background was established in a stationary area away from the tectonic influence of the fault zone. The sites of radon measurements were chosen according to the accessibility and suitability of the area, besides some indicative geologic and tectonic evidences. A total of 81 radon sampling points were analyzed, and the results revealed some reasonable spatial increases, with peak values of 2–3 times higher than the background level, trending in accordance with what is believed to be the general direction of the fault in the bedrock. However, permeability properties rather than geotectonic activities seemed to be the main causes controlling the variations of radon concentration over the concerned fault zone. Yet, the moderate level of the observed radon values could be attributed to the nature of the prevailing rock types, as well as the probable effect of locked tectonic structure due to the action of high regional compressive regime which typically originates such reverse faulting. Further, the accumulation of fill materials due to rock alteration along the plane of such dormant fault, through long geologic time, possibly led to increase in the ratio of clay minerals which may affect soil gas mobility through the medium.     

Diffuse instabilities with transition to localization in loose granular materials

This paper is concerned with diffuse and other ensuing failure modes in geomaterials when tested under homogeneous states of shearing in various loading programs and drainage conditions. Material instability is indeed the basic property that accounts for the instability of an initially homogeneous deformation field leading to diffuse failure and strain localization in geomaterials. The former is normally characterized by a runaway type of failure accompanied with a sudden and violent collapse of the material in the absence of any localization phenomena. Against this backdrop, we present a brief overview of material instability in elastoplastic solids where one finds a rich source of theoretical concepts including bifurcation, strain localization, diffuse failure and second‐order work, as well as a considerable body of experiments. Some compelling laboratory experimental studies of material instability with focus to diffuse failure are then presented and interpreted based on the second‐order work. Finally, various material instability analyses using an elastoplastic constitutive and a general finite element analysis of the above‐mentioned laboratory experimental tests are presented as a boundary value problem. It is shown that instability can be captured from otherwise uniform stress, density and hydraulic states, whereas uniform deviatoric loads are being applied on the external boundaries of a specimen. Although the numerical simulations reproduce well the laboratory experimental results, they also highlight the hierarchy of failure modes where localization phenomena emerge in the post‐bifurcation regime as a result of a degradation of homogeneity starting from a diffuse mode signalled by a zero second‐order work. Copyright © 2012 John Wiley & Sons, Ltd.     

The middle Eocene high-K magmatism in Eastern Iran Magmatic Belt: constraints from U-Pb zircon geochronology and Sr-Nd isotopic ratios

ABSTRACT

Intrusive rocks are well-exposed in the south Birjand around the Koudakan is herein compared to previously studied outcrops along the middle Eocene to late Oligocene Eastern Iran Magmatic Belt. This pluton is composed mainly of monzonite, quartz-monzonite, and granite with high-K calc-alkaline to shoshonitic affinities. The U-Pb zircon geochronology from monzonite and quartz-monzonite reveals the crystallization ages of 40.96 ± 0.48 to 38.78 ± 0.78 Ma (Bartonian). The monzonite, quartz-monzonite, and granite rocks show similar REEs and trace element patterns, as well as limited variations in εNd_(i) and ⁸⁷Sr/⁸⁶Sr_(i) ratio, suggesting that they are a comagmatic intrusive suite. The chondrite and primitive mantle normalized rare earth and trace element patterns show enrichment in the light rare earth elements, K, Rb, Cs, Pb, Th, and U and depletion in heavy rare earth elements, Nb, Zr, and Ti. The εNd_(i) and ⁸⁷Sr/⁸⁶Sr_(i) values range from +1.32 to +1.68 and 0.7044 to 0.7047, respectively, identical to island-arc basalt composition. The whole-rock Nd model age (T_DM) for the intrusive rocks range between 0.69 and 0.73 Ga. These geochemical and isotopic signatures indicate a subduction-related sub-continental lithospheric mantle source for these rocks. Our new geochemical, isotopic, and geochronological studies integrated with previously published data indicate that the middle Eocene to late Oligocene magmatism in eastern Iran was formed in a post-collisional tectonic environment. We suggest the northeastward subduction of the Neo-Tethys ocean beneath the Lut block and the eastward subduction of the Sistan ocean beneath the Afghan block caused mantle wedge to be metasomatized by slab components. At a later stage, a collision between the Lut and Afghan blocks was accompanied by the lithospheric delamination, and the subsequent asthenospheric upwelling led to the melting of the metasomatized sub-continental lithospheric mantle and the generation of middle Eocene to late Oligocene magmatism in the Eastern Iran Magmatic Belt.