A Raman spectroscopic study on the structural disorder of monazite–(Ce)

This study addresses whether Raman spectra can be used to estimate the degree of accumulated radiation damage in monazite-(Ce) samples whose chemical composition was previously determined. Our results indicate that the degree of disorder in monazite–(Ce), as observed from increasing Raman band broadening, generally depends on both the structural state (i.e., radiation damage) and the chemical composition (i.e., incorporation of non-formula elements). The chemical effects were studied on synthetic orthophosphates grown using the Li-Mo flux method, and non radiation-damaged analogues of the naturally radiation-damaged monazite–(Ce) samples, produced by dry annealing. We found that the “chemical” Raman-band broadening of natural monazite–(Ce) can be predicted by the empirical formula, $$ {\hbox{FWHM}} {\hbox{[c}}{{\hbox{m}}^{ - {1}}}{]} = {3}{.95} + {26}{.66} \times {\hbox{(Th}} + {\hbox{U}} + {\hbox{Ca}} + {\hbox{Pb)}} {\hbox{[apfu]}} $$ where, FWHM = full width at half maximum of the main Raman band of monazite–(Ce) (i.e., the symmetric PO₄ stretching near 970?cm^?1), and (Th+U+Ca+Pb) = sum of the four elements in apfu (atoms per formula unit). Provided the chemical composition of a natural monazite–(Ce) is known, this “chemical band broadening” can be used to estimate the degree of structural radiation damage from the observed FWHM of the ν₁(PO₄) band of that particular sample using Raman spectroscopy. Our annealing studies on a wide range of monazite–(Ce) reference materials and other monazite–(Ce) samples confirmed that this mineral virtually never becomes highly radiation damaged. Potential advantages and the practical use of the proposed method in the Earth sciences are discussed.     

Deciphering the Variscan tectonothermal overprint and deformation partitioning in the Cadomian basement of the Teplá–Barrandian unit, Bohemian Massif

The Teplá–Barrandian unit (TBU) has long been considered as a simply bivergent supracrustal ‘median massif’ above the Saxothuringian subduction zone in the Variscan orogenic belt. This contribution reveals a much more complex style of the Variscan tectonometamorphic overprint and resulting architecture of the Neoproterozoic basement of the TBU. For the first time, we describe the crustal-scale NE–SW-trending dextral transpressional Krakovec shear zone (KSZ) that intersects the TBU and thrusts its higher grade northwestern portion severely reworked by Variscan deformation over a southeastern very low grade portion with well-preserved Cadomian structures and only brittle Variscan deformation. The age of movements along the KSZ is inferred as Late Devonian (~380–370?Ma). On the basis of structural, microstructural, and anisotropy of magnetic susceptibility data from the KSZ, we propose a new synthetic model for the deformation partitioning in the Teplá–Barrandian upper crust in response to the Late Devonian to early Carboniferous subduction and underthrusting of the Saxothuringan lithosphere. We conclude that the Saxothuringian/Teplá–Barrandian convergence was nearly frontal during ~380–346?Ma and was partitioned into pure shear dominated domains that accommodated orogen-perpendicular shortening alternating with orogen-parallel high-strain domains that accommodated dextral transpression or bilateral extrusion. The synconvergent shortening of the TBU was terminated by a rapid gravity-driven collapse of the thickened lithosphere at ~346–337?Ma followed by, or partly simultaneous with, dextral strike-slip along the Baltica margin-parallel zones, driven by the westward movement of Gondwana from approximately 345?Ma onwards.     

Evolution of geochemistry and depositional settings of Early Palaeozoic siliciclastics of the Barrandian (Teplá-Barrandian Unit,Bohemian Massif,Czech Republic)

Cambrian and Ordovician-Middle Devonian sequences of two successive Early Palaeozoic basins of the Barrandian unconformably overlie Cadomian basement in the Bohemian Massif NW interior (Teplá-Barrandian unit) which is the easternmost peri-Gondwanan remnant within the Variscides. Correlation of stratigraphy and geochemistry of the Early Palaeozoic siliciclastic rocks elucidated sediment provenances. Sandstones of the Middle Cambrian Píbram-Jince Basin were derived from a Cadomian Neoproterozoic island arc. The source area of the Ordovician shallow-marine siliciclastics of the successor Prague Basin is a dissected Cadomian orogen. Late Cambrian acid volcanics of the Barrandian and Cambrian (meta)granitoids emplaced in the W part of the Teplá-Barrandian Cadomian basement are also discernible in these sediments. Old sedimentary component increased during the Ordovician. Early Llandovery siliciclastic rocks show characteristics of an abruptly weakened supply of terrigenous material and an elevated proportion of synsedimentary basic volcanics as a result of Silurian transgression. Emsian siliciclastics (intercalated in the Late Silurian to Early Devonian limestone suite) presumably comprise an addition of coeval basic/ultrabasic volcaniclastics. Middle Devonian flysch-like siliciclastics indicate reappearance of Cadomian source near the Barrandian during early Variscan convergences of Armorican microplates that preceeded accretion of the Teplá-Barrandian unit within the Bohemian Massif terrane mosaic.Dr. Patoka deceased in July 2004.     

Fast and direct nonparametric procedures in the L-moment homogeneity test

Regional frequency analysis is an important tool to properly estimate hydrological characteristics at ungauged or partially gauged sites in order to prevent hydrological disasters. The delineation of homogeneous groups of sites is an important first step in order to transfer information and obtain accurate quantile estimates at the target site. The Hosking–Wallis homogeneity test is usually used to test the homogeneity of the selected sites. Despite its usefulness and good power, it presents some drawbacks including the subjective choice of a parametric distribution for the data and a poorly justified rejection threshold. The present paper addresses these drawbacks by integrating nonparametric procedures in the L-moment homogeneity test. To assess the rejection threshold, three resampling methods (permutation, bootstrap and Pólya resampling) are considered. Results indicate that permutation and bootstrap methods perform better than the parametric Hosking–Wallis test in terms of power as well as in time and procedure simplicity. A real-world case study shows that the nonparametric tests agree with the HW test concerning the homogeneity of the volume and the bivariate case while they disagree for the peak case, but that the assumptions of the HW test are not well respected.     

Invertebrate colonization of leaves and roots within sediments of intermittent Coastal Plain streams across hydrologic phases

Ecological flows between habitats are vital for predicting and understanding structure and function of recipient systems. Ecological flows across riparian areas and headwater intermittent streams are likely to be especially important in many river networks because of the shear extent of these interfaces, their high edge-to-width ratio, and the alternation of wet and dry conditions in intermittent channels. While there has been substantial research supporting the importance of riparian-stream linkages above-ground, comparatively less research has investigated below-ground linkages. We tested the hypothesis that riparian roots are colonized by invertebrates as a food source within stream beds of intermittent headwater streams. We compared benthic invertebrate assemblages colonizing three types of buried substrates (leaves, roots, and plastic roots) among three intermittent Coastal Plain streams, each with a different riparian management treatment (clearcut, thinned, and reference), over a 1-year period. Invertebrate density was significantly lower in root litterbags than in plastic roots litterbags, but neither differed from densities in leaf litterbags. Total invertebrate abundances, however, were significantly higher in leaf and root litterbags compared to abundances in plastic root litterbags. Invertebrate biomass and richness did not vary among substrates, but invertebrate density, abundance, and richness all declined from the wet phase (September–December) through the dry phase (June–August). Meiofauna and aquatic dipterans were the primary colonizing invertebrates during the wet phase. Relative abundance of terrestrial taxa increased during the dry phase, but their absolute abundance remained lower than aquatic taxa during the wet phase. Invertebrate composition did not differ among substrate types, but was significantly different among streams and time periods. Cumulative number of dry days, degree days, and redox depth all strongly correlated with assemblage structure as indicated by ordination scores. Our results suggest that subsurface invertebrates respond to leaves and roots as food sources, but assemblage composition is not substrate specific. Colonization of leaves and roots within stream beds by aquatic and terrestrial taxa supports the idea that headwater intermittent streams are important interfaces for the reciprocal exchange of energy and materials between terrestrial and aquatic ecosystems.     

Bayesian maximum entropy approach and its applications: a review

The present paper reviews the conceptual framework and development of the Bayesian Maximum Entropy (BME) approach. BME has been considered as a significant breakthrough and contribution to applied stochastics by introducing an improved, knowledge-based modeling framework for spatial and spatiotemporal information. In this work, one objective is the overview of distinct BME features. By offering a foundation free of restrictive assumptions that limit comparable techniques, an ability to integrate a variety of prior knowledge bases, and rigorous accounting for both exact and uncertain data, the BME approach was coined as introducing modern spatiotemporal geostatistics. A second objective is to illustrate BME applications and adoption within numerous different scientific disciplines. We summarize examples and real-world studies that encompass the perspective of science of the total environment, including atmosphere, lithosphere, hydrosphere, and ecosphere, while also noting applications that extend beyond these fields. The broad-ranging application track suggests BME as an established, valuable tool for predictive spatial and space–time analysis and mapping. This review concludes with the present status of BME, and tentative paths for future methodological research, enhancements, and extensions.     

The effect of screening factors and thermonuclear reaction rates in the pre-main sequence evolution of low mass stars

In understanding the nucleosynthesis of the elements in stars, one of the most important quantities is the reaction rate and it must be evaluated in terms of the stellar temperature T, and its determination involves the knowledge of the excitation function σ(E) of the specific nuclear reaction leading to the final nucleus. In this paper, the effect of thermonuclear reaction rates to the pre-main sequence evolution of low mass stars having masses 0.7, 0.8, 0.9 and 1M_⊙ are studied by using our modified Stellar Evolutionary Program.     

The secular variation of inner zone high energy proton environment in the SAA

The main portion of the inner radiation belt en-countered by spacecraft in low-Earth orbits (LEOs) is concentrated over the South Atlantic Anomaly (SAA) where satellites observed the highest particle flux. The anomaly arises from the Earth’s magnetic field being less intense in the region centered near the east of the Atlantic coast of South America. The trapped radiation belt particles therefore have their lowest mirroring altitudes over the center region of the SAA. Drift shells in t…     

土地持续利用的五维空间分析

土地资源的持续利用是人类社会发展的基础，文章较为系统地提出了时间，空间，用途，技术和制度是实现土地资源持续利用的五维空间，并对各维度的内涵进行了较为深入的分析。其中，土地持续利用的时间维主要表现为从伦理角度考虑如何在代际间合理分配土地资源，使代际间利益之和最大；空间维则要求实现土地利用在空间上的合理布局；胜任维要求将土地资源合理配置到各种用途上，从而使人们从土地所提供的产品和劳各中获得的总效用最大；技术维选择意味着土地利用的直接或间接技术的选用能够保证土地的永续使用；制度维要求制度建设适应土地利用情况的变化，通过消除不同的土地制度之间存在着的外部利润来实现土地资源的最优配置。     

环洞庭湖区城镇体系发展研究

通过对环洞庭湖区城镇体系发展的历史背景以及现状特征分析，指出其发展过程存在着城市空间格局发展不平衡，产业结构重复严重等问题，在此基础上，提出了相应的对策与发展措施，确保环湖区内城镇体系的持续，快速发展，并最终实现带动区域经济发展的目的。