Distribution and origin of nitrate in groundwater in an urban and suburban aquifer in Mar del Plata,Argentina

The impact of urbanization on groundwater quality is of special concern for water managers dealing with the provision of drinking water to large urban centers. Nitrate is one of the most common contaminants found in urban aquifers. This paper presents a case study aiming at evaluating the distribution and sources of nitrate in an urban aquifer in the city of Mar del Plata, Argentina. Four study zones under different land uses, including a pristine, a semi-rural, an intermediate, and an urban area, were evaluated as a part of this study. The three latter zones are linked by the groundwater flow system. The average nitrate concentration in the pristine area is 6.7 mg/L as nitrate and is over the permissible level of 50 mg/L for drinking water in the other areas. In the semi-rural area it ranges from 39.2 to 107.1 mg/L with an average value of 38.2 mg/L and the nitrate concentration tends to decrease in the intermediate zone to an average value of 38.2 mg/L; however, values above 60 mg/L are also observed there. Then the nitrate concentration in the urban area water is higher than that in the intermediate zonewater ranging from 48.2 to 100.3 mg/L with an average value of 67.3 mg/L. Data on the stable isotopes 15N and 18O in nitrate show that the main sources of nitrate in the study area are manure associated to agriculture uses and cesspools in the semi-rural area, and leakage of the sewage distribution network in the urban area, respectively. This is supported by a previous study which found that 20 % of the water flooding many underground structures in the city came from leakage of the sewage network. No evidence of nitrate attenuation by denitrification was found in the groundwater. This study has shown that aquifers in urban areas can be affected by agricultural activity in the upstream areas and leakage of the sewage network in the urban area.     

First observation of energetic neutral atoms in the Venus environment

The ASPERA-4 instrument on board the Venus Express spacecraft offers for the first time the possibility to directly measure the emission of energetic neutral atoms (ENAs) in the vicinity of Venus. When the spacecraft is inside the Venus shadow a distinct signal of hydrogen ENAs usually is detected. It is observed as a narrow tailward stream, coming from the dayside exosphere around the Sun direction. The intensity of the signal reaches several , which is consistent with present theories of the plasma and neutral particle distributions around Venus.     

Updating of Population Parameters and Credibility of Discriminant Analysis

The uncertainty of classification in discriminant analysis may result from the original characteristics of the phenomena studied, the approach of inferring population parameters, and the credibility of the parameters which are estimated by geologist or statistician. A credibility function and a significance function are proposed. Both can be used to appraise the uncertainty of classification. The former is involved with the uncertainty resulting from the errors in the reward-penalty matrix, while the latter may be involved with the uncertainty resulting from the original characteristics of the phenomena studied and the statistical approach. Inappropriate classified results may be originated from the bias estimates of population parameters (mean vector and covariance matrix), which are estimated by bias samples. These bias estimates can be updated by constraining the varying region of the mean vector. The equations for updating Bayesian estimates of the mean vector and the covariance matrix are demonstrated if the mean vector is restricted to a subregion of the entire real space. Results for a gas reservoir indicate that the discriminant rules based on the updated equations are more efficient than the traditional discriminant rules.     

Verification of a Synthesized Method for the Calculation of Low-Level Climatological Wind Fields Using a Mesoscale Boundary-Layer Model

Low-level climatological wind fields over the La Plata River region of South America are synthesized with a dry, hydrostatic mesoscale boundary-layer numerical model. The model is forced at the upper boundary with the 1200 UTC local radiosonde observations and at the lower boundary with a land-river differential heating function defined from the daily meteorological observations of the region. The climatological wind field is defined as the mean value of a series of individual daily forecasts, employing two methods. The simplified method considers a 192-member ensemble (16 wind directions and 12 wind-speed classes at the upper boundary). Each member has a probability of occurrence that is determined from the 1959–1984 observations; the daily method uses a total of 3,248 days with available data during the same period. In both methods each realization is a daily forecast from which the mean wind distributions at 0300, 0900, 1500 and 2100 local standard time are calculated and compared to the observations of five meteorological stations in the region. The validation of the climatological wind fields for both methods is evaluated by means of the root-mean-square error of the wind-direction frequency distribution and mean wind speed by wind sector. The results obtained with the two methods are similar, and the errors in wind speed are always smaller than those in wind direction. The combined errors of wind direction and wind speed show that the ensemble method is outperformed by the daily method, on average by meteorological station in only one out of five of them, and on average by the time of the day in only one out of 4 h. The conclusion of the study is that the ensemble method is an appropriate methodology for determining high resolution, low-level climatological wind fields, with the boundary-layer model applied to a region with a strong diurnal cycle of surface thermal contrast. The proposed methodology is of particular utility for synthesizing wind fields over regions with limited meteorological observations, since the 192-member matrix can be easily defined with few observing points, as well as in the case of relatively incomplete records.     

Rotating magnetopolytropes: spherical figures of equilibrium due to balance of magnetic field and rotation

In this paper we compute spherical figures of equilibrium resulting from the balance of toroidal magnetic field and rotation. These two distortion effects are assumed to act on rotating magneto-polytropic constant-mass sequences, that is, sequences with each of their members having mass constant and equal to that of the corresponding nondistorted model.     

Twenty years of paleoseismology in Italy

Italy has one of the most complete and historically extensive seismic catalogues in the World due to a unique and uninterrupted flow of written sources that have narrated its seismic history since about the end of the Iron Age. Seismic hazard studies have therefore always been mainly based upon this huge mass of data. Nevertheless, the Italian catalogue probably “lacks” many M ≥ 6.5 events, the seismogenetic structures responsible for which are characterized by recurrence times that are longer than the time span covered by our historical sources. For these reasons, and as in other countries, earthquake data that in Italy have been derived from paleoseismological studies should finally become a necessary ingredient in seismic risk assessment. Indeed, over the past 20 years, some hundred trenches have been excavated, supplying reliable and conclusive data on the recent activities of many faults. Through to many robust datings of surface fault events, these studies have provided the ages of several unknown or poorly known M ≥ 6.5 earthquakes. Here, we summarize the state of the art of paleoseismology in Italy, and present a first catalogue of 56 paleoearthquakes (PCI) that occurred mainly in the past 6 kyr. The PCI integrates the historical/instrumental seismic catalogue, and extends it beyond the recurrence time of the seismogenetic faults (2000 ± 1000 yr). We feel confident that the use of the PCI will enhance future probabilistic seismic hazard assessment, and thus contribute to more reliable seismic risk mitigation programs.     

Three magnitude 7 earthquakes on a single fault in central Italy in 1400 years,evidenced by new palaeoseismic results

New palaeoseismic trenching across the main splay of the Fucino fault system provides evidence for a High Middle Age surface‐faulting episode conceivably associated with a disruptive earthquake, similar to the one that occurred in 1915 (Mw 7.0). The existence of this event, which has already been suggested by some previous studies, implies a shortening of the recurrence interval for Mw 7.0 earthquakes with respect to current knowledge. If we assume that the palaeoseismic Holocene record is complete, this shortening is focused in the historical period, when the Fucino structure sourced three strong earthquakes in only 1.4 ka. A similar clustering of energy release in the recent past is consistent with both palaeoseismological studies on other faults affecting the Apennine divide, and the high GPS strain rates observed in the same chain sectors.     

Surface breaks along the coastal plain of Cirò (Ionian Calabria,southern Italy): geophysical and paleoseismological insights

On July 28, 2004, the coastal plain of Cirò (Calabria, Ionian Sea) was interested by the sudden opening of a ~5-km-long fracture, paralleling the coastline. All the buildings, roads, and pipelines crossed by the fracture were damaged, inducing several inhabitants to abandon their houses. The crack was 1–2-cm wide, downthrowing the seaward block up to 1–2 cm. This phenomenon is known for having already hit this area at least in the past century, both concurrently or not to earthquakes with epicentre far away from Cirò. In order to investigate the subsurface geometry, and the nature of the crack, we performed 5 electrical resistivity tomography and two paleoseismological trenches across it. The two methods provided evidences for the whole displacement of the local coastal succession, with offsets of several metres cumulated during the late Holocene. Giving the radiocarbon age of samples collected in trenches, we have constrained the dates of a couple of offset events which match some paleoearthquakes caused by the Lakes Fault, in the neighbouring Sila Massif. Excluding other possible causes (i.e. anthropic or tectonic), we are inclined to interpret these phenomena as the westernmost, surficial expression of a submarine deep-seated gravity sliding.     

Hydrochemical and isotopic characterization of the hydrological budget of a MAB Reserve: Mar Chiquita lagoon,province of Buenos Aires,Argentina

Mar Chiquita is a coastal lagoon located in the Argentine Buenos Aires province in South America. The aim of this study was to perform a hydrochemical and stable isotopes characterization in order to better the understanding of the hydrology of the Mar Chiquita lagoon’s catchment and its water budget. Groundwater samples were taken from 144 wells and 21 samples from main streams, and seven lagoon water samples were also collected. Chemical analyses were carried out using standard laboratory methods, and isotopic determinations were made through laser spectroscopy using a DLT-100 liquid–water isotope analyzer. Hydrochemical analysis permits a general classification of groundwater and streamwater as sodium bicarbonate waters, while the lagoon chemical composition shows an evolution toward seawater composition, from the north to its mouth, which is located southerly. Isotopic data show a source of aquifer recharge from rainfall and a groundwater domain into the streams’ flow. Three main components can be recognized as end members in a plot of electrical conductivity (EC) versus δ¹⁸O: seawater, streamwater and groundwater. Obtained EC values for groundwater in the discharge zone (EC average value = 3,516 μS/cm) allow minimizing its direct contribution and to take into consideration two dominating end members: streamwater and seawater. Mar Chiquita lagoon’s water falls close to the line between streamwater and seawater end members according to its EC and δ¹⁸O. The obtained seawater proportion for these samples ranges from 84 % in the lagoon’s mouth to around 0 % in the more distal area.     

Tectonometamorphic history of the Gruf complex (Central Alps): exhumation of a granulite–migmatite complex with the Bergell pluton

We describe field occurrences of sapphirine-bearing granulites, charnockites and migmatites in the Gruf complex, Central Alps and present a new geological map and a structural analysis of the entire Gruf complex for the first time. We have carried out an accurate analysis of the relationships between granulite facies metamorphism, migmatisation and deformation within the complex, in relation to the intrusion of the Bergell pluton. Granulites and charnockites display fabrics different from those defined by the regional foliation and lineation, which are, typically for migmatites, disordered on the mesoscale. On a regional scale, strike variations are also related to the structural complexity of migmatites within which no major antiform could be identified. Irregular interfingering of sub-parallel leucosome veins and back-veining along the contact between the Gruf migmatites and the Bergell tonalite are evidence for contemporaneous emplacement and crystallisation at about 740 °C and 6.5–7.5 kbar in Oligocene times (ca 30 Ma). Metamorphic conditions in the charnockites and granulites (>920 °C for 8.5–9.5 kbar) largely exceed these regional metamorphic conditions and are dated at 282–260 Ma. We propose that the ascending Bergell pluton entrained the polymetamorphic, granulitic lower crust enclosed within the peripheral migmatitic Gruf complex.